Flow in the separation bubble formed along the sides of a blunt flat plate with right-angled corners has been studied in terms of extensive single- and two-point measurements of velocity and surface-pressure fluctuations. The cross-correlations between the surface-pressure and velocity fluctuations are found to be useful for the study of large-scale vortex structure in the bubble. Large-scale vortices are shed downstream from the separation bubble with a frequency of about 0.6U∞/xR, where U∞ is the approaching velocity and xR is the time-mean length of the bubble. On top of this regular vortex shedding, there exists a large-scale unsteadiness in the bubble. Vortices which are much larger than the regular vortices are shed with frequencies less than about 0.2U∞/xR. The large-scale unsteadiness is accompanied by enlargement and shrinkage of the bubble and also by a flapping motion of the shear layer near the separation line. The intermittent nature of the flow in the bubble is clarified in some detail. The distributions of the cross-correlations between the pressure and velocity fluctuations demonstrate the vortex structure in the reattaching zone. The longitudinal distance between the vortices is estimated to be (0.7–0.8) xR and their convection velocity is about 0.5U∞ near the reattachment line. The cross-correlations also suggest the existence of a longitudinal counter-rotating system in the bubble. The distance between the axes of the rotation is of the order of 0.6xR. Variations of timescales, lengthscales and phase velocities of the vortices are presented and discussed.

This paper describes experiments concerning the structure of large-scale vortices and the unsteady reverse-flow properties in the reattaching zone of a nominally two-dimensional separation bubble formed at the leading edge of a blunt flat plate with right-angled corners. The experiment was performed in a wind tunnel with a constant Reynolds number 2.6 × 104 (based on the main-flow velocity and the thickness of the plate). Split-film probes, being sensitive to instantaneous reversals of flow direction, were extensively employed. An important feature of this study is a judicious use of surface-pressure fluctuations as a conditioning signal to educe the structure of the large-scale vortices.Distributions of fluctuating-velocity vectors and contour lines of high-frequency turbulent energy in a few space–time domains are presented and discussed. The most economical interpretation of these space-time distributions is that the large-scale vortices in the reattaching zone are hairpin vortices whose configuration is sketched in the text. The unsteady flow in the reattaching zone is mainly governed by two agents; the motion of the large-scale vortices and the low-frequency unsteadiness. The unsteady flow is clarified in terms of the motion (in a space–time domain) of zeros of the longitudinal velocity close to the surface of the plate; the effects of the two agents on this motion are presented separately. On the basis of these results, a mathematical model of the unsteady flow in the reattaching zone is suggested and found to yield good comparison with measured reverse-flow intermittency and frequency of local-flow reversals. It appears that the separation bubble experiences shrinkage and enlargement in connection with the low-frequency unsteadiness and that the speed of shrinkage is much greater than that of enlargement. The strength of the large-scale vortices in the reattaching zone seems to be dependent on the phase of the low-frequency unsteadiness.

Perfluorooctanoate and Perfluorooctane Sulfonate Concentrations in Surface Water in Japan: Norimitsu Saito, et al. Institute for Environmental Sciences and Public Health of Iwate Prefecture—Perfluorooctanoate (PFOA) and perfluorooctane sulfonate (PFOS) are synthetic surfactants used in Japan. An epidemiological study of workers exposed to PFOA revealed a significant increase in prostate cancer mortality. A cross‐sectional study of PFOA‐exposed workers showed that PFOA perturbs sex hormone homeostasis. We analyzed their concentrations in surface water samples collected from all over Japan by LC/MS with a solid phase extraction method. The lowest limits of detection (LOD) (ng/L) were 0.06 for PFOA and 0.04 for PFOS. The lowest limits of quantification (LOQ) (ng/L) were 0.1 for both analytes. The levels [geometric mean (GM); geometric standard deviation (GS)] (ng/L) of PFOA and PFOS in the surface waters were GM (GS): 0.97 (3.06) and 1.19 (2.44) for Hokkaido‐Tohoku (n=16); 2.84(3.56) and 3.69 (3.93) for Kanto (n=14); 2.50 (2.23) and 1.07 (2.36) for Chubu (n=17); 21.5 (2.28) and 5.73 (3.61) for Kinki (n=8); 1.51 (2.28) and 1.00 (3.42) for Chugoku (n=9); 1.93 (2.40) and 0.89 (3.09) for Kyushu‐Shikoku (n=15). The GM of PFOA in Kinki was significantly higher than in other areas (ANOVA p<0.01). Systematic searches of Yodo and Kanzaki Rivers revealed two highly contaminated sites, a public‐water‐disposal site for PFOA and an airport for PFOS. The former was estimated to release 18 kg of PFOA/d. PFOA in drinking water in Osaka city [40 (1.07) ng/L] was significantly higher than in other areas. The present study confirms that recognizable amounts of PFOA are released in the Osaka area and that people are exposed to PFOA through drinking water ingestion.

Two predominant perfluorinated compounds (PFCs), Perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA), in surface water (SW, 0-20 cm), subsurface water (SSW, > 30 cm depth), and sea surface microlayer (SML, 50 microm thickness) were measured from Dalian Coastal waters in China. The SML samples were collected using glass-plate dipping method. Analysis of the PFCs was conducted through solid-phase extraction, followed by LC/MS-SIM. The PFC's concentrations in SW samples were consistent with previously reported data in this region. Significantly higher concentrations of PFCs were found in SML samples than corresponding SSW samples. The enrichment factors (EF = C(SML)/C(SSW)) for PFOS were as high as 24-109 atthree near-shore sites. The concentration in SW was also generally higher than corresponding SSW samples, giving C(SW)/C(SSW) mean ratios of 1.5 and 1.4 for PFOS and PFOA, respectively. This apparent enrichment of PFCs in surface water, especially in the microlayer, has implications for designing measurement techniques, understanding their distributions, and sea spray-mediated transport in the environment.

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