This study uses high-resolution radar and surface observations to investigate the finescale structural evolution of airflow and precipitation over complex terrain in the Pyeongchang area, South Korea. The Taebaek Mountain range (TMR) runs parallel to the northeastern coast of South Korea, with a perpendicular ridge known as the Pyeongchang branch (PCB). The objective of this study was to identify the mechanisms of wintertime precipitation over these topographic features during the passage of a low pressure system (LPS) through the southern Korean Peninsula. The analysis indicates that intense precipitation occurred over the southwestern and northeastern sides of the TMR during stage I but only over the northeastern side during stage II. The prevailing southwesterly winds were dominated by warm advection associated with the LPS over the PCB during stage I. These prevailing southwesterly winds locally enhanced precipitation on the southwestern end of the PCB; multiple influences of mountain waves, airflow convergence, and drifted particles are possible factors for causing precipitation on the northeastern side of the TMR. During stage II, the prevailing winds changed from easterlies to northeasterlies offshore from Gangneung. The easterly winds decelerated and were deflected locally along the mountainous coast, and this blocked zone interacted with the oncoming flow to trigger a precipitation band. Consequently, the northeasterly winds helped push the precipitation band toward the coast, causing heavy precipitation in Gangneung. The observational evidence presented shows that the interaction of temporally changing winds accompanying the movement of an LPS over topography is a critical factor for determining the distribution and intensity of precipitation.

Continued efforts are made in improving the performance of the low-cost forward osmosis (FO) membrane process which utilizes naturally available osmotic pressure of the draw solution (DS) as the driving force. Selection of a suitable DS and development of a better performing membrane remained the main research focus. In this study, the performance of a hollow fiber forward osmosis (HFFO) membrane was evaluated with respect to various operating conditions such as different cross-flow directions, membrane orientation, solution properties, and solution flow rates (Reynolds number). The study observed that operating parameters significantly affect the performance of the FO process. FO comparatively showed better performance at counter-current orientation. NaCl, KCl, and NH 4 Cl were evaluated as DS carrying common anion. Properties of the anionic part of the DS were found important for flux outcome, whereas reverse solute flux (RSF) was largely influenced by the properties of DS cationic part. FO was operated at different DS and feed solution (FS) flow rates and FO outcome was assessed for varying DS and FS Reynolds number ratio. FO showed better flux outcome as Re ratio for DS and FS decreases and vice versa. Results indicated that by adjusting FO processes conditions, HFFO membrane could achieve significantly lower specific RSF and higher water flux outcome. It was observed that using 2 M NaCl as DS and deionized water as FS, HFFO successfully delivered flux of 62.9 LMH which is significantly high compared to many FO membranes reported in the literature under the active layer-DS membrane orientation mode.

Abstract. Snowfall in the northeastern part of South Korea is the result of complex snowfall mechanisms due to a highly contrasting terrain combined with nearby warm waters and three synoptic pressure patterns. All these factors together create unique combinations, whose disentangling can provide new insights into the microphysics of snow on the planet. This study focuses on the impact of wind flow and topography on the microphysics drawing of 20 snowfall events during the ICE-POP 2018 (International Collaborative Experiment for PyeongChang 2018 Olympic and Paralympic winter games) field campaign in the Gangwon region. The vertical structure of precipitation and size distribution characteristics are investigated with collocated MRR (micro rain radar) and PARSIVEL (particle size velocity) disdrometers installed across the mountain range. The results indicate that wind shear and embedded turbulence were the cause of the riming process dominating the mountainous region. As the strength of these processes weakens from the mountainous region to the coastal region, riming became less significant and gave way to aggregation. This study specifically analyzes the microphysical characteristics under three major synoptic patterns: air–sea interaction, cold low, and warm low. Air–sea interaction pattern is characterized by more frequent snowfall and vertically deeper precipitation systems on the windward side, resulting in significant aggregation in the coastal region, with riming featuring as a primary growth mechanism in both mountainous and coastal regions. The cold-low pattern is characterized by a higher snowfall rate and vertically deep systems in the mountainous region, with the precipitation system becoming shallower in the coastal region and strong turbulence being found in the layer below 2 km in the mountainous upstream region (linked with dominant aggregation). The warm-low pattern features the deepest system: precipitation here is enhanced by the seeder–feeder mechanism with two different precipitation systems divided by the transition zone (easterly below and westerly above). Overall, it is found that strong shear and turbulence in the transition zone is a likely reason for the dominant riming process in the mountainous region, with aggregation being important in both mountainous and coastal regions.

The performance of recently developed polyamide thin film composite hollow fibre forward osmosis (HFFO) membrane module was assessed for the desalination of brackish groundwater (BGW) for fertigation. Four different fertilisers were used as draw solution (DS) with real BGW from the Murray-Darling Basin in Australia. Membrane charge and its electrostatic interactions with ions played a significant role in the performance of the HFFO module using fertiliser as DS. Negatively charged polyamide layer promotes sorption of multivalent cations such as Ca 2+ enhancing ion flux and membrane scaling. Inorganic scaling occurred both on active layer and inside the support layer depending on the types of fertiliser DS used resulting in severe flux decline and this study therefore underscores the importance of selecting suitable fertilisers for the fertiliser drawn forward osmosis (FDFO) process. Water flux under active layer DS membrane orientation was about twice as high as the other orientation indicating the need to further optimise the membrane support structure formation. Water flux slightly improved at higher crossflow rates due to enhanced mass transfer on the fibre lumen side. At 45% packing density, HFFO could have three times more membrane area and four times more volumetric flux output for an equivalent 8040 cellulose triacetate flat-sheet FO membrane module.

Abstract. Ground-based radar and radiometer data observed during the 2017–2018 winter season over the Pyeongchang area on the east coast of the Korean Peninsula were used to simultaneously estimate both the cloud liquid water path and snowfall rate for three types of snow clouds: near-surface, shallow, and deep. Surveying all the observed data, it is found that near-surface clouds are the most frequently observed cloud type with an area fraction of over 60 %, while deep clouds contribute the most in snowfall volume with about 50 % of the total. The probability distributions of snowfall rates are clearly different among the three types of clouds, with the vast majority hardly reaching 0.3 mm h−1 (liquid water equivalent snowfall rate) for near-surface, 0.5 mm h−1 for shallow, and 1 mm h−1 for deep clouds. However, the liquid water paths in the three types of clouds all have the substantial probability to reach 500 g m−2. There is no clear correlation found between snowfall rate and the liquid water path for any of the cloud types. Based on all observed snow profiles, brightness temperatures at Global Precipitation Measurement Microwave Imager (GPM/GMI) channels are simulated, and the ability of a Bayesian algorithm to retrieve snowfall rate is examined using half the profiles as observations and the other half as an a priori database. Under an idealized scenario, i.e., without considering the uncertainties caused by surface emissivity, ice particle size distribution, and particle shape, the study found that the correlation as expressed by R2 between the “retrieved” and “observed” snowfall rates is about 0.32, 0.41, and 0.62, respectively, for near-surface, shallow, and deep snow clouds over land surfaces; these numbers basically indicate the upper limits capped by cloud natural variability, to which the retrieval skill of a Bayesian retrieval algorithm can reach. A hypothetical retrieval for the same clouds but over ocean is also studied, and a major improvement in skills is found for near-surface clouds with R2 increasing from 0.32 to 0.52, while a smaller improvement is found for shallow and deep clouds. This study provides a general picture of the microphysical characteristics of the different types of snow clouds and points out the associated challenges in retrieving their snowfall rate from passive microwave observations.

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DNA microspheres formed by self-assembly of DNA three-way junctions with self-complementary sticky-ends undergo an unexpected dynamic transformation from filled spheres into hollow capsules upon addition of cationic surfactants such as cetyltrimethylammonium bromide.

Hyperbranched polymers with (N,N-diethylamino)dithiocarbamoyl (DC) units as peripheral groups (HBP-DC) spontaneously form nanospheres in aqueous silver nitrate. Although HBP-DC itself is insoluble in water, coordination of Ag(I) ions to surface DC units imparts cationic charges which make Ag(I)/ HBP-DC complexes dispersible in water and drive their self-assembly into nanospheres. These Ag(I)/HBP-DC complexes show binding of hydrophobic guest molecules in the course of self-assembly. When mixtures of tetraphenylporphyrin (TPP) and HBP-DC in THF are added to aqueous silver nitrate, intense fluorescence of TPP was observed. As TPP molecules form nonluminescent aggregates when injected in water, the luminescence observed in aqueous Ag(I)/HBP-DC nanospheres indicates that TPP molecules are confined in the hydrophobic interior of aqueous nanospheres. The surface of Ag(I)/HBP-DC nanospheres, meanwhile, serve as scaffolds to produce silver nanocrystals. The Ag(I)-DC complexes formed on the surface of Ag(I)/ HBP-DC nanospheres undergo photoreduction, which give small silver nanocrystals evenly distributed on nanospheres. The size and density of silver nanocrystals are tunable depending on the reaction condition. The coordination-assisted self-assembly of HBPs provides a simple and useful means to develop aqueous nanospheres whose interior and exterior surfaces are readily modifiable. It offers up considerable possibilities for their application as polymer-inorganic integrated vessels.