Results of crossed-beam measurements of cross sections differential in ejected electron energy and angle for ionization of atomic hydrogen by 20-1 14-keV protons are reported. Secondary electrons were measured over an energy range of 1.5-300 eV and an angular range of 15"-165". Atomic-hydrogen targets were produced in a radio-frequency discharge source with a dissociation fraction of about 74%. Ratios of cross sections for H targets to those for Hz targets were obtained from measurements on the mixed target. From these ratios, the measured dissociation fractions, and the absolute cross sections measured for H, targets, the cross sections for H targets were determined. These measurements are compared with the results of the first-order Born approximation, the continuum-distorted-wave eikonalinitial-state approximation, and the classical trajectory Monte Carlo (CTMC) methods. Good overall agreement is found with the CTMC results, except for slow, backward electron emission. The addition of the classically suppressed dipole transitions from the Born approximation to the CTMC results yields a good estimate of the ejected electron spectrum.PACS number (& 34.50.Fa

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Electronic energy transfer in photosynthesis occurs over a range of time scales and under a variety of intermolecular coupling conditions. Recent work has shown that electronic coupling between chromophores can lead to coherent oscillations in two-dimensional electronic spectroscopy measurements of pigment-protein complexes measured with femtosecond laser pulses. A persistent issue in the field is to reconcile the results of measurements performed using femtosecond laser pulses with physiological illumination conditions. Noisy-light spectroscopy can begin to address this question. In this work we present the theoretical analysis of incoherent two-dimensional electronic spectroscopy, I(4) 2D ES. Simulations reveal diagonal peaks, cross peaks, and coherent oscillations similar to those observed in femtosecond two-dimensional electronic spectroscopy experiments. The results also expose fundamental differences between the femtosecond-pulse and noisy-light techniques; the differences lead to new challenges and new opportunities.

We have studied the fundamental process of ionization in a pure three-body ionatom collision involving atomic hydrogen as a target and a bare heavy-ion as a projectile. We report the measurements of the double-differential cross section (DDCS) of ionization for 2.5 MeV u −1 C 6+ + H (v = 10 au). The measurements of the energy and angular distributions of the double-differential cross sections of the low-energy electrons and a comparison with the CDW-EIS and FBA calculations provide a detailed understanding of the two-centre mechanism of electron emission. The forward-backward asymmetry parameters have also been studied. The DDCS ratio between molecular and atomic hydrogen shows a prominent structure.

Ion-pair interactions between pyridinium cations and various carboxylate anions are explored using noisy light based coherent anti-Stokes Raman scattering (I(2)CARS). Binary mixtures of pyridine and various carboxylic acids (including halo-acetic acids, straight-chain carboxylic acids, and pivalic acid) are prepared. A Brønsted type acid-base reaction occurs in these mixtures to create pyridinium and carboxylate ions. Both pyridine, itself, and pyridinium have strong I(2)CARS signals originating from their ring breathing modes. The vibrational frequency of the ring breathing mode for pyridine is blue-shifted by hydrogen bonding, and that same mode for pyridinium is red-shifted by ion-pair interaction. Frequency shift data for the ring breathing mode of pyridine and pyridinium are presented. These data are discussed in terms of a simplistic model for the electronic behavior of these compounds.