The interaction behavior and the
process of mixed micellization
for binary mixtures of an amino sulfonate amphoteric surfactant sodium
3-(N-dodecyl ethylenediamino)-2-hydropropyl sulfonate
(C12AS) and a cationic surfactant octadecyltrimethylammonium bromide
(OTAB) in aqueous solution of NaCl (0.250 M) at 313.15 K were investigated
using both the tensiometry and the UV–vis spectrometry using
pyrene as a probe. The mixed critical micelle concentration (cmc) of the C12AS/OTAB mixtures were determined by two techniques.
Based on regular solution theory, pseudophase separation model, Clint’s
model, Rosen’s model, and Rubingh’s model, some parameters
(including the ideal mixed cmc, the compositions
in mixed micelle, the interaction parameters between two surfactants,
the activity coefficients in mixed micelle, some thermodynamic parameters,
etc.) were evaluated and calculated. The deviation of mixed cmc from its ideal value indicates a nonideal mixing between
two surfactants. In comparison with those in aqueous solutions, the
presence of NaCl induces some differences in the dependence of compositions
in mixed micelle on its content in bulk solution, and there has a
stronger synergism between two surfactants. Thermodynamic parameters
shows that the mixed micellization of the C12AS/OTAB mixtures is an
entropically spontaneous process, while the addition of NaCl to the
solution can partly suppress the contribution of entropy to the process
of micellization. The electrostatic attraction between two surfactants,
the steric effect of hydrophilic group of C12AS, and the interaction
repulsion between head groups of individual surfactants may play vital
roles on the process of micellization. These findings help with probing
the effect of additives on the process of micellization and understanding
the interaction behavior between surfactants so as to design surfactant
formulations.
Wireless sensor networks (WSNs) are adopted in a variety of fields where coverage enhancing is a critical challenge because of the requirements of service quality, cost, and energy consumption. Coverage-enhancing approaches have currently attracted a lot of interest owing to their superior abilities in the deployment of the WSNs, e.g., maximum coverage, minimum sensors, and minimum energy. In this paper, a differential evolution-based regional coverage-enhancing algorithm is proposed for directional 3D WSNs, which is able to maximizing coverage while minimize the number of sensors. First, a directional cone perception model is designed to better display the actual sensing performance of sensor nodes. Subsequently, the coverage region is established to describe the perceptual range of nodes. Thereafter, a three-stage coverage-enhancing method is derived, which includes the pitch angle optimization, the deflection angle optimization and the redundant node sleeping. These strategies are designed to maximize the perception range of a single sensor node, maximize the coverage rate, and minimize the number of nodes, respectively. Finally, simulation results show that our method is able to ensure better performance compared to the stateof-the-art frameworks.
With the advancement of multimedia technology, a series of problems have emerged in the reform of college English teaching. How to use multimedia to assist college students in English learning has become a meaningful study. Multimedia-assisted instruction is a common method of teaching English. The design of multimedia-assisted English teaching resource software determines its development, management, evaluation and other aspects, so the design of multimedia platform plays a vital role in the effect of multimedia teaching. This paper will discuss the design and implementation of multimedia-assisted college English independent education resources from the perspective of knowledge classification. Through the content analysis, some problems exist in the design process of some college English multimedia teaching, and the status quo is analyzed. It also studies the difficulties of college students in the process of multimedia assisted learning, and how college students hope to design multimedia independent learning multimedia platform. Finally, the five knowledge classification learning theories of “listening, speaking, reading, writing and translating” can change the status quo, meet the needs of college students, and develop the knowledge of vocabulary, grammar and listening in college English. The design strategy of self-learning multimedia-assisted instruction and the design of college English self-learning multimedia teaching is briefly written.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.