Sodium-ion batteries (SIBs) are considered as one of the most promising candidates for competing with lithium-ion batteries owing to significant natural abundance of sodium and similar reaction mechanism. The large radius of Na + (1.02 Å) severely impedes the electrochemical performance, especially high-rate capability and long-cycle stability of SIBs. Together with the cathode and electrolyte, the anode determines full battery's operating voltage and plays a vital role in avoiding sodium dendrite in terms of redox potential. On this account, the anode holds a prime importance toward the development of advanced SIBs with high rate capability and superior durability. Herein, we present a review on the exciting advances in alloy-and conversion-type anode materials as well as solid-electrolyte interphase layer for SIBs aiming at the improvement of rate capability and cycling life. Finally, the challenges and some of the critical issues in alloy-type and conversion-type anode materials for sodium-ion batteries are addressed.
Doxorubicin impairs viability of cardiomyocytes at least partially by activating the p53-mediated, mitochondrion-dependent apoptotic signalling. EGb761 can effectively and extensively counteract this action of doxorubicin, and may potentially protect the heart from the severe toxicity of doxorubicin.
Fengycin, a lipopeptide biosurfactant, was produced by indigenous Bacillus subtilis F29-3 isolated from a potato farm. Although inhibiting the growth of filamentous fungi, the fengycin is ineffective against yeast and bacteria. In this study, fengycin was isolated from fermentation broth of B. subtilis F29-3 via acidic precipitation (pH 2.0 with 5 N HCl) followed by purification using ultrafiltration and nanofiltration. The purified fengycin product was characterized qualitatively by using fast atom bombardment-mass spectrometer, Fourier transform infrared spectrometer, ultraviolet-visible spectrophotometer, 13C-nuclear magnetic resonance spectrometer and matrix assisted laser desorption ionization-time of flight, followed by quantitative analysis using reversed-phase HPLC system. This study also attempted to increase fengycin production by B. subtilis F29-3 in order to optimize the fermentation medium constituents. The fermentation medium composition was optimized using response surface methodology (RSM) to increase fengycin production from B. subtilis F29-3. According to results of the five-level four-factor central composite design, the composition of soybean meal, NaNO3, MnSO4·4H2O, mannitol-mannitol, soybean meal-mannitol, soybean meal-soybean meal, NaNO3-NaNO3 and MnSO4·4H2O-MnSO4·4H2O significantly affected production. The simulation model produced a coefficient of determination (R2) of 0.9043, capable of accounting for 90.43% variability of the data. Results of the steepest ascent and central composite design indicated that 26.2 g/L of mannitol, 21.9 g/L of soybean meal, 3.1 g/L of NaNO3 and 0.2 g/L of MnSO4·4H2O represented the optimal medium composition, leading to the highest production of fengycin. Furthermore, the optimization strategy increased the fengycin production from 1.2 g/L to 3.5 g/L.
Electroluminescence (EL) is the property of a semiconductor material pertaining to emitting light in response to an electrical current or a strong electric field. The purpose of this paper is to develop a flexible and lightweight EL device. Thermogravimetric analysis (TGA) was conducted to observe the thermal degradation behavior of NinjaFlex. Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonic acid)-PEDOT:PSS-with ethylene glycol (EG) was coated onto polyester fabric where NinjaFlex was placed onto the coated fabric using three-dimensional (3D) printing and phosphor paste, and BendLay filaments were subsequently coated via 3D printing. Adhesion strength and flexibility of the 3D-printed NinjaFlex on textile fabrics were investigated. The TGA results of the NinjaFlex depict no weight loss up to 150°C and that the NinjaFlex was highly conductive with a surface resistance value of 8.5 ohms/sq.; the coated fabric exhibited a uniform surface appearance as measured and observed by using four-probe measurements and scanning electron microscopy, respectively, at 60% PEDOT:PSS. The results of the adhesion test showed that peel strengths of 4160 N/m and 3840 N/m were recorded for polyester and cotton specimens, respectively. No weight loss was recorded following three washing cycles of NinjaFlex. The bending lengths were increased by only a factor of 0.082 and 0.577 for polyester and cotton samples at 0.1-mm thickness, respectively; this remains sufficiently flexible to be integrated into textiles. The prototype device emitted light with a 12-V alternating current power supply.
Coating of textile fabrics with poly (3, 4-ethylenedioxythiophene): poly (styrene sulfonate) (PEDOT:PSS) is one of the methods used for obtaining functional or smart applications. In this work, we prepared PEDOT:PSS polymer with certain additives such as polyethylene glycol, methanol (MeOH), and ethylene glycol on polyester fabric substrates by a simple immersion process. Surface resistance was measured and analyzed with analysis of variance to determine the coating parameters at 95% confidence level. Fourier transform infrared (FTIR) analysis and scanning electron microscopy (SEM) study of the samples were performed. Contact angle and washing fastness measurements were conducted, to observe the wettability and washing fastness of the samples, respectively. Surface resistance values were decreased by a factor of 100, due to conductive enhancers. As the immersion time and temperature condition varies, surface resistance showed no difference, statistically. FTIR analysis supports the idea that the mechanism responsible for the conductivity enhancement is the partial replacement of PSS from PEDOT chain by forming a hydrogen bond with hydroxyl ion (OH) of the conductive enhancers. A SEM images showed that PEDOT:PSS is well distributed to the surface of the fabrics. Contact angle measurements showed morphology change in the samples. The conductivity was reasonably stable after 10 washing cycles. Altogether, an effective simple immersion of coated polyester fabric is presented to achieve functional textiles that offer a broad range of possible applications.
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