1NTRODUCTIONHafnium-based high-K dielectrics such as HfOz, HfON and HfSiON have attracted a great deal of attention because of their potential for successful integration into CMOS technology. However, channel mobility degradation, charge trapping and reliability are major concerns. In this paper, we will review our recent research results, namely, the charge trapping characteristics, the effects of nitrogen on minority carrier lifetime and channel mobility, and Hf-Ti-0 dielectrics. We have investigated how N affects the minority carrier lifetime in the Si substrate and how it relates to pcff. A new dielectric stack consists of TrOz/HfOz bilayer has shown improved thermal stability and increased K value (thus scaled EOT < I.0nm) without the disadvantages of incorporated N.
EXPERIMENTALMOSCAPs and MOSFETs (both n-channel and p-channel) with Hf02, HfO,N,, and HfSiON gate dielectrics deposited using PVD or ALD methods; and TaN, TiN or polysilicon gate electrodes have been fabricated (the detailed fabrication process can be found in [l-61). Also a bi-layer structure of TiOJHfOz multi-metal dielectrics have been formed by DC magnetron sputtering of hafnium and titanium targets in Ar ambient (more details are given below). Most of these dielectrics have undergone a post-deposition anneal (PDA) at -5OO'C immediately after the dielectric deposition; and a PMA (post-metal anneal ranging from 600-900T).
RESULTSA recent approach to achieve top nitridation of high-k dielectrics was via HfO,N, on the top of high-k dielectrics [7]. The application of HfON on top of HfOz was effective in suppressing the diffusion of both oxygen and dopant. But it was found that the incorporated N amount was so limited. In this work, HfSiON was applied on HfOz to achieve higher N concentration at the top of dielectrics while keeping higher mobility. The effects of top nitridation on MOSFET performance of high-k devices have been investigated. For the HfSiONiHfO? ("top silicon and nitrogen": Fig. 1) gate stack, a very thin HfSiON (-8 A) layer was formed on the top of HfOz (35-40 A) by co-sputtering Hf and Si in Ar/N2/02 ambient. For higher dielectric constant, the ratio of HfiSi was kept larger than 1 in the HfSiON process. This was followed by rapid-thermal annealing at 550-600°C in Nz for 20 sec. The MOS capacitors and N-MOSFETS were fabricated with TaN (-200 nm) gate electrodes by reactive sputtering. Conventional self-aligned process was used for transistors and deuterium annealing at 6OOoC for 20 min was done before AI metal deposition for better transistor performance. In short, this TSN ("Top-Silicon-Nitrogen" dielectrics ( Fig. 1)) is designed to put N near the top of the HfOz structure so that it can incorporate more N (because Si "traps" N and prevents N out-diffusion) and keeps the N away from the Si interface (N at the SI interface can degrade channel mobility).The Zerbst plots for various HfOz and nitrogen-incorporated HfOz MOSCAP are shown in Fig. 2, It shows that TaN gate devices resulted in reduced minority carrier lifetime in the ...
In the present literature survey, we focused on the performance of polymeric materials encompassing silicone rubber (SiR), ethylene propylene diene monomer (EPDM) and epoxy resins loaded with micro, nano, and micro/nano hybrid fillers. These insulators are termed as composite insulators. The scope of the added fillers/additives was limited to the synthetic inorganic family. Special attention was directed to understanding the effect of fillers on the improvement of the thermal conductivity, dielectric strength, mechanical strength, corona discharge resistance, and tracking and erosion resistance performance of polymeric materials for use as high-voltage transmission line insulators. The survey showed that synthetic inorganic fillers, which include silica (SiO2) and hexagonal boron nitride (h-BN), are potential fillers to improve insulation performance of high-voltage insulators. Furthermore, nano and micro/nano filled composites performed better due to the better interaction between the filler and polymer matrix as compared to their only micro- or nano filled counterparts. Finally, some aspects requiring future work to further exploit fillers are identified and discussed.
The development in materials technology has produced stronger, lighter, stiffer, and more durable electrically insulating composites which are replacing metals in many applications. These composites require alternative inspection techniques because the conventional nondestructive testing (NDT) techniques such as thermography, eddy currents, ultrasonic, X-ray and magnetic particles have limitations of inspecting them. Microwave NDT technique employing open-ended rectangular waveguides (OERW) has emerged as a promising approach to detect the defects in both metal and composite materials. Despite its promising results over conventional NDT techniques, OERW microwave NDT technique has shown numerous limitations in terms of poor spatial resolution due to the stand-off distance variations, inspection area irregularities and quantitative estimation in imaging the size of defects. Microwave NDT employing OERW in conjunction with robust artificial intelligence approaches have tremendous potential and viability for evaluating composite structures for the purpose mentioned here. Artificial intelligence techniques with signal processing techniques are highly possible to enhance the efficiency and resolution of microwave NDT technique because the impact of artificial intelligence approaches is proven in various conventional NDT techniques. This paper provides a comprehensive review of NDT techniques as well as the prospect of using artificial intelligence approaches in microwave NDT technique with regards to other conventional NDT techniques. INDEX TERMS Microwave nondestructive testing, open-ended rectangular waveguides, artificial intelligence.
Electrical and chemical characteristics of metal-oxide semiconductor field-effect transistors (MOSFETs) prepared by low-thermal-budget (∼600 °C) NH3 post-deposition annealing of HfSiON gate dielectric have been investigated. Compared to control Hf-silicate, HfSiON showed excellent thickness scalability, low leakage current density (J), and superior thermal stability. With proper annealing-time optimization, effective oxide thickness as low as 9.2 Å with J<100 mA/cm2 at gate voltage Vg=−1.5 V has been achieved. C–V hysteresis of HfSiON MOSFET was found to be small (<20 mV). Unlike NH3 surface nitridation (NH3 pre-treatment prior to Hf-silicate deposition), no degradation in Gm (transconductance), Id–Vg (drain current–gate voltage), or Id–Vd (drain current–drain voltage) characteristics has been observed.
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