Nonfullerene acceptors tend to decompose in the presence of ZnO due to photocatalytic activity, and SnO2 is an alternative for higher efficiency and better stability.
Polymer binders with high ion and electron conductivities are prepared by assembling ionic polymers (polyethylene oxide and polyethylenimine) onto the electrically conducting polymer poly(3,4‐ethylenedioxythiophene): poly(styrenesulfonate) chains. Crosslinking, chemical reductions, and electrostatics increase the modulus of the binders and maintain the integrity of the anode. The polymer binder shows lithium‐ion diffusivity and electron conductivity that are 14 and 90 times higher than those of the widely used carboxymethyl cellulose (with acetylene black) binder, respectively. The silicon anode with the polymer binder has a high reversible capacity of over 2000 mA h g−1 after 500 cycles at a current density of 1.0 A g−1 and maintains a superior capacity of 1500 mA h g−1 at a high current density of 8.0 A g−1.
Nonfullerene (NF) organic solar cells (OSCs) have been attracting significant attention in the past several years. It is still challenging to achieve high-performance flexible NF OSCs. NF acceptors are chemically reactive and tend to react with the low-temperature-processed lowwork function (low-WF) interfacial layers, such as polyethylenimine ethoxylated (PEIE), which leads to the "S" shape in the current-density characteristics of the cells. In this work, the chemical interaction between the NF active layer and the polymer interfacial layer of PEIE by increasing its protonation is deactivated. The PEIE processed from aqueous solution shows more protonated N + than that processed from isopropanol solution, observed from X-ray photoelectron spectroscopy. NF solar cells (active layer: PCE-10:IEICO-4F) with the protonated PEIE interfacial layer show an efficiency of 13.2%, which is higher than the reference cells with a ZnO interlayer (12.6%). More importantly, the protonated PEIE interfacial layer processed from aqueous solution does not require a further thermal annealing treatment (only processing at room temperature). The room-temperature processing and effective WF reduction enable the demonstration of high-performance (12.5%) flexible NF OSCs.
Achieving high power conversion efficiency and good mechanical robustness is still challenging for the ultraflexible organic solar cells. Interlayers simultaneously having good mechanical robustness and good chemical compatibility with the active layer are highly desirable. In this work, we present an interlayer of Zn2+-chelated polyethylenimine (denoted as PEI-Zn), which can endure a maximum bending strain over twice as high as that of ZnO and is chemically compatible with the recently emerging efficient nonfullerene active layers. On 1.3 μm polyethylene naphthalate substrates, ultraflexible nonfullerene solar cells with the PEI-Zn interlayer display a power conversion efficiency of 12.3% on PEDOT:PSS electrodes and 15.0% on AgNWs electrodes. Furthermore, the ultraflexible cells show nearly unchanged power conversion efficiency during 100 continuous compression-flat deformation cycles with a compression ratio of 45%. At the end, the ultraflexible cell is demonstrated to be attached onto the finger joint and displays reversible current output during the finger bending-spreading.
Vertical phase distribution plays an important role in the quasi-two-dimensional perovskite solar cells. So far, the driving force and how to tailor the vertical distribution of layer numbers have been not discussed. In this work, we report that the vertical distribution of layer numbers in the quasi-two-dimensional perovskite films deposited on a hole-transporting layer is different from that on glass substrate. The vertical distribution could be explained by the sedimentation equilibrium because of the colloidal feature of the perovskite precursors. Acid addition will change the precursors from colloid to solution that therefore changes the vertical distribution. A self-assembly layer is used to modify the acidic surface property of the hole-transporting layer that induces the appearance of desired vertical distribution for charge transport. The quasi-two-dimensional perovskite cells with the surface modification display a higher open-circuit voltage and a higher efficiency comparing to reference quasi-two-dimensional cells.
All‐solution‐processed organic solar cells (from the bottom substrate to the top electrode) are highly desirable for low‐cost and ubiquitous applications. However, it is still challenging to fabricate efficient all‐solution‐processed organic solar cells with a high‐performance nonfullerene (NF) active layer. Issues of charge extraction and wetting are persistent at the interface between the nonfullerene active layer and the printable top electrode (PEDOT:PSS). In this work, efficient all‐solution‐processed NF organic solar cells (from the bottom substrate to the top electrode) are reported via the adoption of a layer of hydrogen molybdenum bronze (HXMoO3) between the active layer and the PEDOT:PSS. The dual functions of HXMoO3 include: 1) its deep Fermi level of −5.44 eV can effectively extract holes from the active layer; and 2) the wetting issues of the PEDOT:PSS on the hydrophobic surface of the NF active layer can be solved. Importantly, fine control of the HXMoO3 composition during the synthesis is critical in obtaining processing orthogonality between HXMoO3 and the PEDOT:PSS. Flexible all‐solution‐processed NF organic solar cells with power conversion efficiencies of 11.9% and 10.3% are obtained for solar cells with an area of 0.04 and 1 cm2, respectively.
Bacterial cellulose (BC) production by Acetobacter xylinum NUST4.1 was carried out in the shake flask and in a stirred-tank reactor by means of adding sodium alginate (NaAlg) into the medium. When 0.04% (w/v) NaAlg was added in the shake flask, BC production reached 6.0 g/l and the terminal yield of the cellulose was 27% of the total sugar initially added, compared with 3.7 g/l and 24% in the control, respectively. The variation between replicates in all determinations was less than 5%. During the cultivation in the stirred-tank reactor, the addition of NaAlg changed the morphology of cellulose from the irregular clumps and fibrous masses entangled in the internals to discrete masses dispersing into the broth, which indicates that NaAlg hinders formation of large clumps of BC, and enhances cellulose yield. Because the structure of cellulose is changed depending on the culture condition such as additives, structural characteristics of BC produced in the NaAlg-free and NaAlg medium are compared using scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD). SEM photographs show some differences in reticulated structures and ribbon width and FT-IR spectra indicate that there is the hydrogen bonding interaction between BC and NaAlg, then X-ray diffraction (XRD) analysis reveals that BC produced with NaAlg-added has a lower crystallinity and a smaller crystalline size. The results show that enhanced yields and modification of cellulose structure occur in the presence of NaAlg.
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