No abstract

No abstract

Zircon OD-3 from the Paleogene Kawamoto Granodiorite (Mihara body) in Japan has been identified as a potential multi-grain secondary standard for U-Pb dating. We have carried out an inter-laboratory evaluation in order to evaluate possible heterogeneity amongst the OD-3 zircon grains. U-Pb ages were obtained using two analytical techniques (a sensitive high-resolution ion microprobe and a laser ablation-inductively coupled plasma-mass spectrometry) in eight laboratories. All the 238 U-206 Pb ages show good agreement, with an overall weighted average 238 U-206 Pb age of 33.0 Ϯ 0.1 Ma (2s). The U-Pb age results revealed no significant variation or heterogeneity in the U-Pb ages of the OD-3 grains. Twelve fission-track (FT) ages from three laboratories are also reported, and have a weighted average of 32.6 Ϯ 0.6 Ma (2s). Despite the different closure and annealing temperatures of the U-Pb and FT chronometers, respectively, the FT age is in good agreement with the U-Pb age. This suggests that the OD-3 zircon had a relatively fast cooling history and has not experienced later thermal annealing. The chronological dataset reported here clearly demonstrates that the OD-3 zircon could be a useful and reliable secondary standard for use during U-Pb dating studies of Cenozoic zircons.

No abstract

No abstract

No abstract

No abstract

Carbonate concretions occur in sedimentary rocks of widely varying geological ages throughout the world. Many of these concretions are isolated spheres, centered on fossils. The formation of such concretions has been variously explained by diffusion of inorganic carbon and organic matter in buried marine sediments. However, details of the syn-depositional chemical processes by which the isolated spherical shape developed and the associated carbon sources are little known. Here we present evidence that spherical carbonate concretions (diameters φ : 14 ~ 37 mm) around tusk-shells (Fissidentalium spp.) were formed within weeks or months following death of the organism by the seepage of fatty acid from decaying soft body tissues. Characteristic concentrations of carbonate around the mouth of a tusk-shell reveal very rapid formation during the decay of organic matter from the tusk-shell. Available observations and geochemical evidence have enabled us to construct a ‘Diffusion-growth rate cross-plot’ that can be used to estimate the growth rate of all kinds of isolated spherical carbonate concretions identified in marine formations. Results shown here suggest that isolated spherical concretions that are not associated with fossils might also be formed from carbon sourced in the decaying soft body tissues of non-skeletal organisms with otherwise low preservation potential.