We report a detection of methane in the martian atmosphere by the Planetary Fourier Spectrometer onboard the Mars Express spacecraft. The global average methane mixing ratio is found to be 10 +/- 5 parts per billion by volume (ppbv). However, the mixing ratio varies between 0 and 30 ppbv over the planet. The source of methane could be either biogenic or nonbiogenic, including past or present subsurface microorganisms, hydrothermal activity, or cometary impacts.

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The NOMAD ("Nadir and Occultation for MArs Discovery") spectrometer suite on board the ExoMars Trace Gas Orbiter (TGO) has been designed to investigate the comThis paper is dedicated to the memory of M. Allen, V. Formisano, and J. McConnell. position of Mars' atmosphere, with a particular focus on trace gases, clouds and dust. The detection sensitivity for trace gases is considerably improved compared to previous Mars missions, compliant with the science objectives of the TGO mission. This will allow for a major leap in our knowledge and understanding of the Martian atmospheric composition and the related physical and chemical processes. The instrument is a combination of three spectrometers, covering a spectral range from the UV to the mid-IR, and can perform solar occultation, nadir and limb observations. In this paper, we present the science objectives of the instrument and explain the technical principles of the three spectrometers. We also discuss the expected performance of the instrument in terms of spatial and temporal coverage and detection sensitivity.

We present the seasonal and geographical variations of the Martian water vapor monitored from the Planetary Fourier Spectrometer Long Wavelength Channel aboard the Mars Express spacecraft. Our dataset covers one Martian year (end of Mars Year 26, Mars Year 27), but the seasonal coverage is far from complete. The seasonal and latitudinal behavior of the water vapor is globally consistent with previous datasets, Viking Orbiter Mars Atmospheric Water Detectors (MAWD) and Mars Global Surveyor Thermal Emission Spectrometer (MGS/TES), and with simultaneous results obtained from other Mars Express instruments, OMEGA and SPICAM. However, our absolute water columns are lower and higher by a factor of 1.5 than the values obtained by TES and SPICAM respectively. In particular, we retrieve a northern midsummer maximum of 60 pr-μm, lower than the 100-pr-μm observed by TES. The geographical distribution of water exhibits two local maxima at low latitudes, located over Tharsis and Arabia. Global Climate Model (GCM) simulations suggest that these local enhacements are controlled by atmospheric dynamics. During Northern spring, we observe a bulge of water vapor over the seasonal polar cap edge, consistent with the northward transport of water from the retreating seasonal cap to the permanent polar cap. In terms of vertical distribution, we find that the water volume mixing ratio over the large volcanos remains constant with the surface altitude within a factor of two. However, on the whole dataset we find that the water column, normalized to a fixed pressure, is anti-correlated with the surface pressure, indicating a vertical distribution intermediate between control by atmospheric saturation and confinement to a surface layer. This anti-correlation is not reproduced by GCM simulations of the water cycle, which do not include exchange between atmospheric and subsurface water. This situation suggests a possible role for regolith-atmosphere exchange in the Martian water cycle.

The Nadir and Occultation for MArs Discovery (NOMAD) instrument on board ExoMars Trace Gas Orbiter measured a large increase in water vapor at altitudes in the range of 40-100 km during the 2018 global dust storm on Mars. Using a three-dimensional general circulation model, we examine the mechanism responsible for the enhancement of water vapor in the upper atmosphere. Experiments with different prescribed vertical profiles of dust show that when more dust is present higher in the atmosphere, the temperature increases, and the amount of water ascending over the tropics is not limited by saturation until reaching heights of 70-100 km. The warmer temperatures allow more water to ascend to the mesosphere. Photochemical simulations show a strong increase in high-altitude atomic hydrogen following the high-altitude water vapor increase by a few days. Plain Language Summary The ExoMars Trace Gas Orbiter (TGO) is currently in orbit aroundMars measuring the composition of the atmosphere. TGO was able to make observations before, during, and after a large planet-encircling dust storm that occurred from June to August 2018. The TGO measurements provide the first opportunity to observe how water vapor is distributed with height in the atmosphere during a global-scale dust event. It was found that there was a large increase in water vapor very high (40-100 km) in the atmosphere during the dust storm. Using a three-dimensional numerical model of the Mars atmosphere, we found that when dust from the storm is transported up to levels above~40 km, it warms the atmosphere due to solar absorption, and this in turn prevents ice clouds from forming at heights of 40-60 km and allows more water vapor to ascend to greater heights in the atmosphere. This is of interest in terms of the planetary evolution, as water molecules at greater heights are more readily dissociated by sunlight and lost from the atmosphere. This is an important factor for understanding the changes that have occurred since the period when surface features on Mars indicate that liquid water was present.

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The NOMAD spectrometer suite on the ExoMars Trace Gas Orbiter will map the composition and distribution of Mars’atmospheric trace species in unprecedented detail, fulfilling many of the scientific objectives of the joint ESA-Roscosmos ExoMars Trace Gas Orbiter mission. The instrument is a combination of three channels, covering a spectral range from the UV to the IR, and can perform solar occultation, nadir and limb observations. In this paper, we present the science objectives of the instrument and how these objectives have influenced the design of the channels. We also discuss the expected performance of the instrument in terms of coverage and detection sensitivity