Platinum (Pt)‐based electrocatalysts are the benchmark catalysts for hydrogen evolution reaction (HER); however, they are limited by the scarcity and high price. Introducing an adequate substrate to disperse and anchor Pt‐based species is a feasible pathway to improve the utilization efficiency. Herein, a quick and continuous spray drying route is proposed to fabricate 3D crumpled Ti3C2Tx MXene loaded with sub‐nanometer platinum clusters (Pt/MXene). The 3D crumpled structure inhibits the restacking of layered MXene nanosheets and guarantees the fully exposure of Pt clusters. The as‐prepared catalyst exhibits excellent HER performances comparable to commercial Pt/C, including a low overpotential of 34 mV to reach a current density of 10 mA cm−2, a superior mass activity (1847 mA mgPt−1), a small Tafel slope (29.7 mV dec−1), and a high turnover frequency (10.66 H2 s−1). The improved activity of Pt/MXene can be attributed to the charge transfer from Pt clusters to MXene, which weakens the hydrogen adsorption, as evidenced by the density functional theory calculations. The present contribution proposes a novel strategy to anchor low‐mass‐loading sub‐nanometer precious metal clusters on crumpled MXene with fully exposed active sites for catalysis.
Bismuth‐based materials have been recognized as promising catalysts for the electrocatalytic CO2 reduction reaction (ECO2RR). However, they show poor selectivity due to competing hydrogen evolution reaction (HER). In this study, we have developed an edge defect modulation strategy for Bi by coordinating the edge defects of bismuth (Bi) with sulfur, to promote ECO2RR selectivity and inhibit the competing HER. The prepared catalysts demonstrate excellent product selectivity, with a high HCOO− Faraday efficiency of ≈95 % and an HCOO− partial current of ≈250 mA cm−2 under alkaline electrolytes. Density function theory calculations reveal that sulfur tends to bind to the Bi edge defects, reducing the coordination‐unsaturated Bi sites (*H adsorption sites), and regulating the charge states of neighboring Bi sites to improve *OCHO adsorption. This work deepens our understanding of ECO2RR mechanism on bismuth‐based catalysts, guiding for the design of advanced ECO2RR catalysts.
In this work, the effect of modified graphene oxide and polytetrafluoroethylene (PTFE) on the tribological and anticorrosion properties of waterborne polyurethane (WPU) was studied. The modified graphene oxide (MGO) was obtained by the surface functionalization modification of graphene oxide (GO) with isophorone diisocyanate (IPDI), and MGO/WPU composite coating and MGO-PTFE/WPU composite coating with different mass fractions of MGO were prepared. The tribological and electrochemical experiment results demonstrated that the tribological properties of the coating and the corrosion resistance of the worn coating were effectively enhanced under the synergistic effect of MGO and PTFE. Finally, a mechanism was proposed to explain the improvement in anticorrosion performance of the worn coating.
The double high index of current density and Faradaic efficiency in carbon dioxide electroreduction is a great challenge. Herein, we synthesized carburized indium oxide nanorods (In 2 O 3 -C) by pyrolysis of the metal−organic framework (MOF) precursor ]. The electronic structure of In was regulated, and the localization of negative charges was increased on the surface of the In 2 O 3 -C catalyst, resulting in a high Faradaic efficiency of 97.2% at −1.0 V vs RHE and above 90% in a wide potential range of 500 mV. Furthermore, it reached a current density of −1.0 A•cm −2 in the flow cell for producing formate efficiently. The complete reaction path from CO 2 to formate on In 2 O 3 -C was in situ investigated by attenuated total reflection surface-enhanced infrared adsorption spectroscopy and 2D/ 3D surface-enhanced Raman spectroscopy.
KVPO4F is one of the most competitive cathode candidates for potassium‐ion batteries (KIBs) because of its high output voltage and energy density. Although the gravimetric energy density of KIBs is intensively discussed in literature, little attention is paid to the volumetric energy density. In view of this, pomegranate‐like carbon‐coated KVPO4F microspheres with a high volumetric energy density are designed in this work. The nano‐sized primary particles with carbon sheets in KVPO4F microspheres enable promis rate capability by enhancing the K+ diffusion kinetics, while the micro‐sized spheres guarantee the improvement of cycling stability. Owing to the dense hierarchical microspheres, the volumetric energy density of cells is greatly improved compared to bulk materials. This cathode delivers a reversible capacity of 101.5 mA h g−1 at 0.3 C with an average output voltage of 4.0 V and a capacity retention of 85.1% after 200 cycles. The KVPO4F@C microspheres have a compact density of 2.45 g cm−3 and further offer a high volumetric energy density up to 891.3 Wh L−1. The overcharge behavior of KVPO4F in the first three cycles is also revealed. The presented KVPO4F@C microspheres cathode provides a new sight for developing KIBs with large volumetric energy density.
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