In the Southern Ocean, high accumulation rates of opal--which forms by precipitation from silica-bearing solutions--have been found in the sediment in spite of low production rates of biogenic silica and carbon in the overlying surface waters. This so-called 'opal paradox' is generally attributed to a higher efficiency of opal preservation in the Southern Ocean than elsewhere. Here we report biogenic silica production rates, opal rain rates in the water column and opal sediment burial rates for the Indian Ocean sector of the Southern Ocean, which show that the assumed opal paradox is a result of underestimated opal production rates and overestimated opal accumulation rates. Our data thus demonstrate that the overall preservation efficiency of biogenic opal in this region is substantially lower than previously thought, and that it lies within a factor of two of the global mean. The comparison of our revised opal preservation efficiencies for the Southern Ocean with existing values from the equatorial Pacific Ocean and the North Atlantic Ocean shows that spatial differences in preservation efficiencies are not the primary reason for the differences in sedimentary opal accumulation. The reconciliation of surface production rates and sedimentary accumulation rates may enable the use of biogenic opal in the reconstruction of palaeo-productivity when the factors that affect the Si/C ratio are better understood.

International audienceA high-resolution record of paleostorm events along the French Mediterranean coast over the past 7000 years was established from a lagoonal sediment core in the Gulf of Lions. Integrating grain size, faunal analysis, clay mineralogy and geochemistry data with a chronology derived from radiocarbon dating, we recorded seven periods of increased storm activity at 6300-6100, 5650-5400, 4400-4050, 3650-3200, 2800-2600, 1950-1400 and 400-50 cal yr BP (in the Little Ice Age). In contrast, our results show that the Medieval Climate Anomaly (1150-650 cal yr BP) was characterised by low storm activity.;The evidence for high storm activity in the NW Mediterranean Sea is in agreement with the changes in coastal hydrodynamics observed over the Eastern North Atlantic and seems to correspond to Holocene cooling-in the North Atlantic. Periods of low SSTs there may have led to a stronger meridional temperature gradient and a southward migration of the westerlies. We hypothesise that the increase in storm activity during Holocene cold events over the North Atlantic and Mediterranean regions was probably due to an increase in the thermal gradient that led to an enhanced lower tropospheric baroclinicity over a large Central Atlantic-European domain. (C) 2011 University of Washington. Published by Elsevier Inc. All rights reserved

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[1] We report the last glacial-interglacial transition of marine denitrification off northern Chile based on sedimentary nitrogen isotopes. Our results show a relatively early, large and abrupt transition from low to high denitrification regimes consistent with recentlyreported data from off Peru. The deglaciation is characterized by millennial-scale adjustments of the oxygen minimum zone that mimic the atmospheric temperature record from Antarctica. We also show that the sharp denitrification onset was not caused by an increase in local primary productivity, nor by ventilation changes occurring in the Southern Ocean, as previously proposed. We found that the magnitude and timing of the deglacial denitrification changes are in close agreement with the fresh-water pulses that resulted from the melting of the Patagonian Ice Sheet. We consequently attribute the deglacial onset of marine denitrification in the area to a collapse of the thermocline ventilation occurred at the mid-latitude subduction region of the eastern South Pacific.

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A sediment core encompassing 3500 years of continuous sedimentation has been collected from a coastal lagoon located on the southwestern French Mediterranean coast. Lead concentrations and stable isotopes show that the sediments have recorded the three major periods of Pb pollution: the Etruscan-Greek-Roman period (650 BC to AD 50), the medieval period (AD 650 to AD 1450), and the modern period (from around AD 1850 to the present). These periods were separated by low pollution periods during the Dark Ages (between AD 50 and 650) and during the 16th century. From the end of the 19th century to the 1960s, Pb pollution increased exponentially. Coal combustion was the major source of Pb in the lagoon in the second half of the 20th century. Both the decrease in coal consumption and the ban on leaded gasoline resulted in a decrease in Pb pollution by a factor of 1.5 between 1973 and 1995. From 1991, sewage treatment plants and incinerators could be the major source of Pb. The average baseline Hg concentration from 1525 BC to AD 900 was 0.017 ± 0.003 μg g⁻¹ (n = 54). The Hg concentrations profile shows three major peaks: in AD 1150, AD 1660, and AD 1969, with the concentrations being respectively 8, 5, and 34 times higher than the baseline levels. The medieval peak (AD 1150) is attributed the medical use of Hg in the town of Montpellier and/or the burning of soil and vegetation. Noticeable Hg pollution was also detected during the 17th century in relation to gold and silver amalgamation in Europe. From the end of the 19th century, Hg concentrations increased exponentially until 1969. This modern pollution is attributed to the burning of coal.