In order to study the effects of the crystallinity of polyethylene with different densities on breakdown strength and conductance properties, this paper mainly tests the X-ray diffraction (XRD), different scanning calorimeter (DSC), direct current (DC) breakdown and conductance properties of low-density polyethylene (LDPE), linear low density polyethylene (LLDPE), medium density polyethylene (MDPE), and high-density polyethylene (HDPE), and further analyzes the experimental results separately. The results show that an increase in the density of polyethylene leads to the continuous improvement of crystallinity, and an increase in crystallinity causes a significant decrease in the conduction current at the same field strength. The field strength corresponding to the two turning points in the conductance characteristic curve increases simultaneously.
First, a novel nonlinear Muskingum flood routing model with a variable exponent parameter and simultaneously considering the lateral flow along the river reach (named VEP-NLMM-L) was developed in this research. Then, an improved real-coded adaptive genetic algorithm (RAGA) with elite strategy was applied for precise parameter estimation of the proposed model. The problem was formulated as a mathematical optimization procedure to minimize the sum of the squared deviations (SSQ) between the observed and the estimated outflows. Finally, the VEP-NLMM-L was validated on three watersheds with different characteristics (Case 1 to 3). Comparisons of the optimal results for the three case studies by traditional Muskingum models and the VEP-NLMM-L show that the modified Muskingum model can produce the most accurate fit to outflow data. Application results in Case 3 also indicate that the VEP-NLMM-L may be suitable for solving river flood routing problems in both model calibration and prediction stages.
Three series of new anthranilic diamide derivatives containing sulfide, N-cyanomethylsulfilimine, and N-cyanomethylsulfoximine groups were designed and synthesized by coupling the active substructures of anthranilic diamides and sulfoxaflor. The structures of the synthesized compounds were confirmed by infrared spectroscopy, 1 H and 13 C NMR, and elemental analysis. Several unique structural characteristics were revealed via the crystal structure analysis of compoundBioassay results indicated that most of the synthesized compounds showed superior insecticidal activities against Mythimna separata and Plutella xylostella when compared with the positive control cyantraniliprole. In particular, N- (2-(2-methyl-2-(N-cyanomethylsulfideimino)propylcarbamoyl)-4-chloro-6-methylphenyl)-3-bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxamide 17e showed excellent insecticidal activity against Mythimna separata, with a mortality rate of 100 % at a concentration of 1 mg mL À1 . These results indicated that sulfide, N-cyanomethylsulfilimine, and N-cyanomethylsulfoximine moieties, as important active substructures, could improve or maintain the activity of the anthranilic diamide and promote novel pesticide development.
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