This study investigates transformations of a pre-mechanically activated saponite-containing material with subsequent high-temperature treatment. The thermogravimetric analysis confirmed that the mechanical activation of saponite leads to the destruction of its layered structure, accompanied by the release of silicon dioxide and magnesium oxide in free form. The values of surface activity for mechanically activated saponite-containing material are also calculated. It is shown that when mechanically activated saponite-containing material is mixed with water, minerals of the serpentine group are formed, and further high-temperature treatment leads to the formation of minerals of the olivine group. It is experimentally shown that high-temperature treatment leads to the creation of a more durable structure of the saponite-containing material. This is due to decreased porosity and pore size, and sorption of moisture from the environment is also reduced. The study showed that saponite-containing waste materials can be effectively treated to create composite materials based on magnesia binders. Thus, with this method, the waste is effectively recycled into various green building material and can be used as supplementary cementitious material or fine aggregate replacement in concrete.
This paper discusses some of the major environmental problems of North-Arctic region. It has been proposed to use provisions of Architectural geonics and "green" composite compounds with nanodisperse organic mineral additive to improve the ecological situation in the region and enhance the effectiveness of the "Man-Material-Habitat" system.
the paper shows the possibility of producing a thermal insulating composite based on basalt fibers and sapo-nite-containing mining waste. A method for manufacturing thermal insulating composites from hydro-mass with different contents of the mixture components is proposed. Basalt fibers were used as a filler, and pre-mechanoactivated saponite-containing material (SCM) was used as a binder. It was found experimentally that depending on the composition of composites, the coefficient of thermal conductivity varies from 0.1109 to 0.1342 W/(m•K), and the compressive strength – from 0.45 to 0.93 MPa. In addition, it was found that thermal modification of composites at temperatures up to 1200°C significantly (up to 3 times) increases the compressive strength of composites, while not affecting the coefficient of thermal conductivity. The ex-periments to determine the conductivity of the composite “basalt fiber – SСM” depending on its moisture content showed that the obtained composite is characterized by intense and linear increase in the values of conductivity when the humidity of the sample to 12% and further increase in humidity practically does not change the values of the coefficient of thermal conductivity. Comparison of the studied thermal insulation composite with known structural thermal insulation materials in terms of its thermal insulation and strength characteristics showed that it is comparable to gas and foam blocks. It should also be noted that this material is environmentally safe and can withstand high temperatures without collapsing.
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