We report a detection of methane in the martian atmosphere by the Planetary Fourier Spectrometer onboard the Mars Express spacecraft. The global average methane mixing ratio is found to be 10 +/- 5 parts per billion by volume (ppbv). However, the mixing ratio varies between 0 and 30 ppbv over the planet. The source of methane could be either biogenic or nonbiogenic, including past or present subsurface microorganisms, hydrothermal activity, or cometary impacts.

Heat transport and ice sublimation in comets are interrelated processes reflecting properties acquired at the time of formation and during subsequent evolution. The Microwave Instrument on the Rosetta Orbiter (MIRO) acquired maps of the subsurface temperature of comet 67P/Churyumov-Gerasimenko, at 1.6 mm and 0.5 mm wavelengths, and spectra of water vapor. The total H2O production rate varied from 0.3 kg s(-1) in early June 2014 to 1.2 kg s(-1) in late August and showed periodic variations related to nucleus rotation and shape. Water outgassing was localized to the "neck" region of the comet. Subsurface temperatures showed seasonal and diurnal variations, which indicated that the submillimeter radiation originated at depths comparable to the diurnal thermal skin depth. A low thermal inertia (~10 to 50 J K(-1) m(-2) s(-0.5)), consistent with a thermally insulating powdered surface, is inferred.

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The Atmospheric Chemistry Suite (ACS) package is an element of the Russian contribution to the ESA-Roscosmos ExoMars 2016 Trace Gas Orbiter (TGO) mission. ACS consists of three separate infrared spectrometers, sharing common mechanical, electrical, and thermal interfaces. This ensemble of spectrometers has been designed and developed in response to the Trace Gas Orbiter mission objectives that specifically address the requirement of high sensitivity instruments to enable the unambiguous detection of trace gases of potential geophysical or biological interest. For this reason, ACS embarks a set of instruments achieving simultaneously very high accuracy (ppt level), very high resolving power (>10,000) and large spectral coverage (0.7 to 17 µm-the visible to thermal infrared range). The near-infrared (NIR) channel is a versatile spectrometer covering the 0.7-1.6 µm spectral range with a resolving power of ∼20,000. NIR employs the combination of an echelle grating with an AOTF (Acousto-Optical Tunable Filter) as diffraction order selector. This channel will be mainly operated in solar occultation and nadir, and can also perform limb observations. The scientific goals of NIR are the measurements of water vapor, aerosols, and dayside or night side airglows. The mid-infrared (MIR) channel is a cross-dispersion echelle instrument dedicated to solar occultation measurements in the 2.2-4.4 µm range. MIR achieves a resolving power of >50,000. It has been designed to accomplish the most sensitive measurements ever of the trace gases present in the Martian atmosphere. The thermal-infrared channel (TIRVIM) is a 2-inch double pendulum Fourier-transform spectrometer encompassing the spectral range of 1.7-17 µm with apodized resolution varying from 0.2 to 1.3 cm −1 . TIRVIM is primarily dedicated to profiling temperature from the surface up to ∼60 km and to monitor aerosol abundance in nadir. TIRVIM also has a limb and solar occultation capability. The technical concept of the instrument, its accommodation on the spacecraft, the optical designs as well as some of the calibrations, and the expected performances for its three channels are described.

Hydrogen radicals are produced in the martian atmosphere by the photolysis of water vapour and subsequently initiate catalytic cycles that recycle carbon dioxide from its photolysis product carbon monoxide. These processes provide a qualitative explanation for the stability of the atmosphere of Mars, which contains 95 per cent carbon dioxide. Balancing carbon dioxide production and loss based on our current understanding of the gas-phase chemistry in the martian atmosphere has, however, proven to be difficult. Interactions between gaseous chemical species and ice cloud particles have been shown to be key factors in the loss of polar ozone observed in the Earth's stratosphere, and may significantly perturb the chemistry of the Earth's upper troposphere. Water-ice clouds are also commonly observed in the atmosphere of Mars and it has been suggested previously that heterogeneous chemistry could have an important impact on the composition of the martian atmosphere. Here we use a state-of-the-art general circulation model together with new observations of the martian ozone layer to show that model simulations that include chemical reactions occurring on ice clouds lead to much improved quantitative agreement with observed martian ozone levels in comparison with model simulations based on gas-phase chemistry alone. Ozone is readily destroyed by hydrogen radicals and is therefore a sensitive tracer of the chemistry that regulates the atmosphere of Mars. Our results suggest that heterogeneous chemistry on ice clouds plays an important role in controlling the stability and composition of the martian atmosphere.

Aims. Disk-averaged infrared spectra of Neptune between 1.8 and 13 μm, obtained by the AKARI infrared camera (IRC) in May 2007, have been analysed to (a) determine the globally-averaged stratospheric temperature structure; (b) derive the abundances of stratospheric hydrocarbons; and (c) detect fluorescent emission from CO at 4.7 μm. Methods. Mid-infrared spectra (SG1 and SG2 channels of AKARI/IRC), with spectral resolutions of 47 and 34 respectively, were modelled using a line-by-line radiative transfer code to determine the temperature structure between 1-1000 μbar and the abundances of CH 4 , CH 3 D and higher-order hydrocarbons. A full non-LTE radiative model was then used to determine the best fitting CO profile to reproduce the fluorescent emission observed at 4.7 μm in the NG channel (with a spectral resolution of 135). Results. The globally-averaged stratospheric temperature structure is quasi-isothermal between 1-1000 μbar, which suggests little variation in global stratospheric conditions since studies by the Infrared Space Observatory a decade earlier. The derived CH 4 mole fraction of (9.0 ± 3.0) × 10 −4 at 50 mbar, decreasing to (0.9 ± 0.3) × 10 −4 at 1 μbar, is larger than that expected if the tropopause at 56 K acts as an efficient cold trap, but consistent with the hypothesis that CH 4 leaking through the warm south polar tropopause (62-66 K) is globally redistributed by stratospheric motion. The ratio of D/H in CH 4 of 3.0 ± 1.0 × 10 −4 supports the conclusion that Neptune is enriched in deuterium relative to the other giant planets. We determine a mole fraction of ethane of (8.5 ± 2.1) × 10 −7 at 0.3 mbar, consistent with previous studies, and a mole fraction of ethylene of 5.0 +1.8 −2.1 × 10 −7 at 2.8 μbar. An emission peak at 4.7 μm is interpreted as a fluorescent emission of CO, and requires a vertical distribution with both external and internal sources of CO. Finally, comparisons to previous L-band studies indicate significant variability of Neptune's flux densities in the 3.5-4.1 μm range, related to changes in solar energy deposition.

We report the Ðrst detection of the methyl radical in the upper atmosphere of Neptune. Obser-(CH 3 ) vations with the Short-Wavelength Spectrometer of the Infrared Space Observatory (ISO) satellite at a resolving power of 2200 revealed several emission features from the Q-branch of around 16.50 l 2 CH 3 km. The column density of methyl radicals above the 0.2 mbar level is molecules cm~2. 1.6~0 .91.2 ] 1013 Results are compared with predictions of photochemical models. The abundance is mostly sensitive CH 3 to the eddy mixing proÐle and to the poorly known methyl recombination rate at low pressure. Using Slagle et al.Ïs expression for this rate, the present observations imply an eddy mixing coefficient at the methane homopause in the range of 2È9 ] 106 cm2 s~1. Recombination rates higher than used in current photochemical models would lead to larger eddy mixing coefficients.

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