The tunnel magnetoresistance (TMR) effect in magnetic tunnel junctions (MTJs) is the key to developing magnetoresistive random-access-memory (MRAM), magnetic sensors and novel programmable logic devices. Conventional MTJs with an amorphous aluminium oxide tunnel barrier, which have been extensively studied for device applications, exhibit a magnetoresistance ratio up to 70% at room temperature. This low magnetoresistance seriously limits the feasibility of spintronics devices. Here, we report a giant MR ratio up to 180% at room temperature in single-crystal Fe/MgO/Fe MTJs. The origin of this enormous TMR effect is coherent spin-polarized tunnelling, where the symmetry of electron wave functions plays an important role. Moreover, we observed that their tunnel magnetoresistance oscillates as a function of tunnel barrier thickness, indicating that coherency of wave functions is conserved across the tunnel barrier. The coherent TMR effect is a key to making spintronic devices with novel quantum-mechanical functions, and to developing gigabit-scale MRAM.

Magnetoresistance (MR) ratio up to 230% at room temperature (294% at 20 K) has been observed in spin-valve-type magnetic tunnel junctions (MTJs) using MgO tunnel barrier layer fabricated on thermally oxidized Si substrates. We found that such a high MR ratio can be obtained when the MgO barrier layer was sandwiched with amorphous CoFeB ferromagnetic electrodes. Microstructure analysis revealed that the MgO layer with (001) fiber texture was realized when the MgO layer was grown on amorphous CoFeB rather than on polycrystalline CoFe. Since there have been no theoretical studies on the MTJs with a crystalline tunnel barrier and amorphous electrodes, the detailed mechanism of the huge tunneling MR effect observed in this study is not clear at the present stage. Nevertheless, the present work is of paramount importance in realizing high-density magnetoresistive random access memory and read head for ultra high-density hard-disk drives into practical use.

When an electric current passes from one ferromagnetic layer via a non-magnetic layer into another ferromagnetic layer, the spin polarization and subsequent rotation of this current can induce a transfer of angular momentum that exerts a torque on the second ferromagnetic layer 1-4 . This provides a potentially useful method to reverse 3,5-7 and oscillate 8 the magnetic momenta in nanoscale magnetic structures. Owing to the large current densities required to observe spin-torqueinduced magnetization switching and microwave emission (∼10 7 A cm −2 ), accurately measuring the strength, or even the direction, of the associated spin torque has proved difficult. Yet, such measurements are crucial to refining our understanding of the mechanisms responsible and the theories that describe them 9,10 . To address this, we present quantitative experimental measurements of the spin torque in MgO-based magnetic tunnel junctions 11-14 for a wide range of bias currents covering the switching currents. The results verify the occurrence of two different spin-torque regimes with different bias dependences that agree well with theoretical predictions 10 .Magnetic tunnel junctions (MTJs) consisting of a MgO insulating layer sandwiched between two ferromagnetic layers (S 1 and S 2 in Fig. 1a) were used to provide very large magnetoresistance 11,14 . Such MTJs are now useful as data storage cells in magnetic random-access memories (M-RAMs) and as magnetic-field sensors in magnetic hard disk drives [11][12][13] . The MTJs with a layer structure of Ir-Mn/Co-Fe/Ru/Co 60 Fe 20 B 20 /MgO/Co 60 Fe 20 B 20 were prepared on a MgO substrate using an ultrahigh-vacuum sputtering system (C-7100; Canon ANELVA). The 3-nm-thick bottom Co-Fe-B layer (S 1 ) acts as a spin polarizer. The top Co-Fe-B layer (S 2 ), a 2-nm-thick free layer, is excited by the spin torque. The MgO tunnel barrier is about 1 nm thick. The MTJs are rectangular with dimensions of approximately 70 nm × 250 nm (see the Methods section for preparation details).Resistance-magnetic-field (R-H ) curves measured at a small bias voltage (0.1-0.3 mV) and different in-plane field directions, that is, θ H = 0 and 45 • , are shown in Fig. 1b. θ H is the angle between the applied field direction and the easy axis of the magnetic cell along the long axis of the rectangular cell (see Fig. 1a). The magnetoresistance ratio is defined as MR = (R AP − R P )/R P , where R P and R AP respectively represent resistance in the parallel and antiparallel magnetization alignments of S 1 and S 2 . A positive bias current denotes electron flow from S 2 to S 1 . The magnetoresistance ratio and R P at a small bias voltage are, respectively, 154% and about 120 (R P × (Junction area) = 2 µm 2 ). Figure 1c shows the bias voltage, V b , dependence of the tunnelling resistance, as measured in four different fields (A-D), which are indicated by arrows in Fig. 1b. For antiparallel alignment (curves A and B), the resistance decreases with increasing V b because new tunnelling channels open at higher bias voltages 1...

The acid ionization of HCl in water is examined via a combination of electronic structure calculations with ab initio molecular orbital methods and Monte Carlo computer simulations. The following key features are taken into account in the modeling:  the polarization of the electronic structure of the solute reaction system by the solvent, the quantum character of the proton nuclear motion, the solvent fluctuation and reorganization along with the solvent polarization effects on the proton potential, and a Grotthuss mechanism of the aqueous proton transfer. The mechanism is found to involve the following:  first, a nearly activationless motion in a solvent coordinate, which is adiabatically followed by the quantum proton rather than tunneling, to produce a contact ion pair Cl-−H3O+, which is stabilized by ∼7 kcal/mol; second, motion in the solvent with a small activation barrier, as a second adiabatic proton transfer produces a solvent-separated ion pair from the contact ion pair in a nearly thermoneutral process. Motion of a neighboring water moleculeto accommodate the change of the primary coordination number from 4 for H2O to 3 for H3O+ of a proton-accepting water moleculeis indicated as a key feature in the necessary solvent reorganizations. It is estimated, via a separate argument, that the remainder of the process to produce the completely separated ions involves a free energy change of less than 1 kcal/mol. It is argued that the reorganization of the heavy atoms between which the proton transfers plays an essential role in assisting the adiabatic (nontunneling) and stepwise transfer mechanism and that the concerted pathway of the multiple proton transfers in water is unfavorable.

Spin-polarized current can excite the magnetization of a ferromagnet through the transfer of spin angular momentum to the local spin system. This pure spin-related transport phenomenon leads to alluring possibilities for the achievement of a nanometer scale, complementary metal oxide semiconductor-compatible, tunable microwave generator that operates at low bias for future wireless communication applications. Microwave emission generated by the persistent motion of magnetic vortices induced by a spin-transfer effect seems to be a unique manner to reach appropriate spectral linewidth. However, in metallic systems, in which such vortex oscillations have been observed, the resulting microwave power is much too small. In this study, we present experimental evidence of spin-transfer-induced vortex precession in MgObased magnetic tunnel junctions, with an emitted power that is at least one order of magnitude stronger and with similar spectral quality. More importantly and in contrast to other spintransfer excitations, the thorough comparison between experimental results and analytical predictions provides a clear textbook illustration of the mechanism of spin-transfer-induced vortex precession.

Combinatorial laser molecular-beam epitaxy method was employed to fabricate epitaxial ZnO thin films doped with all the 3d transition metal (TM) ions in a high throughput fashion. The solubility behavior of TM ions was discussed from the viewpoints of the ionic radius and valence state. The magneto-optical responses coincident with absorption spectra were observed for Mn- and Co-doped samples. Cathodoluminescence spectra were studied for Cr-, Mn-, Fe-, and Co-doped samples, among which Cr-doped ZnO showed two sharp peaks at 2.97 eV and 3.71 eV, respectively, at the expense of the exciton emission peak of pure ZnO at 3.25 eV. Different magnetoresistance behavior was observed for the samples codoped with n-type carriers. Ferromagnetism was not observed for Cr- to Cu-doped samples down to 3 K.

Fully epitaxial Co(001)∕MgO(001)∕Co(001) magnetic tunnel junctions (MTJs) with metastable bcc Co(001) electrodes were fabricated with molecular beam epitaxy. The MTJs exhibited giant magnetoresistance (MR) ratios up to 410% at room temperature, the highest value reported to date. Temperature dependence of the MR ratio was observed to be very small compared with fully epitaxial Fe∕MgO∕Fe and textured CoFeB∕MgO∕CoFeB MTJs. The MR ratio of the Co∕MgO∕Co MTJ showed larger bias voltage dependence than that of the epitaxial Fe∕MgO∕Fe MTJs, which probably reflects the band structures of bcc Co and Fe for the k‖=0 direction.

The magnetic and magneto-optical properties of a Cr-doped II-VI semiconductor ZnTe were investigated. Magnetic circular dichroism measurements showed a strong interaction between the sp carriers and localized d spins, indicating that Zn(1-x)Cr(x)Te is a diluted magnetic semiconductor. The Curie temperature of the film with x=0.20 was estimated to be 300+/-10 K, which is the highest value ever reported for a diluted magnetic semiconductor in which sp-d interactions were confirmed. In spite of its high Curie temperature, Zn(1-x)Cr(x)Te film shows semiconducting electrical transport properties.