Metal-free dual singlet-triplet organic light-emitting diode (OLED) emitters can provide direct insight into spin statistics, spin correlations and spin relaxation phenomena, through a comparison of fluorescence to phosphorescence intensity. Remarkably, such materials can also function at room temperature, exhibiting phosphorescence lifetimes of several milliseconds. Using electroluminescence, quantum chemistry, and electron paramagnetic resonance spectroscopy, we investigate the effect of the conjugation pathway on radiative and nonradiative relaxation of the triplet state in phenazine-based compounds and demonstrate that the contribution of the phenazine nπ* excited state is crucial to enabling phosphorescence.

Utilization of triplets is important for preparing organic light-emitting diodes with high efficiency. Very recently, both electrophosphorescence and electrofluorescence could be observed at room temperature for thienyl-substituted phenazines without any heavy metals ( Ratzke et al. J. Phys. Chem. Lett. , 2016 , 7 , 4802 ). It was found that the phosphorescence efficiency depends on the orientation of fused thiophenes. In this work, the thienyl-substituted phenazines are investigated in more detail by time-resolved electron paramagnetic resonance (EPR) and quantum chemical calculations. Spin dynamics, zero-field splitting constants, and electron-spin structures of the excited triplet states for the metal-free room-temperature triplet emitters are correlated with phosphorescence efficiency. Complete active space self-consistent field (CASSCF) calculations clearly show that the electron spin density distributions of the first excited triplet states are strongly affected by the molecular geometry. For the phosphorescent molecules, the electron spins are localized on the phenazine unit, in which the sulfur atom of the fused thiophene points upward. The electron spins are delocalized onto the thiophene unit just by changing the orientation of the fused thiophenes from upward to downward, resulting in the suppression of phosphorescence. Time-resolved EPR measurements and time-dependent density functional theory (TD-DFT) calculations demonstrate that the electron spins delocalized onto the thiophene unit lead to the acceleration of nonradiative decays, in conjunction with the narrowing of the singlet-triplet energy gap.

Background Although cancer outcomes have improved in recent decades, substantial disparities by race, ethnicity, income and education persist. Increasingly, patient navigation services are demonstrating success in improving cancer detection, treatment and care and in reducing cancer health disparities. To advance progress in developing patient navigation programs, extensive descriptions of each component of the program must be made available to researchers and health service providers. Objective To describe the components of a patient navigation program designed to improve cancer screening based on informed decision-making on cancer screening and cancer treatment services among predominantly Black older adults in Baltimore City. Methods A community-academic participatory approach was used to develop a patient navigation program in Baltimore, Maryland. The components of the patient navigation system included the development of a community academic (advisory) committee (CAC); recruitment and selection of community health workers (CHWs)/navigators and supervisory staff; initial training and continuing education of the CHWs/navigators; and evaluation of CHWs/navigators. The study was approved by the Johns Hopkins Bloomberg School of Public Health Institutional Review Board. Conclusions The incorporation of community-based participatory research (CPBR) principles into each facet of this patient navigation program facilitated the attainment of the intervention’s objectives. This patient navigation program successfully delivered cancer navigation services to 1302 urban Black older adults. Appropriately recruited, selected and trained CHWs monitored by an experienced supervisor and investigators are the key elements in a patient navigation program. This model has the potential to be adapted by research and health service providers.

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With the increase in potential uses of terahertz technology, the need for terahertz transceivers with application-oriented adaptive radiation patterns has emerged. Reconfigurable reflectarrays consisting of actuated sub-wavelength reflectors have been successfully used for terahertz beam steering and beamforming. They do not require a complex feeding network and associated electronics, enabling a compact and power-efficient terahertz beam steering system. However, the current reflectarray-based beam steering is accomplished by forming the reflectarray as a grating structure, which is accompanied by the problems such as grating lobes, limited steering range, and discrete steering angles. Here, we configure a MEMS-based reflectarray with the genetic algorithm to eliminate the grating lobes and open up the possibility of customizing its radiation pattern. We used single-and multi-objective optimization to find the optimal height profile of the reflectarray and verified the results by full-wave electromagnetic simulations. We measured the radiation patterns of four reflectarray phantoms, i.e. reflectarrays without the MEMS actuation systems. The measurement results agree well with the calculated ones, with the main beam deviating at most 2 • from the target direction. Our work demonstrates how a genetic algorithm is used to shape a reconfigurable terahertz reflectarray to eliminate the grating lobes and tailor some specific featuress in its radiation pattern.

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We present the design, fabrication, and characterization of a MEMS-based 3-bit Digital-to-Analog Converter (DAC) that allows the generation of large displacements. The DAC consists of electrostatic bending-plate actuators that are connected to a mechanical amplifier (mechAMP), enabling the amplification of the DAC output displacement. Based on a parallel binary-encoded voltage signal, the output displacement of the system can be controlled in an arbitrary order. Considering the system design, we present a simplified analytic model, which was confirmed by FE simulation results. The fabricated systems showed a total stroke of approx. 149.5 ± 0.3 µm and a linear stepwise displacement of 3 bit correlated to 23 ≙ eight defined positions at a control voltage of 60 V. The minimum switching time between two input binary states is 0.1 ms. We present the experimental characterization of the system and the DAC and derive the influence of the mechAMP on the functionality of the DAC. Furthermore, the resonant behavior and the switching speed of the system are analyzed. By changing the electrode activation sequence, 27 defined positions are achieved upgrading the 3-bit systems into a 3-tri-state (33) system.

An earlier version of this paper was presented at the 2021 15th European Conference on Antennas and Propagation (EuCAP) and was published in its Proceedings. This paper describes a design, fabrication, and characterization of a planar frequency-coded retroreflector for indoor localization. The retroreflector is fabricated in high-resistive silicon and consists of a Luneburg lens antenna and a photonic crystal high-Q resonator reflective layer, providing ranging and identification within the same tag and bandwidth. The Luneburg lens antenna presents a measured gain of 21.63 dBi at a design frequency of 240 GHz. The frequency-coded retroreflector allows for ranging in a continuous 130 degree angular range in azimuthal plane, with a discrete but repeatable two-resonance identification over multiples of 15 degree. Its maximum measured radar cross-section is −23.48 dBsqm at a frequency of 240 GHz. The retroreflective tag set in ideal line-of-sight situation is compared to a non-line-of-sight arrangement showing the influence of a metallic rod as an obstacle on the overall tag detection parameters. Finally, the successful read-out of the retroreflective tag is discussed in unknown environments, where no a-priori information is available.