In this paper an overview of commercial hydrogen separation technologies is given. These technologies are discussed and compared—with a detailed discussion on membrane-based technologies. An emerging and promising novel hydrogen separation technology, namely, electrochemical hydrogen separation (EHS) is reviewed in detail. EHS has many advantages over conventional separation systems (e.g., it is not energy intensive, it is environmentally-friendly with near-zero pollutants, it is known for its silent operation, and, the greatest advantage, simultaneous compression and purification can be achieved in a one-step operation). Therefore, the focus of this review is to survey open literature and research conducted to date on EHS. Current technological advances in the field of EHS that have been made are highlighted. In the conclusion, literature gaps and aspects of electrochemical hydrogen separation, that require further research, are also highlighted. Currently, the cost factor, lack of adequate understanding of the degradation mechanisms related to this technology, and the fact that certain aspects of this technology are as yet unexplored (e.g., simultaneous hydrogen separation and compression) all hinder its widespread application. In future research, some attention could be given to the aforementioned factors and emerging technologies, such as ceramic proton conductors and solid acids.

This paper reports on an experimental evaluation of the hydrogen separation performance in a proton exchange membrane system with Pt-Co/C as the anode electrocatalyst. The recovery of hydrogen from H2/CO2, H2/CH4, and H2/NH3 gas mixtures were determined in the temperature range of 100–160 °C. The effects of both the impurity concentration and cell temperature on the separation performance of the cell and membrane were further examined. The electrochemical properties and performance of the cell were determined by means of polarization curves, limiting current density, open-circuit voltage, hydrogen permeability, hydrogen selectivity, hydrogen purity, and cell efficiencies (current, voltage, and power efficiencies) as performance parameters. High purity hydrogen (>99.9%) was obtained from a low purity feed (20% H2) after hydrogen was separated from H2/CH4 mixtures. Hydrogen purities of 98–99.5% and 96–99.5% were achieved for 10% and 50% CO2 in the feed, respectively. Moreover, the use of proton exchange membranes for electrochemical hydrogen separation was unsuccessful in separating hydrogen-rich streams containing NH3; the membrane underwent irreversible damage.

Simmentaler cows grazing Cymbopogon-Themeda veld in the western Highveld region of South Africa (1985/86-1989/90) received three levels of phosphorus (P) supplementation. Dicalcium phosphate content of the supplement was manipulated to give intakes of 8 (CS), 4 (HS) or 0 (ZS) g P/cow/day during summer. All cows received supplemental P (10 g/cow/day) during winter (1986-1989). In 1990, supplemental P (10 (CW), 5 (HW) or 0 (ZW) g P/cow/day) was given in a winter maintenance supplement (protein, energy and minerals). Rainfall was above average during the trial period. Reproductive performance was not influenced by P supplementation. Mean livemass of the CS group was greatest (p < 0.01), and that of HS was greater (p < 0.01) than ZS at the end of summer. Both CS and HS had better (p < 0.01) condition scores than ZS. Bone P content was lowest and indicative of deficiency (p < 0.01) in ZS cows (112.6 vs 141.9 and 130.8 mg P/cm 3 bone for CS and HS respectively). Calf performance was not affected (p > 0.05) by P supplementation. Cow mass was affected by winter P supplementation (p < 0.05). Both CW and HW displayed improved (p < 0.01) condition scores and higher (p < 0.01) bone P content than ZW. Fatalities (4) occurred in ZW due to P deficiency (74.5 mg P/cm 3 bone), and deficiency symptoms were manifested in the entire group. Both summer and winter veld is deficient in P, which makes continuous supplementation a recommended practice in this area.

The effects of fertilization (100 kg nitrogen plus 10kg phosphorus per ha per year) of Cymbopogon-Themeda veld on certain chemical components in vitro dry-matter digestibility (IVDMD), intake by either lactating cows or steers as well as daily gain of pre-weaned calves or steers, were determined in the summer rainfall area of the Republic of South Africa.The nutritive value of fertilized veld herbage was, in terms of crude protein and acid-detergent fibre content, IVDMD and herbage intake, superior to that of unfertilized veld. Species, classified as palatable according to the literature, were more abundant on the fertilized veld than on the unfertilized veld. In spite of the fact that the stocking rate on the fertilized veld was double that of the unfertilized veld, the average daily gain (ADG) of steers on the former was higher than that of steers on the latter. There was no significant difference in the ADG of the pre-weaned calves, whose dams grazed either fertilized or unfertilized veld. It was calculated that the fertilization of veld for growing steers can (under the conditions that prevailed) be a financially viable proposition if the beef price per kg live weight amounts to at least 0·65% of the cost of fertilization per ha.

This paper describes an experimental evaluation and comparison of Pt/C and Pt-Ru/C electrocatalysts for high-temperature (100–160 °C) electrochemical hydrogen separators, for the purpose of mitigating CO poisoning. The performances of both Pt/C and Pt-Ru/C (Pt:Ru atomic ratio 1:1) were investigated and compared under pure hydrogen and a H2/CO gas mixture at various temperatures. The electrochemically active surface area (ECSA), determined from cyclic voltammetry, was used as the basis for a method to evaluate the performances of the two catalysts. Both CO stripping and the underpotential deposition of hydrogen were used to evaluate the electrochemical surface area. When the H2/CO gas mixture was used, there was a complex overlap of mechanisms, and therefore CO peak could not be used to evaluate the ECSA. Hence, the hydrogen peaks that resulted after the CO was removed from the Pt surface were used to evaluate the active surface area instead of the CO peaks. Results revealed that Pt-Ru/C was more tolerant to CO, since the overlapping reaction mechanism between H2 and CO was suppressed when Ru was introduced to the catalyst. SEM images of the catalysts before and after heat treatment indicated that particle agglomeration occurs upon exposure to high temperatures (>100 °C)