We report the synthesis of colloidal EuS, La 2 S 3 , and LaS 2 nanocrystals between 150 and 255 °C using rare-earth iodides in oleylamine. The sulfur source dictates phase selection between La 2 S 3 and LaS 2 , which are stabilized for the first time as colloidal nanocrystals. The indirect bandgap absorption of LaS 2 shifts from 635 nm for nanoellipsoids to 365 nm for square-based nanoplates. Er 3+ photoluminescence in La 2 S 3 :Er 3+ (10%) is sensitized by the semiconducting host in the 390−450 nm range. The synthetic route yields tunable compositions of rare-earth sulfide nanocrystals. Interaction of light with these novel semiconducting nanostructures hosting rare-earth emitters should be attractive for applications that require broadband sensitization of RE emitters.

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In this paper, Bi 1−x Pb x CuOS samples (0 ≤ x ≤ 0.05) have been synthesized with a simple and scalable ballmilling process, followed by a reactive Spark Plasma Sintering. Our results highlight that, Pb for Bi substitution increases the charge carriers concentration by more than 2 orders of magnitude from 1.4 × 10 17 cm −3 to 2.6 × 10 19 cm −3 for x = 0 and x = 0.05, respectively. As a result, the electrical resistivity is divided by more than 50 at room temperature and the Seebeck coefficient drops from 707 μV K −1 to 265 μV K −1 where our experimental results are supported with density functional theory (DFT) calculations. Electronic structure calculations show that, just below the top of the valence band, several other bands are present and may contribute to the transport properties with appropriate tuning of the heavy-light valence band and the position of the Fermi level. Pb doping increases the number of holes pockets and several band degeneracies appear around the Fermi level, leading to a drastic enhancement of the power factor up to 0.2 mW m −1 K −2 at 700 K. This is 5 times higher than the value of the pristine compound. The intrinsically low thermal conductivity of 0.7 W m −1 K −1 at 700 K is interpreted on the basis of vibrational properties calculations within the Density Functional Perturbation Theory (DFPT) approach. It indicates that soft acoustic modes along the Γ−Z direction suggest weak interatomic bonding between the layers and possible strong anharmonicity. The power factor being enhanced with a minimal impact on the thermal conductivity, the figure of merit ZT reaches 0.2 at 700 K for x = 0.05. To the best of our knowledge, it is considered the best reported value among the family of oxysulfides