The effect of exposure to high temperature on rock strength is a topic of interest in many engineering fields. In general, rock strength is known to decrease as temperature increases. The most common test used to evaluate the rock strength is the uniaxial compressive strength test (UCS). It can only be carried out in laboratory and presents some limitations in terms of the number, type and preparation of the samples. Such constrains are more evident in case of rocks from historical monuments affected by a fire, where the availability of samples is limited. There are alternatives for an indirect determination of UCS, such as the point load test (PLT), or non-destructive tests such as the Schmidt’s hammer, that can also be performed in situ. The aims of this research are: (i) measuring the effect of high temperatures and cooling methods on the strength and hardness of a limestone named Pedra de Borriol widely used in several historic buildings on the E of Spain, and (ii) studying the possibility of indirectly obtaining UCS by means of PLT and Leeb hardness tests (LHT), using Equotip type D. Limestone samples were heated to 105 (standard conditions), 200, 300, 400, 500, 600, 700, 800 and 900 ºC and cooled slowly (in air) and quickly (immersed in water). After that, UCS, PLT and LHT tests were performed to evaluate the changes as temperature increases. Results show decreases over 90% in UCS, of between 50 and 70% in PLT index and smaller than 60% in LHT index. Insignificant differences between cooling methods were observed, although slowly cooled samples provide slightly higher values than quickly cooled ones. The results indicate that LHT can be used to indirectly estimate UCS, providing an acceptable prediction. Research on correlating strength parameters in rocks after thermally treated is still scarce. This research novelty provides correlations to predict UCS in historic buildings if affected by a fire, from PLT and non-destructive methods such as LHT whose determination is quicker and easier.

Temperature and cooling methods strongly affect the stability of tunnels drilled in rock masses and so condition interventions for fire emergencies. Samples from two horizontal boreholes drilled in 'Prada' limestone during the design stage of the Tres Ponts Tunnel in the Catalan south Pyrenean zone (Spain) are heated from 105 to 600º C, and subsequently cooled with air or water to simulate fire extinguishing interventions. Changes in chemical composition and microstructure, physical properties (open porosity, volume, dry total weight, P and S-wave velocity), and mechanical properties (uniaxial compressive strength, elastic modulus, and Poisson's ratio) are analysed. Rock weakening is observed even at low temperatures (T<300º C). The influence of the cooling method appeared at intermediate temperatures of 300-400º C and open porosity, P and S-wave velocities, and elastic modulus show greater variation for water-cooled samples. A temperature of 500º C is of paramount importance for 'Prada' limestone as it leads to a dramatic increase in porosity and a notable decrease in P and S-wave velocities under both cooling methods. Trans-granular micro-crack progression is observed at 500º C using scanning electron microscope (SEM), and water-cooled samples show a greater loss in uniaxial compressive strength (UCS), and this is due to micro-crack connections and growing fissures. Thermal damage at 600º C is also greater when samples are quickly cooled. An ANOVA and a simple regression analysis are performed to discard the influence of the natural location of the borehole samples in the obtained experimental results. Finally, correlations to predict UCS and elastic modulus from volume, open porosity, and P-wave velocity after thermal treatment are proposed using simple exponential and potential functions to help make preliminary decisions after a tunnel fire. These predictive results on the effects of fire on Prada limestone will be considered for the definition of future fire intervention protocols in the Tres Ponts Tunnel.

In this investigation, two different varieties of 'Prada' limestones were studied: a dark grey texture, bearing quartz, clay minerals, organic matter and pyrites, and a light grey texture with little or no presence of such components. We have observed two effects of different intensity when heating the dark texture from 400º C: i) the explosion of certain samples and ii) greater thermal damage than in the light grey texture. Chemical and mineralogical composition, texture, microstructure, and physical properties (i.e. colour, open porosity, P and S-wave velocity) have been evaluated at temperatures of 105, 300, 400 and 500º C in order to identify differences between textures. The violence of the explosive events was clear and cannot be confounded with ordinary splitting and cracking on thermally-treated rocks: exploded samples underwent a total loss of integrity, displacing and overturning the surrounding samples, and embedding fragments in the walls of the furnace, whose impacts were clearly heard in the laboratory. Thermogravimetric results allowed the identification of a process of oxidation of pyrites releasing SO 2 from 400º C. This process jointly with the presence of micro-fissures in the 2 dark texture, would cause a dramatic increase in pore-pressure, leading to a rapid growth and coalescence of microcracks that leads to a process of catastrophic decay in rock integrity. In addition to the explosive events, average ultrasound velocities and open porosity showed a greater variation in the dark grey texture from 400º C. That results also points towards a significant contribution of oxidation of pyrites on the thermochemical damage of the rock, among other factors such as the pre-existence of microfissuresand the thermal expansion coefficient mismatch between minerals. Implications in underground infrastructure and mining engineering works are critical, as the explosive potential of pyrite-bearing limestones bear risk for mass fracturing and dramatic strength decay from 400º C. Moreover, SO 2 released has harmful effects on health of people and the potential to form acid compounds that corrode materials, shortening their durability and increasing maintenance costs.

This work evaluates the effect of high temperatures and cooling methods on the drillability of Prada limestone. Samples from boreholes drilled during the design stage of the Tres Ponts Tunnel in the Catalan south Pyrenean zone (Spain) were subjected to temperatures of 105, 200, 300, 400, and 600 °C, and then cooled at a slow rate or by quenching. Sievers’ J-value (SJ) and brittleness (S20) were determined on thermally treated samples, and the drilling rate index (DRI) was calculated for each temperature. The results show that thermal treatment implied a sustained increase in the drillability of the rock of up to 40% at 600 °C and a change in the drillability category (from medium to high). At 600 °C, SJ and S20 tripled and doubled, respectively, the initial values obtained for the intact rock. The results were inconclusive about the influence of the cooling method on the drilling performance of Prada limestone for the tested range of temperatures. The substantial improvement observed in the drillability of Prada limestone when heated, measured in terms of DRI, could help in the development of novel thermally-assisted mechanical excavation methods. Additionally, strong correlations between drillability variables (i.e., SJ and S20) and physical and mechanical variables of Prada limestone (i.e., P- and S-wave velocities, uniaxial compression strength, elastic modulus, and Poisson’s ratio) are proposed. Correlations will help make preliminary predictions of drillability based on properties such as uniaxial compression strength and ultrasound wave velocities.

The determination of static elastic modulus in the laboratory requires rock core extraction and the subsequent testing of the samples by means of standardised uniaxial compressive strength tests. However, this destructive procedure is not always suitable – as in the case of protected historic buildings. In these cases, the static elastic modulus can be obtained from the dynamic elastic modulus, in turn derived from the velocity of ultrasonic waves (a non-invasive and non-destructive test). The relationship between both the dynamic and static moduli of rocks has been extensively addressed in the scientific literature. Furthermore, several researchers have separately studied the evolution of static or dynamic elastic moduli of rocks exposed to high temperatures – although few studies have compared both values. It is well known that the dynamic modulus is generally higher than the static modulus, and the values diverge especially in rocks with a low modulus of elasticity. These differences can be mainly explained by the effect of porosity and the size of cracks in the determination of both parameters. In this research, the relationship between static and dynamic moduli for ‘Borriol’ limestone is studied for samples previously subjected to 200, 400, 600 and 800 °C and then cooled slowly (in air) or quickly (immersed in water). The results show that the static modulus of samples heated up to 600 °C decreased 80.9 and 79.1 % and dynamic modulus decreased 62.5 and 64.8 % for slow and quick cooling samples, respectively. For samples heated to 600 and 800 °C, the static and dynamic moduli are similar. In general, no significant differences between both cooling methods are observed, even though static modulus shows more loss than dynamic modulus. Finally, linear models were used to correlate static and dynamic moduli, providing coefficients of determination of 0.99 and 0.97, for slow and quick cooling, respectively. It is also remarkable that the Edyn/Est rate was smaller than 1 for elastic moduli over 30 GPa (i.e., 105, 200 and 400 °C) and greater than 1 for lower moduli (i.e., 600 and 800 °C). The results obtained can be used to calculate the static elastic modulus of ‘Borriol’ limestone from dynamic modulus determined by non-destructive techniques.