In this paper, ferroelectric antimony sulfoiodide (SbSI) nanowires have been used to produce composites for device fabrication, which can be used for energy harvesting and sensors. SbSI is a very useful material for nanogenerators and nanosensors in which the high values of the piezoelectric coefficient (d33 = 650 pC/N) and the electromechanical coefficient (k33 = 0.9) are essential. Alternatively, cellulose and epoxy resin were matrix materials in these composites, whereas SbSI nanowires fill the matrix. Piezoelectric response induced by vibrations has been presented. Then, a composite with an epoxy resin has been used as an element to construct a fiber-reinforced polymer piezoelectric sensor. For the first time, comparison of piezoelectric properties of cellulose/SbSI and epoxy resin/SbSI nanocomposite has been presented. The influence of concentration of SbSI nanowires for properties of epoxy resin/SbSI nanocomposite and in a fiber-reinforced polymer based on them has also been shown. Results of aligning the SbSI nanowires in the epoxy matrix during a curing process have been presented as well.
The paper presents a comparison of the test results for the fiber volume fraction, static bending and Charpy impact strength of glass fiber reinforced polymer laminates reinforced by 0/90 fabric and chopped strand mat, produced by the hand lay-up and the vacuum-assisted resin infusion (VARI) method. The laminates were produced under equivalent conditions, with polyester matrix and lay-up areal mass 2100 g/m2. In the comparison of the obtained measurement results, similar mechanical performance was stated in the case of the hand lay-up and the VARI production. However, significantly smaller scatter of results and better uniformity of the reinforcement in the matrix with smaller amount of local structure defects was observed for the samples obtained by VARI method. The laminates obtained by VARI method show a much more advantageous coefficient of variation than that of the hand lay-up method, especially in the case of the mat reinforcement.
This paper shows a piezoelectric response from an innovative sensor obtained by casting epoxy-SbSI (antimony sulfoiodide) nanowires nanocomposite to a grid structure printed using a fuse deposition modeling (FDM) method. The grid is shown to be a support structure for the nanocomposite. The applied design approach prospectively enables the formation of sensors with a wide spectrum of shapes and a wide applicability. The voltage signal obtained as a result of the piezoelectric effect reached 1.5V and 0.5V under a maximum static stress of 8.5 MPa and under a maximum dynamic stress of 22.3 kPa, respectively. These values are sufficient for potential application in sensor systems. The effect of a systematic increase in the voltage signal with subsequent cycles was also observed, which similarly allows the use of these sensors in monitoring systems for structures exposed to unfavorable cyclical loads. The obtained results also show that the piezoelectric signal improves with increase in strain rate.
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