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Optical printing is a powerful all-optical method that allows the incorporation of colloidal nanoparticles (NPs) onto substrates with nanometric precision. Here, we present a systematic study of the accuracy of optical printing of Au and Ag NPs, using different laser powers and wavelengths. When using light of wavelength tuned to the localized surface plasmon resonance (LSPR) of the NPs, the accuracy improves as the laser power is reduced, whereas for wavelengths off the LSPR, the accuracy is independent of the laser power. Complementary studies of the printing times of the NPs reveal the roles of Brownian and deterministic motion. Calculated trajectories of the NPs, taking into account the interplay between optical forces, electrostatic forces, and Brownian motion, allowed us to rationalize the experimental results and gain a detailed insight into the mechanism of the printing process. A clear framework is laid out for future optimizations of optical printing and optical manipulation of NPs near substrates.

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It was previously believed that larger metal nanoparticles behave as tiny mirrors that are pushed by the light beam radiative force along the direction of beam propagation, without a chance to be confined. However, several groups have recently reported successful optical trapping of gold and silver particles as large as 250 nm. We offer a possible explanation based on the fact that metal nanoparticles naturally occur in various non-spherical shapes and their optical properties differ significantly due to changes in localized plasmon excitation. We demonstrate experimentally and support theoretically three-dimensional confinement of large gold nanoparticles in an optical trap based on very low numerical aperture optics. We showed theoretically that the unique properties of gold nanoprisms allow an increase of trapping force by an order of magnitude at certain aspect ratios. These results pave the way to spatial manipulation of plasmonic nanoparticles using an optical fibre, with interesting applications in biology and medicine.

We examine the rotational dynamics of spheroidal particles in an optical trap comprising counter-propagating Gaussian beams of opposing helicity. Isolated spheroids undergo continuous rotation with frequencies determined by their size and aspect ratio, whilst pairs of spheroids display phase locking behaviour. The introduction of additional particles leads to yet more complex behaviour. Experimental results are supported by numerical calculations.

Within the Rayleigh approximation, we investigate the behavior of an individual ellipsoidal metal nanorod that is optically confined in three dimensions using a single focused laser beam. We focus on the description of the optical torque and optical force acting upon the nanorod placed into a linearly polarized Gaussian beam (scalar description of the electric field) or a strongly focused beam (vector field description). The study comprises the influence of the trapping laser wavelength, the angular aperture of focusing optics, the orientation of the ellipsoidal nanorod, and the aspect ratio of its principal axes. The results reveal a significantly different behavior of the nanorod if the trapping wavelength is longer or shorter than the wavelength corresponding to the longitudinal plasmon resonance mode. Published experimental observations are compared with our theoretical predictions with satisfactory results.

Recently, increasing attention has been devoted to mastering a new technique of optical delivery of micro-objects tractor-beam’1, 2, 3, 4, 5, 6, 7, 8, 9. Such beams have uniform intensity profiles along their propagation direction and can exert a negative force that, in contrast to the familiar pushing force associated with radiation pressure, pulls the scatterer toward the light source. It was experimentally observed that under certain circumstances, the pulling force can be significantly enhanced6 if a non-spherical scatterer, for example, a linear chain of optically bound objects10, 11, 12, is optically transported. Here we demonstrate that motion of two optically bound objects in a tractor beam strongly depends on theirs mutual distance and spatial orientation. Such configuration-dependent optical forces add extra flexibility to our ability to control matter with light. Understanding these interactions opens the door to new applications involving the formation, sorting or delivery of colloidal self-organized structures.

While the behavior of optically trapped dielectric spherical particles has been extensively studied, the behavior of non-spherical particles remains mainly unexplored. In this work we focus on the dynamics of oblate spheroidal particles trapped in a tightly focused elliptically-polarized vortex beam. In our experiments we used polystyrene spheroids of aspect ratio of major to minor axes equal to 2.55 and of a volume equal to a sphere of diameter 1.7μm. We demonstrate that such particles can be trapped in three dimensions, with the minor axis oriented perpendicular to both the beam polarization (linear) and the beam propagation, can spin in a circularly polarized beam and an optical vortex beam around the axis parallel with the beam propagation. We also observed that these particles can exhibit a periodic motion in the plane transversal to the beam propagation. We measured that the transfer of the orbital angular momentum from the vortex beam to the spheroid gives rise to torques one order of magnitude stronger comparing to the circularly polarized Gaussian beam. We employed a phase-only spatial light modulator to generate several vortex beam traps with one spheroid in each of them. Due to independent setting of beams parameters we controlled spheroids frequency and sense of rotation and observed hydrodynamic phase and frequency locking of rotating spheroids. These optically driven spheroids offer a simple alternative approach to the former techniques based on birefringent, absorbing or chiral microrotors.