With the increasing demand for multispectral information acquisition, infrared multispectral imaging technology that is inexpensive and can be miniaturized and integrated into other devices has received extensive attention. However, the widespread usage of such photodetectors is still limited by the high cost of epitaxial semiconductors and complex cryogenic cooling systems. Here, we demonstrate a noncooled two-color infrared photodetector that can provide temporal-spatial coexisting spectral blackbody detection at both near-infrared and mid-infrared wavelengths. This photodetector consists of vertically stacked back-to-back diode structures. The two-color signals can be effectively separated to achieve ultralow crosstalk of ~0.05% by controlling the built-in electric field depending on the intermediate layer, which acts as an electron-collecting layer and hole-blocking barrier. The impressive performance of the two-color photodetector is verified by the specific detectivity (D*) of 6.4 × 109 cm Hz1/2 W−1 at 3.5 μm and room temperature, as well as the promising NIR/MWIR two-color infrared imaging and absolute temperature detection.

Low‐symmetry 2D materials with unique anisotropic optical and optoelectronic characteristics have attracted a lot of interest in fundamental research and manufacturing of novel optoelectronic devices. Exploring new and low‐symmetry narrow‐bandgap 2D materials will be rewarding for the development of nanoelectronics and nano‐optoelectronics. Herein, sulfide niobium (NbS3), a novel transition metal trichalcogenide semiconductor with low‐symmetry structure, is introduced into a narrowband 2D material with strong anisotropic physical properties both experimentally and theoretically. The indirect bandgap of NbS3 with highly anisotropic band structures slowly decreases from 0.42 eV (monolayer) to 0.26 eV (bulk). Moreover, NbS3 Schottky photodetectors have excellent photoelectric performance, which enables fast photoresponse (11.6 µs), low specific noise current (4.6 × 10−25 A2 Hz−1), photoelectrical dichroic ratio (1.84) and high‐quality reflective polarization imaging (637 nm and 830 nm). A room‐temperature specific detectivity exceeding 107 Jones can be obtained at the wavelength of 3 µm. These excellent unique characteristics will make low‐symmetry narrow‐bandgap 2D materials become highly competitive candidates for future anisotropic optical investigations and mid‐infrared optoelectronic applications.

Benefit from high quantum efficiency and low dark current, blocked-impurity-band (BIB) detectors have been the state-of-the-art choice in astronomy science. The temperature extrinsic-response-reduction mechanism in BIB detectors is vague for lack of pertinent research. We fabricated Si:P BIB detectors with a remarkable blackbody detectivity of 2 × 1012 cm · Hz1/2/W at 4 K, 2 V (blackbody 800 K). Both varying temperature optoelectronic characterization and calculated results overturn the common standpoint that focuses on ionization proportion. Instead, solid evidence indicates that the increase in the negative charge density according to temperature significantly influences the width of the depletion region until it totally vanishes beyond 20 K. The mechanism enriches the design thoughts of the BIB detector for improving its performance.

Silicon-based blocked impurity band (BIB) detectors have become the preferred candidate for the astronomical observation field because of their excellent ability for far-infrared detection, easy integration with the readout circuit, and potential for large-scale preparation. We fabricate Si:Ga BIB far-infrared detectors by a molecular beam epitaxy technique with an impressive blackbody specific detectivity of 4.21 × 1011 cm Hz1/2 W−1 at 10 K and nearly uniform broadband response between 2.5 and 20  μm. A response mechanism with variable temperature is described minutely by the varying temperature optoelectronic characterization and theoretical calculation as well as energy band diagram. The substantial results indicate that the responsivity of the detector can steadily maintain up to 26 K for far-infrared. This paper not only increases the accessibility of BIB detectors' fabrication tools but also provides an approach of high-operating temperature far-infrared detectors for astronomy explorations.