Cooling is a significant end-use of energy globally and a major driver of peak electricity demand. Air conditioning, for example, accounts for nearly fifteen per cent of the primary energy used by buildings in the United States. A passive cooling strategy that cools without any electricity input could therefore have a significant impact on global energy consumption. To achieve cooling one needs to be able to reach and maintain a temperature below that of the ambient air. At night, passive cooling below ambient air temperature has been demonstrated using a technique known as radiative cooling, in which a device exposed to the sky is used to radiate heat to outer space through a transparency window in the atmosphere between 8 and 13 micrometres. Peak cooling demand, however, occurs during the daytime. Daytime radiative cooling to a temperature below ambient of a surface under direct sunlight has not been achieved because sky access during the day results in heating of the radiative cooler by the Sun. Here, we experimentally demonstrate radiative cooling to nearly 5 degrees Celsius below the ambient air temperature under direct sunlight. Using a thermal photonic approach, we introduce an integrated photonic solar reflector and thermal emitter consisting of seven layers of HfO2 and SiO2 that reflects 97 per cent of incident sunlight while emitting strongly and selectively in the atmospheric transparency window. When exposed to direct sunlight exceeding 850 watts per square metre on a rooftop, the photonic radiative cooler cools to 4.9 degrees Celsius below ambient air temperature, and has a cooling power of 40.1 watts per square metre at ambient air temperature. These results demonstrate that a tailored, photonic approach can fundamentally enable new technological possibilities for energy efficiency. Further, the cold darkness of the Universe can be used as a renewable thermodynamic resource, even during the hottest hours of the day.

Radiative cooling technology utilizes the atmospheric transparency window (8–13 μm) to passively dissipate heat from Earth into outer space (3 K). This technology has attracted broad interests from both fundamental sciences and real world applications, ranging from passive building cooling, renewable energy harvesting and passive refrigeration in arid regions. However, the temperature reduction experimentally demonstrated, thus far, has been relatively modest. Here we theoretically show that ultra-large temperature reduction for as much as 60 °C from ambient is achievable by using a selective thermal emitter and by eliminating parasitic thermal load, and experimentally demonstrate a temperature reduction that far exceeds previous works. In a populous area at sea level, we have achieved an average temperature reduction of 37 °C from the ambient air temperature through a 24-h day–night cycle, with a maximal reduction of 42 °C that occurs when the experimental set-up enclosing the emitter is exposed to peak solar irradiance.

A solar absorber, under the sun, is heated up by sunlight. In many applications, including solar cells and outdoor structures, the absorption of sunlight is intrinsic for either operational or aesthetic considerations, but the resulting heating is undesirable. Because a solar absorber by necessity faces the sky, it also naturally has radiative access to the coldness of the universe. Therefore, in these applications it would be very attractive to directly use the sky as a heat sink while preserving solar absorption properties. Here we experimentally demonstrate a visibly transparent thermal blackbody, based on a silica photonic crystal. When placed on a silicon absorber under sunlight, such a blackbody preserves or even slightly enhances sunlight absorption, but reduces the temperature of the underlying silicon absorber by as much as 13°C due to radiative cooling. Our work shows that the concept of radiative cooling can be used in combination with the utilization of sunlight, enabling new technological capabilities.radiative cooling | thermal radiation | photonic crystal | solar absorber T he universe, at a temperature of 3 K, represents a significant renewable thermodynamic resource: it is the ultimate heat sink. Over midinfrared wavelengths, in particular between 8 and 13 μm, Earth's atmosphere is remarkably transparent to electromagnetic radiation. This wavelength range coincides with the peak wavelength of thermal radiation from terrestrial structures at typical ambient temperatures. Thus, a sky-facing terrestrial object can have radiative access to the universe. Exploiting this radiative access has led to the demonstration of radiative cooling (1-7), as well as proposals for direct electric power generation from thermal radiation of terrestrial objects (8).Whereas historically radiative cooling was largely developed for night-time applications (1-6, 9-13), recent works have achieved daytime radiative cooling (7,14). In particular, it was shown that the radiative cooling to below ambient air temperature can be achieved (7), with a photonic structure that reflects almost all incident sunlight and simultaneously emits significant thermal radiation in the midinfrared. Such a structure, being a near-perfect solar reflector, makes no use of incident sunlight. On the other hand, in many applications, including solar cells (15) and outdoor structures (16), the utilization of sunlight through absorption is intrinsic for either operational or aesthetic considerations, but the heating associated with sunlight absorption is undesirable. For these applications, lowering operating temperatures via radiative cooling is only viable if one can simultaneously preserve the absorption of sunlight.Here we experimentally demonstrate a visibly transparent thermal blackbody, based on a silica photonic crystal, using a thermophotonic approach (17-30). When placed on a silicon absorber under sunlight, such a blackbody preserves and even slightly enhances sunlight absorption, but reduces the temperature of the silicon absorber by as m...

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The heating of a solar cell has significant adverse consequences on both its efficiency and its reliability. Here to fully exploit the cooling potential of solar cells, we experimentally characterized the thermal radiation and solar absorption properties of current silicon solar cells and, on the basis of such experimental characterization, propose a comprehensive photonic approach by simultaneously performing radiative cooling while also selectively utilizing sunlight. In particular, we design a photonic cooler made of one-dimensional photonic films that can strongly radiate heat through its thermal emission while also significantly reflecting the solar spectrum in the sub-band-gap and ultraviolet regimes. We show that applying this photonic cooler to a solar panel can lower the cell temperature by over 5.7 °C. We also show that this photonic cooler can be used in a concentrated photovoltaic system to significantly reduce the solar cell temperature or required cooling power. This photonic cooler can be readily implemented in current photovoltaic modules as a retrofit to improve both efficiency and lifetime. Our approach points to an optimal photonic approach for thermal management of solar cells.