In this review, we survey the state of the art on polymeric foams incorporating nano-scale fillers. Particular focus of the review is on foams from polyolefinic nanocomposite formulations incorporating a wide variety of fillers. The nano-scale additives can influence the foam structure and properties in two ways: Firstly, they can act as composite reinforcement to enhance the mechanical properties and functionality of the matrix polymer; and secondly, they can act as foaming-processing aids through modification of the rheological, thermal and crystallization properties of the matrix as well as serving as heterogeneous nucleation sites. Through a combination of these influences, and using advanced processing techniques it is possible to achieve nanocomposite foams that have higher cell density, and more uniform cell size or controlled cell-size distribution. Such controlled foam morphologies, in turn, can yield better specific mechanical properties resulting in more effective light-weighting solutions. Further, the nano-scale additives can impart additional desired functionality resulting in multi-functional foams. In this article, we provide an overview of the mechanical, thermal and a few other relevant functional properties – such as piezoelectric sensitivity, acoustics, and filtration efficiency – of foams prepared using nanocomposite formulations, along with the processing considerations for achieving high quality foams using such materials.
The broad objective of this work was to demonstrate a modelling and simulation framework for foam blow molding using commercially available simulation software. The simulation framework would have to account for the initial morphology of the foam, the relationship between the morphology and the rheological and deformation characteristics of the foam at high temperatures and high strains that are typically encountered during blow molding, and correlate the strains developed during blow molding to the morphological aspects in the resulting blow molded part. These aspects are addressed in this paper using simulations of uniaxial tensile deformation of a virtual representative volume element of a foam microstructure (rendered in DIGIMAT-FE) to derive the nonlinear tensile response of the foam at high temperatures (using ABAQUS). The resulting simulated stress-strain curve is employed to parameterize a nonlinear rheological constitutive equation. These parameters are then employed for the homogenized representation of the foam in the blow molding simulation carried out in B-SIM, a commercially available simulation software for blow molding. The regions where the simulated parison has undergone primarily uniaxial elongation are then mapped back to the expected local foam morphology using the transfer functions derived from the RVE simulations. These steps result in a preliminary and simple demonstration of the simulation framework, and offer a template that can be detailed further with experimental rheological information on actual foamed parisons, and more detailed post-processing algorithms to correlate multiaxial elongations with microstructure.
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