Abstract. An approach for detecting hazardous volatile organic compounds (VOCs) in ppb and sub-ppb concentrations is presented. Using three types of metal oxide semiconductor (MOS) gas sensors in temperature cycled operation, formaldehyde, benzene and naphthalene in trace concentrations, reflecting threshold limit values as proposed by the WHO and European national health institutions, are successfully identified against a varying ethanol background of up to 2 ppm. For signal processing, linear discriminant analysis is applied to single sensor data and sensor fusion data.Integrated field test sensor systems for monitoring of indoor air quality (IAQ) using the same types of gas sensors were characterized using the same gas measurement setup and data processing. Performance of the systems is reduced due to gas emissions from the hardware components. These contaminations have been investigated using analytical methods. Despite the reduced sensitivity, concentrations of the target VOCs in the ppb range (100 ppb of formaldehyde; 5 ppb of benzene; 20 ppb of naphthalene) are still clearly detectable with the systems, especially when using the sensor fusion method for combining data of the different MOS sensor types.

No abstract

Abstract:Monitoring of volatile organic compounds (VOCs) is of increasing importance in many application fields such as environmental monitoring, indoor air quality, industrial safety, fire detection, and health applications. The challenges in all of these applications are the wide variety and low concentrations of target molecules combined with the complex matrix containing many inorganic and organic interferents. This paper will give an overview over the application fields and address the requirements, pitfalls, and possible solutions for using low-cost sensor systems for VOC monitoring. The focus lies on highly sensitive metal oxide semiconductor gas sensors, which show very high sensitivity, but normally lack selectivity required for targeting relevant VOC monitoring applications. In addition to providing an overview of methods to increase the selectivity, especially virtual multisensors achieved with dynamic operation, and boost the sensitivity further via novel pro-concentrator concepts, we will also address the requirement for high-performance gas test systems, advanced solutions for operating and read-out electronic, and, finally, a cost-efficient factory and on-site calibration. The various methods will be primarily discussed in the context of requirements for monitoring of indoor air quality, but can equally be applied for environmental monitoring and other fields.

This article presents a test gas generation system designed to generate ppb level gas concentrations from gas cylinders. The focus is on permanent gases and volatile organic compounds (VOCs) for applications like indoor and outdoor air quality monitoring or breath analysis. In the design and the setup of the system, several issues regarding handling of trace gas concentrations have been considered, addressed and tested. This concerns not only the active fluidic components (flow controllers, valves), which have been chosen specifically for the task, but also the design of the fluidic tubing regarding dead volumes and delay times, which have been simulated for the chosen setup. Different tubing materials have been tested for their adsorption/desorption characteristics regarding naphthalene, a highly relevant gas for indoor air quality monitoring, which has generated high gas exchange times in a previous gas mixing system due to long time adsorption/desorption effects. Residual gas contaminations of the system and the selected carrier air supply have been detected and quantified using both an analytical method (GC-MS analysis according to ISO 16000-6) and a metal oxide semiconductor gas sensor, which detected a maximum contamination equivalent to 28 ppb of carbon monoxide. A measurement strategy for suppressing even this contamination has been devised, which allows the system to be used for gas sensor and gas sensor system characterization and calibration in the low ppb concentration range.

No abstract