Sandstones of Punagarh basin of Trans Aravalli region, NW Indian shield were analyzed for their major and trace element contents in conjunction with petrographic modes. The Punagarh basin comprises four formations (Sojat, Bambolai, Khamal and Sowania), amongst which the Sojat Formation in uncoformable contact with overlying formations, is significantly older and enjoys separate status as rest of the formations constitute Punagarh Group. Petrographic attributes suggest that Sojat sandstones contain distinct modal abundances like high content of quartz and low content of feldspar, mica, matrix, rock fragments and cement. In general there is a decrease in the average modal abundance of quartz and mica with concomitant increase of feldspar, chert and rock fragments from base to top in Punagarh sandstones. Sojat sandstones are also geochemically distinct as they possess high SiO2/Al2O3, Th/U and Cr/Th ratios coupled with lowest Na2O/K2O ratio and Zr content, least fractionated LREE, more fractionated HREE and largest Eu* anomaly compared to Punagarh sandstones. The weathering indices suggest intense chemical weathering for Sojat sandstones and low to moderate for Punagarh sandstones. Compositionally all the sandstones of the Punagarh basin come under the category of quartzarenite. Compared to PAAS and UCC, both suite of sandstones are generally depleted in REE, HFSE (with exception of Zr, Hf and Ta), and enriched in ferromagnesian trace elements particularly Cr and Co. The chemical data indicate that the sediments were derived from the source(s) of mixed felsic - mafic composition, with the former being dominant. The source rocks were granites, TTG, basalts, and rhyolites. The Sojat sandstones owe their source form Archean crust while Punagarh sandstones got detritus from Mesoproterozic crust. Immobile element ratios and REE abundances of Sojat sandstones closely match with Paleoproterozoic metagreywackes of Ghana of African craton while Punagarh sandstones show near geochemical characteristic with Gogunda, Kumbalgarh and Vindhyan quartzites of Aravalli craton. This geochemical similarity of Sojat sandstones provides credence to the hypothesis that Trans – Aravalli region of India had been an integral part of Arabian - Nubian shield. The chemical data advocate the deposition of these sandstones in a tectonic setting comparable to modern back arc setting.
The northern part of the Aravalli mountain belt of northwestern Indian shield is broadly composed of three Proterozoic volcano-sedimentary domains, i.e. the Bayana, the Alwar and the Khetri basins, comprising collectively the north Delhi fold belt. Major, trace and rare earth element concentrations of mafic volcanic rocks of the three basins exhibit considerable diversity. Bayana and Alwar volcanics are typical tholeiites showing close similarity with low Ti-continental flood basalts (CFB) with the difference that the former shows enriched and the latter flat incompatible trace element and rare earth element (REE) patterns. However, the Khetri volcanics exhibit a transitional composition between tholeiite and calc-alkaline basalts. It appears that the melts of Bayana and Alwar tholeiites were generated by partial melting of a common source within the spinel stability field possibly in the presence of mantle plume. During ascent to the surface the Bayana tholeiites suffered crustal contamination but the Alwar tholeiites erupted unaffected. Geochemically, the Khetri volcanics are arc-like basalts which were generated in a segment of mantle overlying a Proterozoic subduction zone. It is suggested that at about 1800 Ma the continental lithosphere in northeastern Rajasthan stretched, attenuated and fractured in response to a rising plume. The produced rifts have undergone variable degrees of crustal extension. The extension and attenuation of the crust facilitated shallowing of the asthenosphere which suffered variable degree of melting to produce tholeiitic melts -different batches of which underwent different degrees of lithospheric contamination depending upon the thickness of the crust in different rifted basins. The occurrence of subductionrelated basaltic rocks of Khetri Belt suggests that a basin on the western margin of the craton developed into a mature oceanic basin.
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