Backscattering experiments at microwave frequencies were conducted off the west coast of Scotland in the summer of 1991. Using a dual-polarization, eightfrequency, X band, coherent scatterometer mounted on the bow of a boat, we measured time-resolved backscattering from ocean waves at a range of grazing angles from 10 ø to 70 ø. From the grazing-angle-dependent signals and their Doppler spectra, we are able to differentiate Bragg scattering from non-Bragg scattering and resolve "peak separation" between the vertical and horizontal polarizations. We observe instances of "super" events, i.e., instances when the horizontal polarization return power equals or exceeds the vertical polarization power at particular frequencies. We find that "super" events occur not only at low grazing angles but at any grazing angle for upwind viewing directions and obtain statistics for such occurrences as a function of grazing angle. We study the coherence properties of scatterers and find strong evidence that at low grazing angles, lifetime-dominated, non-Bragg scattering contributes noticeably to returns of both polarizations, but is dominant in providing returns for the horizontal polarization. We examine "spiking" events and find that they can be related to, but need not be limited to, breaking wave events. By comparing the data of upwind runs with cross-wind and circle runs, we obtain wind direction dependence of Doppler spectra, which further assists in the identification of scattering mechanisms. 2591 2592 LEE ET AL.' X BAND MICROWAVE BACKSCATTERING FROM OCEAN WAVESTable 1. Frequency Pairs for Microwave Scatterometer Polarization, GHz Pair Vertical Horizontal 1 9.020 9.021 2 9.170 9.171 3 9.320 9.321 4 9.470 9.471 four quadrature mixers, one for each transmitted frequency. Each mixer generates an in-phase (I) and quadrature (Q) signal with a frequency response of 0 to 1000 Hz. With complex amplitude thus generated for each frequency, there are 16 channels of output. During an experiment the 16 signals are recorded digitally on a multichannel cassette recorder.An absolute calibration of the scatterometer system [Barter et al., 1993] was conducted in a large (10 m x 10 m x 30 m) anechoic chamber using spheres and cylinders of various sizes as well as corner reflector targets. Measurements consisted of establishing the output power and receiver gain of each of the eight frequency channels, the system radiation patterns in two perpendicular planes in the forward half sphere, the range dependence of the signal power, and the cross-polarization isolation of the scatterometer system. The essential results of the calibration are as follows: total power (eight channels), -1 W; nominal receiver gain each channel, -60 dB; system radiation pattern, approximately Gaussian main lobe; azimuthal plane -3 dB beam width, 8.7 ø for VV and 10.3 ø for HH; vertical plane -3 dB beam width, 11 ø for VV and 9.6 ø for HH; average -3 dB beam width, 9.5ø; antenna gain, 26.6 dB; cross-polarization isolation, >35 dB; image rejection ratio, --45 dB. As an ex...

Crystallographic dislocation has been well-known to be one of the major causes responsible for the unfavorable carrier dynamics in conventional semiconductor devices. Halide perovskite has exhibited promising applications in optoelectronic devices. However, how dislocation impacts its carrier dynamics in the ‘defects-tolerant’ halide perovskite is largely unknown. Here, via a remote epitaxy approach using polar substrates coated with graphene, we synthesize epitaxial halide perovskite with controlled dislocation density. First-principle calculations and molecular-dynamics simulations reveal weak film-substrate interaction and low density dislocation mechanism in remote epitaxy, respectively. High-resolution transmission electron microscopy, high-resolution atomic force microscopy and Cs-corrected scanning transmission electron microscopy unveil the lattice/atomic and dislocation structure of the remote epitaxial film. The controlling of dislocation density enables the unveiling of the dislocation-carrier dynamic relation in halide perovskite. The study provides an avenue to develop free-standing halide perovskite film with low dislocation density and improved carried dynamics.

The polarization of light can exhibit unusual features when singular optical beams are involved. In 3-dimensional polarized random media the polarization orientation around singularities describe 1/2 or 3/2 Möbius strips. It has been predicted that if singular beams intersect non-collinearly in free space, the polarization ellipse rotates forming many-turn Möbius strips or twisted ribbons along closed loops around a central singularity. These polarization features are important because polarization is an aspect of light that mediate strong interactions with matter, with potential for new applications. We examined the non-collinear superposition of two unfocused paraxial light beams when one of them carried an optical vortex and the other one a uniform phase front, both in orthogonal states of circular polarization. It is known that these superpositions in 2-dimensions produce space-variant patterns of polarization. Relying on the symmetry of the problem, we extracted the 3-dimensional patterns from projective measurements, and confirmed the formation of many-turn Möbius strips or twisted ribbons when the topological charge of one of the component beams was odd or even, respectively. The measurements agree well with the modelings and confirmed that these types of patterns occur at macroscopic length scales and in ordinary superposition situations.

First principles methods are used to explicitly calculate the nonlinear susceptibility (χ(2)(2ω, ω, ω)) representing the second harmonic generation (SHG) of two dimensional semiconducting materials, namely transition metal dichalcogenides (TMDs) and Boron Nitride (BN). It is found that alloying TMDs improves their second harmonic response, with MoTeS alloys exhibiting the highest of all hexagonal alloys at low photon energies. Moreover, careful examination of the relationship between the concentration of Se in MoxSeySz alloys shows that the SHG intensity can be tuned by modifying the stoichiometry. In addition, materials with curvature can have large second harmonic susceptibility. Of all the calculated monolayer structures, the hypothetical TMD Haeckelites NbSSe and Nb0.5Ta0.5S2 exhibit the highest χ(2), while one of the porous 3D structures constructed from 2D hBN exhibits a larger χ(2) than known large band gap 3-D materials.

Monolayer transition metal dichalcogenides (TMDs) possess superior optical properties, including the valley degree of freedom that can be accessed through the excitation light of certain helicity. While WS2 and WSe2 are known for their excellent valley polarization due to the strong spin-orbit coupling, the optical bandgap is limited by the ability to choose from only these two materials. This limitation can be overcome through the monolayer alloy semiconductor, WS2xSe2(1-x), which promises an atomically thin semiconductor with tunable bandgap. In this work, we show that the high-quality BN encapsulated monolayer WS0.6Se1.4 inherits the superior optical properties of tungsten-based TMDs, including a trion splitting of ~ 6 meV and valley polarization as high as ~60%. In particular, we demonstrate for the first time the emerging and gate-tunable interlayer electron-phonon coupling in the BN/WS0.6Se1.4/BN van der Waals heterostructure, which renders the otherwise optically silent Raman modes visible. In addition, the emerging Raman signals can be drastically enhanced by the resonant coupling to the 2s state of the monolayer WS0.6Se1.4 A exciton. The BN/WS2xSe2(1-x)/BN van der Waals heterostructure with a tunable bandgap thus provides an exciting platform for exploring the valley degree of freedom and emerging excitonic physics in two-dimension.