Water, when confined at the nanoscale acquires extraordinary transport properties, and yet, there is no direct experimental evidence of these properties at nanoscale resolution. Here, by using two-dimensional NMR diffusion–relaxation (D–T 2) and spin–lattice – spin–spin relaxation (T 1–T 2) spectroscopy, we succeeded to resolve at the nanoscale water diffusion in single- and double-walled carbon nanotubes (SWCNTs/DWCNTs). In SWCNTs, the spectra display the characteristic shape of uniform water diffusion restricted in one dimension. Remarkably, in DWCNTs, water is shown to split into two axial components with the inner one acquiring unusual flow properties: high fragility, ultrafast self-diffusion coefficient, and “rigid” molecular environment, revealing a stratified cooperative motion mechanism to underlie fast diffusion in water-saturated CNTs.

It is well known that water inside hydrophobic nano-channels diffuses faster than bulk water. Recent theoretical studies have shown that this enhancement depends on the size of the hydrophobic nanochannels. However, experimental evidence of this dependence is lacking. Here, by combining two-dimensional nuclear magnetic resonance diffusion–relaxation (D–T2eff) spectroscopy in the stray field of a superconducting magnet and molecular dynamics simulations, we analyze the size dependence of water dynamics inside Carbon Nanotubes (CNTs) of different diameters (1.1–6.0 nm), in the temperature range of 265–305 K. Depending on the CNT diameter, the nanotube water is shown to resolve in two or more tubular components acquiring different self-diffusion coefficients. Most notably, a favorable CNT diameter range (3.0–4.5 nm) is experimentally verified for the first time, in which water molecule dynamics at the center of the CNTs exhibits distinctly non-Arrhenius behavior, characterized by ultrafast diffusion and extraordinary fragility, a result of significant importance in the efforts to understand water behavior in hydrophobic nanochannels.

Underwater optical wireless communications (UOWC) have gained a considerable interest during the last years as an alternative means for broadband inexpensive submarine communications. UOWC present numerous similarities compared to free space optical (FSO) communications or laser satellite links mainly due to the fact that they employ optical wavelengths to transfer secure information between dedicated point-to-point links. By using suitable wavelengths, high data rates can be attained. Some recent works showed that broadband links can be achieved over moderate ranges. Transmissions of several Mbps have been realized in laboratory experiments by employing a simulated aquatic medium with scattering characteristics similar to oceanic waters. It was also demonstrated that UOWC networks are feasible to operate at high data rates for medium distances up to a hundred meters. However, it is not currently available as an industrial product and mainly test-bed measurements in water test tanks have been reported so far. Therefore, extensive research is expected in the near future, which is necessary in order to further reveal the "hidden" abilities of optical spectrum to transfer broadband signals at higher distances. The present work summarizes the recent advances in channel modeling and system analysis and design in the area of UOWC.

Molecular motion in nanosized channels can be highly complicated. For example, water molecules in ultranarrow hydrophobic nanopores move rapidly and coherently in a single file, whereas by increasing the pore size they organize into coaxial tubes, displaying stratified diffusion. Interestingly, an analogous complex motion is predicted in viscous charged fluids, such as room temperature ionic liquids (RTILs) confined in nanoporous carbon or silica; however, experimental evidence is still pending. Here, by combining 1H NMR diffusion experiments in different relaxation windows with molecular dynamics simulations, we show that the imidazolium-based RTIL [BMIM]+[TCM]−, entrapped in the MCM-41 silica nanopores, exhibits an intricate dynamic molecular ordering; adsorbed RTIL molecules form a fluctuating charged layer near the pore walls, while in the bulk pore space they diffuse discretely in coaxial tubular shells, with molecular mean square displacement following a nearly ∼τ0.5 time dependence, characteristic of single file diffusion.

A combined experimental and computational approach was used to distinguish between different polymorphs of the pharmaceutical drug aspirin. This method involves the use of ab initio random structure searching (AIRSS), a density functional theory (DFT)-based crystal structure prediction method for the high-accuracy prediction of polymorphic structures, with DFT calculations of nuclear magnetic resonance (NMR) parameters and solid-state NMR experiments at natural abundance. AIRSS was used to predict the crystal structures of form-I and form-II of aspirin. The root-mean-square deviation between experimental and calculated 1 H chemical shifts was used to identify form-I as the polymorph present in the experimental sample, the selection being successful despite the large similarities between the molecular environments in the crystals of the two polymorphs.

Cross-linked polyethylene (XLPE) and silicone rubber (SiR) samples were subjected to a high-voltage AC stress plane-plane configuration and inclined plane test, respectively. The voltage was applied such that discharge was observed across the surface of the XLPE test sample for several hours and for visible damage to occur on SiR samples also after several hours. Selected stressed samples together with virgin samples from the same manufactured batch were tested using nuclear magnetic resonance (NMR) spectroscopy. Specifically, 1 H NMR spin-lattice (T 1) and spin-spin (T 2) relaxation time measurements were employed to examine potential changes in the chemical bonding of undamaged and damaged XLPE and SiR samples. Preliminary results show that there may be a moderate increase in the T 1 and T 2 values of the damaged samples in comparison with the undamaged ones. This raises the possibility that NMR can be a useful additional experimental tool in characterising material degradation.

Confined liquids are model systems for the study of the metastable supercooled state, especially for bulk water, in which the onset of crystallization below 230 K hinders the application of experimental techniques. Nevertheless, in addition to suppressing crystallization, confinement at the nanoscale drastically alters the properties of water. Evidently, the behavior of confined water depends critically on the nature of the confining environment and the interactions of confined water molecules with the confining matrix. A comparative study of the dynamics of water under hydrophobic and hydrophilic confinement could therefore help to clarify the underlying interactions. As we demonstrate in this work using a few representative results from the relevant literature, the accurate assessment of the translational mobility of water molecules, especially in the supercooled state, can unmistakably distinguish between the hydrophilic and hydrophobic nature of the confining environments. Among the numerous experimental methods currently available, we selected nuclear magnetic resonance (NMR) in a field gradient, which directly measures the macroscopic translational self-diffusion coefficient, and quasi-elastic neutron scattering (QENS), which can determine the microscopic translational dynamics of the water molecules. Dielectric relaxation, which probes the re-orientational degrees of freedom, are also discussed.

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