No abstract

In coordination-based supramolecular materials such as metallogels, simultaneous temporal and spatial control of their assembly remains challenging. Here, we demonstrate that the combination of light with acids as stimuli allows for the spatiotemporal control over the architectures, mechanical properties, and shape of porous soft materials based on metalorganic polyhedra (MOPs). First, we show that the formation of a colloidal gel network from a preformed kinetically trapped MOP solution can be triggered upon addition of trifluoroacetic acid (TFA), and that acid concentration determines the reaction kinetics. As determined by time-resolved dynamic light scattering, UV-vis absorption and 1 H NMR spectroscopies and rheology measurements, the consequences of the increase in acid concentration are (i) an increase in the cross-linking between MOPs; (ii) a growth in the size of the colloidal particles forming the gel network; (iii) an increase in the density of the colloidal network; and (iv) a decrease in the ductility and stiffness of the resulting gel. We then demonstrate that irradiation of a dispersed photoacid generator, pyranine, allows the spatiotemporal control of the gel formation by locally triggering the selfassembly process. Using this methodology, we show that the gel can be patterned into a desired shape. Such precise positioning of the assembled structures, combined with the stable and permanent porosity of MOPs, could allow their integration into devices for applications such as sensing, separation, catalysis, or drug release.

In this study, nanoporous carbon (NPC) derived from metal-organic framework was used as support for the immobilization of Burkholderia cepacia lipase. The decorated aluminum oxide within the mesoporous NPC improved the enzyme loading efficiency as well as the catalytic ability for the transesterification of soybean oil, thus making it a promising green and sustainable catalytic system for industrial application.

Successful co-immobilization of Pro and PPL on microporous MOF-1,4-NDC(Al) (PPL-Pro@MOF-1,4-NDC(Al)) has been demonstrated.

This work presents an efficient and facile strategy to prepare an α-amylase bioreactor. As enzymes are quite large to be immobilized inside metal-organic frameworks (MOFs), the tertiary and quaternary structures of α-amylase were first disrupted using a combination of urea, dithiothreitol (DTT), and iodoacetamide (IAA). After losing its tertiary structure, the unfolded proteins can now penetrate into the microporous MOFs, affording fragmented α-amylase@MOF bioreactors. Among the different MOFs evaluated, UiO-66 gave the most promising potential due to the size-matching effect of the α-helix of the fragmented α-amylase with the pore size of UiO-66. The prepared bioreactor exhibited high yields of small carbohydrate (maltose) even when reused up to 15 times (>80% conversion).

Metal-oxide semiconductor gas-sensitive sensors have various advantages as the basic devices of gas detection systems, such as high sensitivity, fast responsibility and low cost, etc. They are widely applied to many fields. Amplifier circuit is an important section of gas detection system. A new type of amplifier circuit including a three-stage operational amplifier was designed in the paper which can effectively eliminate the influence of the follow-up circuit on the sensor output. Theory analysis and experimental simulations were performed. The results show that the output voltage signals have a linear relation with the concentrations of the detected gas.

Aiming at modeling and simulation, the study of improving the performance of the method of multi-domain based on multiple interfaces of satellites by the IOCP technology were focused on. The satellite's attitude and orbit controlling simulation platform was build, with the server based on the IOCP technology build, and the designation problem of interfaces between different software solved, while the model of the satellite build, by using software , such as MATLAB / Simulink, ADAMS, Pro/E, STK and VS. Finally, the model of satellite's attitude maneuver was simulated, and the result proved the efficiency of the method of multi-domain based on multiple interfaces of satellites improved by the IOCP technology.