570reaction with water is considerably slower. The disintegration of high-fired La203 and NdzOs ceramics is no doubt due in large part to the hydration of the A-type structure. All the C-type oxides are stable toward water at room temperature and higher; indeed the structure is so stable t h a t it is extremely difficult to convert this structure, once formed, back per square inch at temperatures where the hydrates are Undoubtedly stable. Unfortunately, although La2O, has been 19%.
It is widely reported in current literature that the precipitation hardened Al-Li sheet alloys exhibit extremely high anisotropy in yield (and ultimate tensile) strength, which is well beyond what can be explained as purely a consequence of the strong crystallographic texture in the material (e.g. J. Mater. Sci. Eng. A265, 1999, 100). This paper presents a crystal plasticity based modeling framework that will (i) facilitate the segregation of the contributions to the overall anisotropy from crystallographic texture and precipitation hardening, and (ii) correlate the contribution from precipitate hardening to either co-planar slip activity or the noncoplanar slip activity in the cold-working step prior to the aging heat treatment. More specifically, a Taylor-type (fully-constrained) crystal plasticity model was formulated to predict the yield strength of the fully processed sheet and its anisotropy, while accounting for the initial texture in the hot-worked sheet, its evolution during the cold-working step prior to aging, and the inhomogeneous nucleation of the T 1 phase platelets (these are known to form on {111} planes, but not usually in equal amounts on the different {111} planes in a given crystal). In an effort to illustrate the methodology developed in the study, a limited set of experiments was conducted on Al-Li 2090-T8E41 alloy sheet. Off-axis stretches were applied on the sheet at room temperature prior to the aging treatment, and the mechanical anisotropy in the fully processed sheets was characterized by performing tension tests on coupons cut from the sheet at 0, 30, 45, 60 and 90 to the original rolling direction (RD). Both the initial texture in the sheet and its evolution during the different off-axis stretches were characterized. The alloys processed in this study showed pronounced anisotropy. The application of the methodology developed in this study revealed that much of the observed anisotropy in this particular data set could be explained by accounting for the texture in the sample in the processed condition. Although the data set available was inadequate to establish clear correlations of the anisotropy with preferential hardening mechanisms arising from either co-planar or non-co-planar slip activity during the off-axis stretch, there were indications favoring the latter. This case study, however, illustrates the application of the methodology developed in this study to obtain better insight into the nature of the anisotropy in these sheets and its physical origin. #
This study aimed to generate data on performance characteristics for 2 real-time TaqMan PCR assays (CSIRO and WOAH WSSV qPCRs) for the purposes of (1) detection of white spot syndrome virus (WSSV) in clinically diseased prawns and (2) detection of WSSV in apparently healthy prawns. Analytical sensitivity of both assays was 2 to 20 genome copies per reaction, and analytical specificity was 100% after testing nucleic acid from 9 heterologous prawn pathogens and 4 prawn species. Results obtained after testing more than 20 000 samples in up to 559 runs with the CSIRO WSSV qPCR and up to 293 runs with the WOAH WSSV qPCR demonstrated satisfactory repeatability for both assays. Both assays demonstrated median diagnostic sensitivity (DSe) 100% (95% CI: 94.9-100%) when testing clinically diseased prawns. When 1591 test results from apparently healthy prawns were analysed by Bayesian latent class analysis, median DSe and diagnostic specificity (DSp) were 82.9% (95% probability interval [PI]: 75.0-90.2%) and 99.7% (95% PI: 98.6-99.99%) for the CSIRO WSSV qPCR and 76.8% (95% PI: 68.9-84.9%) and 99.7% (95% PI: 98.7-99.99%) for the WOAH WSSV qPCR. When both assays were interpreted in parallel, median DSe increased to 98.3 (95% PI: 91.6-99.99%), and median DSp decreased slightly to 99.4% (95% PI: 97.9-99.99%). Routine testing of quantified positive controls by laboratories in the Australian laboratory network demonstrated satisfactory reproducibility of the CSIRO WSSV qPCR assay. Both assays demonstrated comparable performance characteristics, and the results contribute to the validation data required in the WOAH validation pathway for the purposes of detection of WSSV in clinically diseased and apparently healthy prawns.
Nanocomposites have become a new paradigm for thermoelectric research in recent years and have resulted in the reduction of thermal conductivity via the nano-inclusion and grain boundary scattering. In this work, we report the preparation and thermoelectric study of SiGe-yttria stabilized zirconia (YSZ) nanocomposites prepared by Spark Plasma Sintering (SPS). We experimentally investigated the reduction of lattice thermal conductivity (κL) in the temperature range (30–800 K) of n-type Si80Ge20P2 alloys with the incorporation of YSZ nanoparticles (20–40 nm diameter) into the Si-Ge matrix. These samples synthesized by using the SPS technique were found to have densities > 95% of the theoretical density. The thermal conductivity, at both low and high temperatures, was measured by steady state and laser flash techniques, respectively. At room temperature, we observed approximately a 50% reduction in the lattice thermal conductivity as result of adding 10% YSZ by volume to the Si80Ge20P2 host matrix. A phenomenological model developed by Callaway was used to corroborate both the temperature dependence and reduction of κL over the measured temperature range (30–800 K) of both Si80Ge20P2 and Si80Ge20P2 + YSZ samples. The observed κL is discussed and interpreted in terms of various phonon scattering mechanisms such as alloy disorder, the Umklapp phonon scattering, and boundary scattering. In addition, a contribution from the phonon scattering by YSZ nanoparticles was further included to account for the κL of Si80Ge20P2 + YSZ sample. The theoretical calculations are in reasonably good agreement with the experimental results for both the Si80Ge20P2 and Si80Ge20P2 + YSZ alloys.
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