Ingenious
microstructure design and a suitable multicomponent strategy
are still challenging for advanced electromagnetic wave absorbing
(EMA) materials with strong absorption and a broad effective absorption
bandwidth (EAB) at thin sample thickness and low filling level. Herein,
a three-dimensional (3D) dielectric Ti3C2T
x
MXene/reduced graphene oxide (RGO) aerogel
anchored with magnetic Ni nanochains was constructed via a directional-freezing method followed by the hydrazine vapor reduction
process. The oriented cell structure and heterogeneous dielectric/magnetic
interfaces benefit the superior absorption performance by forming
perfect impedance matching, multiple polarizations, and electric/magnetic-coupling
effects. Interestingly, the prepared ultralight Ni/MXene/RGO (NiMR-H)
aerogel (6.45 mg cm–3) delivers the best EMA performance
in reported MXene-based absorbing materials up to now, with a minimal
reflection loss (RLmin
) of −75.2
dB (99.999 996% wave absorption) and a broadest EAB of 7.3
GHz. Furthermore, the excellent structural robustness and mechanical
properties, as well as the high hydrophobicity and heat insulation
performance (close to air), guarantee the stable and durable EMA application
of the NiMR-H aerogel to resist deformation, water or humid environments,
and high-temperature attacks.
Electromagnetic (EM) pollution affecting people's normal lives and health has attracted considerable attention in the current society. In this work, a promising EM wave absorption and shielding material, MXene/Ni hybrid, composed of one-dimensional Ni nanochains and two-dimensional Ti 3 C 2 T x nanosheets (MXene), is successfully designed and developed. As expected, excellent EM wave absorption and shielding properties are obtained and controlled by only adjusting the MXene content in the hybrid. A minimum reflection loss of −49.9 dB is obtained only with a thickness of 1.75 mm at 11.9 GHz when the MXene content is 10 wt %. Upon further increasing the MXene content to 50 wt %, the optimal EM shielding effectiveness (SE) reaches 66.4 dB with an absorption effectiveness (SE A ) of 59.9 dB. Mechanism analysis reveals that the excellent EM wave absorption and shielding performances of the hybrid are contributed to the synergistic effect of conductive MXene and magnetic Ni chains, by which, the dielectric properties and electromagnetic loss can be easily controlled to obtain appropriate impedance matching conditions and good EM wave dissipation ability. This work provides a simple but effective route to develop MXene-based EM wave absorption and shielding materials. A universal guideline for designing the absorbing and shielding materials for the future is also proposed.
Two-dimensional Ti 3 C 2 T x MXene-based hybrids-anchored magnetic metal nanoparticles show a huge potential application as effective wave absorbers due to the synergistic electromagnetic (EM) loss effect. In this work, uniform and size-controllable nickel, cobalt, or nickel−cobalt alloy nanoparticles were in situ grown on the surface of MXene via a facile and moderate co-solvothermal method for the first time. As an example, a nickel nanoparticles-anchored MXene (Ni@MXene) hybrid was homodispersed into dielectric polyvinylidene fluoride to develop its EM waveabsorbing capacity to a great extent. As expected, the results showed strong reflection loss (RL min = −52.6 dB at 8.4 GHz), broad effective absorption bandwidth (EAB = 3.7 GHz including 71% of X-band), low loading (10 wt % Ni@MXene), and thin thickness (3.0 mm). By adjusting the sample thickness, EAB can cover completely the whole X-band with a maximum of 6.1 GHz, showing a huge potential of Ni@MXene hybrid applying as aircraft stealth coating. The mechanism analyses revealed that the excellent impedance matching, magnetocoupling effect, conductance, magnetic loss, and multiple scatterings contribute to the splendid EM wave-absorbing performance of the Ni@MXene hybrid. Considering the excellent overall performance, the Ni@MXene hybrid was identified as a promising candidate for EM wave absorption.
A novel nonlinear phase-field model is proposed for modeling microstructure evolution during highly nonequilibrium processes. We consider electrochemical reactions at electrode/electrolyte interfaces leading to electroplating and electrode/electrolyte interface evolution. In contrast to all existing phase-field models, the rate of temporal phase-field evolution and thus the interface motion in the current model is considered nonlinear with respect to the thermodynamic driving force. It produces Butler-Volmer-type of electro-chemical kinetics for the dependence of interfacial velocity on the overpotential at the sharp-interface limit. At the low overpotential it recovers the conventional Allen-Cahn phase-field equation. This model is generally applicable to many other highly non-equilibrium processes where linear kinetics breaks down.
A nonlinear phase-field model has been developed for describing the electrodeposition process in electrochemical systems that are highly out of equilibrium. Main thermodynamic driving forces for the electrode-electrolyte interface (EEI) evolution are limited to local variations of overpotential and ion concentration. Application of the model to Li-ion batteries describes the electrode interface motion and morphology change caused by charge mass transfer in the electrolyte, an electrochemical reaction at the EEI and cation deposition on the electrode surface during the charging operation. The Li electrodeposition rate follows the classical Butler-Volmer kinetics with exponentially and linearly depending on local overpotential and cation concentration at the electrode surface, respectively. Simulation results show that the Li deposit forms a fiber-like shape and grows parallel to the electric field direction. The longer and thicker deposits are observed both for higher current density and larger rate constant where the surface reaction rate is expected to be high. The proposed diffuse interface model well captures the metal electrodeposition phenomena in plenty of non-equilibrium electrochemical systems.
The facile fabrication of thin flexible electromagnetic interference (EMI) shielding materials with fast heat dissipation for adaptable tuning in both civil and military applications is in urgent demand. In our work, the flexible poly(vinylidene fluoride) (PVDF)/carbon nanotube (CNT) composite films decorated with anisotropy-shaped Co in flowers or chains were prepared and studied. The results showed that by increasing the Co filler contents, the EC (electrical conductivity), TC (thermal conductivity), and EMI shielding properties of such PVDF/CNT/Co (flowers or chains) flexible films were significantly improved. In contrast, the PVDF/CNT/Co-chain flexible films exhibit higher performance with respect to the EC, TC, and EMI shielding properties. Total shielding of 35.3 and 32.2 dB were, respectively, obtained by the PVDF/CNT/6 wt % Cochain with an EC of 2.28 S/cm and the PVDF/CNT/6 wt % Co-flower with an EC of 1.94 S/cm at a film thickness of 0.3 mm. Possibly owing to the conductive dissipation, interfacial polarization, magnetic loss, multiple reflections, and scattering of EM waves, such flexible composite films possessed a remarkable absorption-dominated EMI shielding behavior. These new composite films with enhanced TC are easily able to transform microwave energy into Joule heating systems, making themselves greatly potential for effective EMI shielding as well as rapid heat dissipation.
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