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Study of the perovskite-type manganites Ca1 - x Ce x MnO3 (0.00 ≤ x ≤ 0.25) has been carried out. The electrical resistivity values for these samples were measured in the temperature range from 300 up to 900 K and show that the doping of the phase CaMnO3 with cerium induces simultaneously a marked decrease in the electrical resistivity and a metal-to-insulator transition. This behavior is exceptional since such a transition has not been observed to date in these compounds for these experimental conditions and can be attributed to the formation of Mn3+ ions as a result of charge compensation. The values of metal-to-insulator transition temperature, T MI, change with Mn3+ amount. Further the carrier doping tends to suppress the semiconductor behavior of CaMnO3 and the T MI is attributed to charge ordering observed in these compounds around 255 K.

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