Tremendous efforts have been devoted to the development of electrode materials, electrolytes, and separators of energy-storage devices to address the fundamental needs of emerging technologies such as electric vehicles, artificial intelligence, and virtual reality. However, binders, as an important component of energy-storage devices, are yet to receive similar attention. Polyvinylidene fluoride (PVDF) has been the dominant binder in the battery industry for decades despite several well-recognized drawbacks, i.e., limited binding strength due to the lack of chemical bonds with electroactive materials, insufficient mechanical properties, and low electronic and lithium-ion conductivities. The limited binding function cannot meet inherent demands of emerging electrode materials with high capacities such as silicon anodes and sulfur cathodes. To address these concerns, in this review we divide the binding between active materials and binders into two major mechanisms: mechanical interlocking and interfacial binding forces. We review existing and emerging binders, binding technology used in energy-storage devices (including lithium-ion batteries, lithium-sulfur batteries, sodium-ion batteries, and supercapacitors), and state-of-the-art mechanical characterization and computational methods for binder research. Finally, we propose prospective next-generation binders for energy-storage devices from the molecular level to the macro level. Functional binders will play crucial roles in future high-performance energy-storage devices.
Stable and seamless interfaces among solid components in all‐solid‐state batteries (ASSBs) are crucial for high ionic conductivity and high rate performance. This can be achieved by the combination of functional inorganic material and flexible polymer solid electrolyte. In this work, a flexible all‐solid‐state composite electrolyte is synthesized based on oxygen‐vacancy‐rich Ca‐doped CeO2 (Ca–CeO2) nanotube, lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), and poly(ethylene oxide) (PEO), namely Ca–CeO2/LiTFSI/PEO. Ca–CeO2 nanotubes play a key role in enhancing the ionic conductivity and mechanical strength while the PEO offers flexibility and assures the stable seamless contact between the solid electrolyte and the electrodes in ASSBs. The as‐prepared electrolyte exhibits high ionic conductivity of 1.3 × 10−4 S cm−1 at 60 °C, a high lithium ion transference number of 0.453, and high‐voltage stability. More importantly, various electrochemical characterizations and density functional theory (DFT) calculations reveal that Ca–CeO2 helps dissociate LiTFSI, produce free Li ions, and therefore enhance ionic conductivity. The ASSBs based on the as‐prepared Ca–CeO2/LiTFSI/PEO composite electrolyte deliver high‐rate capability and high‐voltage stability.
HIGHLIGHTS• The roles of binders in both sulfur host-based and sulfur host-free systems are considered for polymer composite frameworks in lithium-sulfur batteries.• The applications of the existing and potential multifunctional polymer composite frameworks are summarized for manufacturing lithium-sulfur batteries.ABSTRACT Extensive efforts have been devoted to the design of micro-, nano-, and/or molecular structures of sulfur hosts to address the challenges of lithium-sulfur (Li-S) batteries, yet comparatively little research has been carried out on the binders in Li-S batteries. Herein, we systematically review the polymer composite frameworks that confine the sulfur within the sulfur electrode, taking the roles of sulfur hosts and functions of binders into consideration. In particular, we investigate the binding mechanism between the binder and sulfur host (such as mechanical interlocking and interfacial interactions), the chemical interactions between the polymer binder and sulfur (such as covalent bonding, electrostatic bonding, etc.), as well as the beneficial functions that polymer binders can impart on Li-S cathodes, such as conductive binders, electrolyte intake, adhesion strength etc. This work could provide a more comprehensive strategy in designing sulfur electrodes for long-life, large-capacity and high-rate Li-S battery.
The sulfur cathode of lithium‐sulfur (Li‐S) batteries suffers from inherent problems of insufficient mechanical strength and the dissolution of sulfur and polysulfides. Inspired by the extraordinarily resilient and strong binding force of the Great Wall binder, that is, the sticky rice mortar, we extracted highly branched amylopectin (HBA), the effective ingredient, as a low‐cost, nontoxic and environmentally benign aqueous binder for the sulfur cathode. The HBA‐based cells outperform the Li‐S batteries based on the traditional polyvinyldene diflouride (PVDF) binder and a lowly branched polysaccharide binder. The improved electrochemical performance in the HBA‐based cell could be attributed to two mechanisms. First, the branched structure of the HBA provides enhanced mechanical and adhesive properties, which allow for a robust electronic and ionic conductive framework to be maintained throughout the cathode after extended cycling. Second, the HBA shows enhanced polysulfide retention due to the polymer's abundant lone‐pair rich hydroxyl groups and the formation of C─S bonds between the HBA and polysulfides prohibits the shuttle effect of polysulfides. The improved mechanical properties and polysulfide retention function of the HBA binder facilitate the HBA‐based Li‐S battery to deliver a long cycle life of 500 cycles at 2 C while only displaying a capacity fading of 0.104% per cycle.
The effects of climate change are just beginning to be felt, and as such, society must work towards strategies of reducing humanity's impact on the environment. Due to the fact that energy production is one of the primary contributors to greenhouse gas emissions, it is obvious that more environmentally friendly sources of power are required. Technologies such as solar and wind power are constantly being improved through research; however, as these technologies are often sporadic in their power generation, efforts must be made to establish ways to store this sustainable energy when conditions for generation are not ideal. Battery storage is one possible supplement to these renewable energy technologies; however, as current Li-ion technology is reaching its theoretical capacity, new battery technology must be investigated. Lithium-sulphur (Li-S) batteries are receiving much attention as a potential replacement for Li-ion batteries due to their superior capacity, and also their abundant and environmentally benign active materials. In the spirit of environmental harm minimization, efforts have been made to use sustainable carbonaceous materials for applications as carbon-sulphur (C-S) composite cathodes, carbon interlayers, and carbon-modified separators. This work reports on the various applications of carbonaceous materials applied to Li-S batteries, and provides perspectives for the future development of Li-S batteries with the aim of preparing a high energy density, environmentally friendly, and sustainable sulphur-based cathode with long cycle life.Batteries 2016, 2, 33 2 of 35 new energy storage systems based on different electrochemistry is urgently needed to go beyond incremental improvements in the specific energy of existing batteries.Lithium-sulphur (Li-S) batteries have the potential advantage of breaking the storage limits of conventional LIBs. As shown in Figure 1, the gravimetric/volumetric energy densities of LIBs and Li-S batteries have been compared. On one hand, sulphur shows the highest theoretical capacity of 1675 mA·h·g −1 among solid cathode elements [1,4]. On the other hand, the matched lithium anode also owns a superior high theoretical capacity of 3861 mA·h·g −1 [5]. Thus, given that Li-S batteries operate on the basis of a stoichiometric redox chemistry between sulphur and lithium, Li-S batteries can reach a theoretical specific energy and volumetric energy density of approximately 2600 W·h·kg −1 and 2800 W·h·L −1 , respectively (based on the complete Li 2 S formation) [6]. The remarkable storage capacity permits electric vehicles to possess a driving range of~500 km after a single charge [1,3]. Moreover, sulphur is an attractive electroactive material for cathodes because it is naturally abundant, low cost, and environmentally friendly [7]. According to the above advantages of sulphur, it is anticipated that Li-S batteries will ultimately rebuild the current energy infrastructure if the technology succeeds.
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