Two-dimensional/two-dimensional (2D/2D) stacking heterostructures are highly desirable in fabricating efficient photocatalysts because face-to-face contact can provide a maximized interfacial region between the two semiconductors; this largely facilitates the migration of charge carriers. Herein, a WS /graphitic carbon nitride (CN) 2D/2D nanosheet heterostructure decorated with CdS quantum dots (QDs) has been designed, for the first time. Optimized CdS/WS /CN without another cocatalyst exhibits a significantly enhanced photocatalytic H evolution rate of 1174.5 μmol h g under visible-light irradiation (λ>420 nm), which is nearly 67 times higher than that of the pure CN nanosheets. The improved photocatalytic activity can be primarily attributed to the highly efficient charge-transfer pathways built among the three components, which effectively accelerate the separation and transfer of photogenerated electrons and holes, and thus, inhibit their recombination. Moreover, the extended light-absorption range also contributes to excellent photocatalytic efficiency. In addition, the CdS/WS /CN photocatalyst shows excellent stability and reusability without apparent decay in the photocatalytic H evolution within 4 cycles in 20 h. It is believed that this work may shed light on specifically designed 2D/2D nanosheet heterostructures for more efficient visible-light-driven photocatalysts.

We have used the Auburn Global Hybrid Code in 3‐D to study the generation, dynamics, and global structure of kinetic Alfvén waves (KAWs) from the magnetotail to the ionosphere. Our results show that KAWs are generated in magnetic reconnection in the plasma sheet, located around fast flows, and carrying transverse electromagnetic perturbations, parallel Poynting fluxes, parallel currents, and parallel electric field. Overall, shear Alfvénic turbulent spectrum is found in the plasma sheet. The KAWs are shear Alfvén waves possessing short perpendicular wavelength with k⊥ρi∼1, where k⊥ is the perpendicular wave number and ρi the ion Larmor radius. The KAWs are identified by their dispersion relation and polarizations. The structures of these KAWs embedded in the plasma sheet are also revealed by placing a virtual satellite in the tail. In order to understand whether the Poynting fluxes carried by the shear Alfvén waves/KAWs in the plasma sheet can be carried directly along field lines to the ionosphere, we have tracked the wave propagation from the plasma sheet to the ionosphere. It is found that in front of the flow‐braking region, the structure and strength of the shear Alfvén waves are significantly altered due to interaction with the dipole‐like field, mainly by the flow shear associated with the azimuthal convection. Also in front of the dipole‐like field region, ion kinetic effects (Hall effects) lead to the generation of additional pairs of KAWs. As such, the generation and transport of the shear Alfvén waves/KAWs to the ionosphere are illustrated for the first time in a comprehensive manner on the global scale.

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A novel flower-like In2S3/CdIn2S4/In2O3 (ICS) ternary heterostructure (HS) is rationally constructed for the first time by a series of carefully designed procedures. In2O3 nanoflakes are the main constituent units which assemble into a flower-like skeleton structure, and CdIn2S4 nanoparticles are in situ generated on the surface of In2O3 nanoflakes through the transformation of CdS quantum dots (QDs) while In2S3 nanoparticles are in situ produced at the region between CdIn2S4 nanoparticles and In2O3 nanoflakes resulting from a synchronous sulfuration procedure. As expected, the rationally designed ICS ternary HSs display significantly enhanced photocatalytic H2 production, especially ICS5 (sulfurized for 5 h) with the highest H2 evolution rate of 20.04 μmol h-1 (10 mg catalyst is used for photocatalytic reaction), which is 26.7 times and 2.6 times higher than that of pure In2O3 (0.75 μmol h-1) and In2S3/In2O3 binary HS (7.88 μmol h-1), respectively. The enhanced photocatalytic activity can be attributed to the multiple interfaces formed in the ICS HSs, including the CdIn2S4-In2O3 interface, the In2S3-In2O3 interface, and the CdIn2S4-In2O3-In2S3 interface, which construct multiple pathways for the transfer of photogenerated charge carriers, effectively promoting the photocatalytic hydrogen production.

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Global structure and evolution of flux tube entropy S, integrated over closed field lines, associated with magnetic reconnection in the magnetotail are investigated using the AuburN Global hybrId codE in three dimensions (3‐D), ANGIE3D. Flux tubes with decreased entropy, or “bubbles,” are found to be generated due to the sudden change of flux tube topology and thus volume in reconnection. By tracking the propagation of the entropy‐depleted flux tubes, the roles of the entropy structure in plasma transport to the inner magnetosphere is examined with a self‐consistent global hybrid simulation for the first time. The value of S first decreases due to the shortening of flux tubes and then increases due to local ion heating as the bubbles are injected earthward by interchange‐ballooning instability, finally oscillating around an equilibrium radial distance where S is nearly the same as the ambient value. The pressure remains anisotropic and not constant along the flux tubes during their propagation with a nonzero heat flux along the field line throughout the duration of the simulation. The correlation of these bubbles with earthward fast flows and specific entropy s is also studied.

Coupling two semiconductors together to construct a Z-scheme type photocatalytic system is an efficient strategy to solve the serious recombination challenge of photogenerated electrons and holes. In this work, we develop a novel composite photocatalyst by sandwiching metallic 1T-phase MoS2 nanosheets between MoO3 and g-C3N4 (MoO3/1T-MoS2/g-C3N4) for the first time. The metallic 1T-phase MoS2 acts as an efficient electron mediator between MoO3 and g-C3N4 to construct an all-solid-state Z-scheme photocatalytic system, resulting in a highly-efficient spatial charge separation and transfer process. Benefiting from this, the newly developed MoO3/1T-MoS2/g-C3N4 exhibits a drastically enhanced photocatalytic H2 evolution rate of 513.0 μmol h-1 g-1 under visible light irradiation (>420 nm), which is nearly 12 times higher than that of the pure g-C3N4 (39.5 μmol h-1 g-1), and 3.5 times higher than that of MoO3/g-C3N4 (145.7 μmol h-1 g-1). More importantly, the originally unstable 1T-phase MoS2 becomes very stable in MoO3/1T-MoS2/g-C3N4 because of the sandwich structure where 1T-phase MoS2 is protected by MoO3 and g-C3N4, which endows the photocatalyst with excellent photostability. It is believed that this study will provide new insights into the design of efficient and stable Z-scheme heterostructures for photocatalytic applications.