The lack of freshwater resources, or the freshwater crisis, is an important issue in the resource field. One potential green and sustainable method to solve this problem is to implement solar energy-driven water evaporation to collect freshwater. Capitalizing on the low cost, high production yield, and simplified fabrication process properties of nonstoichiometric Co2.67S4 nanoparticles, we strategically designed and synthesized a Co2.67S4-deposited Teflon (PTFE) membrane for realizing efficient solar water evaporation and photothermal antibacterial properties under light irradiation. Compared with previously reported cellulose acetate and poly­(vinylidene fluoride) membranes, the PTFE membrane displayed significantly enhanced mechanical properties. Additionally, a Co2.67S4-deposited PTFE membrane with a hydrophobic treatment (termed as the Final-PTFE membrane) exhibited excellent durability. The light-to-heat conversion efficiency (η) of water evaporation reached a value of 82% for our as-prepared Final-PTFE membrane under two sun irradiation conditions. Moreover, the antibacterial mechanism observed by scanning electron microscopy was attributed to the thermal effect, which damaged the cell wall of bacteria. Our work highlights the great potentials of the Final-PTFE membrane as a versatile system for implementing solar energy-driven photothermal water evaporation and water purification.

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A novel solid-phase microextraction (SPME) fiber was fabricated by a porous aromatic framework 48 (PAF-48)/gel hybrid material through a sol-gel process. PAF-48 is a porous organic framework (POF) material that was polymerized from 1,3,5-triphenylbenzene. The uniform pore structure, high surface area, continuous conjugate network, and hydrophobicity make PAF-48 expected to have special abilities to absorb and extract styrene as well as some other harmful volatile aromatic compounds (VACs). The PAF-48/gel-coated fiber was explored for the extraction of styrene and six VACs (benzene, toluene, ethylbenzene, and xylenes) from aqueous food simulants followed by gas chromatography (GC) separation. The fiber was found to be very sensitive for the determination of the target molecules with wide linear ranges (0.1-200 or 500 μg·kg), low limits of detection (LODs, 0.003-0.060 μg·kg), acceptable precisions (intraday relative standard deviation, RSD < 5.9%, interday RSD < 7.3%), and long lifetime (>200 times). Particularly for styrene, the PAF-48/gel-coated fiber exhibited a much lower LOD (0.006 μg·kg) compared with most of the reported fibers. Moreover, the PAF-48/gel-coated fiber had a high extraction selectivity for styrene and VACs over alcohols, phenols, aromatic amines, and alkanes and show a molecular sieving effect for the different molecule sizes. Finally, the PAF-48/gel-coated SPME fiber was successfully applied in GC for the determination of the specific migrations of styrene and VACs from polystyrene (PS) plastic food contact materials (FCMs).

Solar-driven water evaporation provides a promising solution to the energy crisis and environmental issues. Capitalizing on the high photothermal conversion efficiency and excellent resistance to strong acids or strong alkalis of Pt3Ni–S nanowires, we strategically design and prepare a flexible Pt3Ni–S-deposited Teflon (PTFE) membrane for achieving efficient strong acid/alkaline water evaporation under simulated sunlight irradiation (1 sun). By comparing the surface morphology, mechanical properties, and water evaporation performance of the as-prepared three different membranes, we have screened out a high-performance photothermal membrane that has good hydrophobicity (water contact angle = 106°), strong mechanical properties, high light-to-heat conversion efficiency (η = 80%), and excellent durability (10 cycles in a range of pH = 1.2–12). In particular, we explore the mechanism of high surface mechanical properties of the as-prepared membrane using density functional theory. The results demonstrate that the related mechanism can be ascribed to two main reasons: (1) hydrogen bonds can be formed between the 2-pyrrolidone ring and PTFE-3 and (2) the O atom in PTFE-3 carries more negative charge (−0.19 |e|) than PTFE-1 (−0.16 |e|) and PTFE-2 (−0.15 |e|). Our work highlights the great potentials of a Pt3Ni–S-deposited PTFE membrane as a device for implementing solar energy-driven evaporation of industrial wastewater with strong acidity or alkalinity and provides a new strategy for improving the surface mechanical properties of a photothermal membrane.

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