SummaryDuring the development of a GC retention index library very rigorous standard parameters were used in the SADTLER laboratories. Because most chromatographers presumably have their "favourite" and well-proven columns a study has been carried out on how to make use of them for standard index generation. Variables such as column geometry, split ratio, and film thickness were examined and the calculated indices were compared to some "basic" values. Splitless and cool on-column injection techniques were also investigated and comparable temperature programming indices have been obtained. Finally, standard index values of 53 volatile halogenated hydrocarbons measured on very thick-film bonded fused silica capillary columns are tabulated.
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