Interest in cellulose nanocrystals obtained from natural resources has grown mainly because of features that such materials provide when inserted into polymeric matrices. The present study aimed to evaluate the effect of cellulose nanocrystals addition on mechanical properties of biofilms made from hypromellose (or hydroxypropyl methylcellulose - HPMC) and cassava starch blends (CS). The cellulose nanocrystals were produced by acid hydrolysis and characterized by optical microscopy (OM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and thermogravimetry (TG). Films were made with pure CS, pure hypromellose and also with blends of CS and hypromellose by casting. Then cellulose nanocrystals were added to the blends in the concentrations of 1, 3 and 10% (m/m). Evaluations of the films included tensile performance and fracture surface by scanning electron microscopy (SEM). It was observed that the reinforcement with nanocrystals improved the mechanical properties of the films, and their fracture surface showed that cellulose nanocrystals promoted an improvement in the cohesion of the hypromellose and starch molecules in the blend, and created a more homogeneous surface.
ABSTRAT: Thermoplastic composites made with 45, 60 and 75% of rice straw as filler and two types of thermoplastics, virgin polyethylene (PE) and polypropylene (PP) were evaluated. The final boards were made with and without maleic anhydride modified polypropylene (MAPP) at 2% of the total weight of each specimen. The flexural and tensile strengths were measured for dry composites and also measured after 24 h of water immersion of the composites (wet condition). By increasing the filler content, the flexural and tensile strengths and also the density of the specimens decreased. The type of matrix (PE or PP) did not affect significantly the flexural strength, but PP led to higher values of tensile strength for low fiber loadings (45% and 60%). Coupling agents increased the flexural and tensile strength. After water immersion, modulus of elasticity and modulus of rupture were decreased, while tensile strength was less influenced.
COMPÓSITO TERMOPLÁSTICO/PALHA DE ARROZ: EFEITO DA CARGA DE ENCHIMENTO, TIPO DE POLÍMERO E ABSORÇÃO DE UMIDADE NO DESEMPENHORESUMO: Foram avaliados compósitos termoplásticos feitos com 45, 60 e 75% de palha de arroz como material de enchimento e dois tipos de termoplásticos, polietileno virgem (PE) e polipropileno (PP). As placas finais foram feitas com e sem polipropileno modificado com anidrido maleico (MAPP) a 2% do peso total de cada amostra. As resistências à flexão e à tração foram medidas para compósitos secos e também medidas após 24 h de imersão em água dos compósitos (condição úmida). Ao aumentar o teor de enchimento, as resistências à flexão e à tração e também a densidade dos matérias diminuíram. O tipo de matriz (PE ou PP) não afetou significativamente a resistência à flexão, mas o PP levou os maiores valores de resistência à tração para baixas cargas de fibras (45% e 60%). Os agentes de acoplamento aumentaram a resistência à flexão e à tração. Após a imersão em água, o módulo de elasticidade e o módulo de ruptura diminuíram, enquanto que a resistência à tração foi menos influenciada.
The main objective of this research is to evaluate the influence of coating based on cellulose micro/nanofibrils (CMF) and carboxylated styrene butadiene rubber (XSBR) on sack kraft paper, for possible use in packaging. Filmogenic solutions were applied manually as a coating on sack kraft paper. These solutions were prepared by suspensions of CMF 1.5 % w/v with the addition of different content of XSBR (0, 2, 10, and 20 % about the total mass of CMF). Uncoated sack kraft paper was used as control. Films were obtained by casting and characterized physically, morphologically, and mechanically. The results demonstrated that XSBR and CMF composite suspension showed good performance as a coating on sack kraft paper. The formation of homogeneous structures well distributed on paper can be observed on scanning electron microscope images. Coatings containing XSBR presented a smoother surface, less porosity and hydrophilicity, and a greater coalescence, with good properties of air resistance and water vapor permeability. However, regarding mechanical properties, there were no improvements in coated papers. Therefore, the present study contributed information on the development of more flexible and hydrophobic cellulosic papers for possible applications in the industrial packaging sector.
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