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+ n-alkane mixtures at 298.15 K from density and volumetric heat capacity measurements using liquid-flow techniques. The alkanoates selected were n-propyl methanoate, methyl ethanoate, ethyl ethanoate, methyl propanoate, methyl butanoate, methyl pentanoate, and methyl octanoate. p are positive for all systems and rather symmetric. The composition dependence of C; is typically of the o-shaped type with two minima, more or less pronounced, which are separated by a positive part in the case of the more polar esters, i.e. n-propyl methanoate and methyl ethanoate. These results are discussed in terms of possible changes in conformation of both the ester and the n-alkane.