A luminescent solar concentrator (LSC) is a potential low‐cost enhancement of the standard large‐area silicon photovoltaic panels for the generation of electricity from sunlight. In this work, guest–host systems are investigated using anisotropic fluorescent dyes and liquid crystal mesogens to control the direction of emitted light in the LSC. It is determined that up to 30% more light is emitted from the edge of an LSC waveguide with planar dye alignment parallel to the alignment direction than from any edge of an LSC with no alignment (isotropic). The aligned samples continue to show dichroic performance after additions of both edge mirrors and rear scattering layer.
Liquid drops on textured surfaces show different dynamical behaviors depending on their wetting states. They are extremely mobile when they are supported by composite solid-liquid-air interfaces (Cassie-Baxter state) and immobile when they fully wet the textured surfaces (Wenzel state). By reversibly switching between these two states, it will be possible to achieve control over the fluid dynamics. Unfortunately, these wetting transitions are usually prevented by surface energy barriers. We demonstrate here a new, simple design paradigm consisting of parallel grooves with an appropriate aspect ratio that allows for the controlled, barrierless, reversible switching of the wetting states upon application of electrowetting. We report a direct observation of the barrierless dynamical pathway for the reversible transitions between the Wenzel (collapsed) and Cassie-Baxter (suspended) states and present a theory that accounts for these transitions, including detailed lattice Boltzmann simulations.
The influence of a retro-reflective texture cover on light in-coupling and light-trapping in thin film silicon solar cells is investigated. The texture cover is applied to the front glass of the cell and leads to a reflectance as low as r % 3% by reducing the reflection at the air/glass interface and indirectly also reducing the reflections from the internal interfaces. For weakly absorbed light in the long wavelength range, the texture also enhances the light-trapping in the solar cell. We demonstrate an increase of the short circuit current density of exemplary investigated thin film silicon tandem solar cells by up to 0.95 mA cm À2 and of the conversion efficiency by up to 0.74% (absolute). For a planar microcrystalline solar cell, the enhancement of light-trapping was determined from the reduced reflection in the long wavelength range to be up to 17%, leading to an increase of the external quantum efficiency of up to 12%.
The light collection in thin film polymer solar cells is substantially improved by application of a textured retroreflective foil, which reduces primary reflection and outcoupling of unabsorbed light. Consequently the external quantum efficiency (EQE) improves over the whole sensitivity range and the power conversion efficiency is improved by as much as 19%.
Photoembossing is a convenient and economical process to form complex surface relief structures in polymer thin films. We have improved the aspect ratio of photoembossed microstructures by adding t-butyl hydroquinone (TBHQ) to the polymerization mixture. The mechanism that is proposed is based on the radical transfer principle, where TBHQ converts acrylate radicals into stable phenol radicals that at elevated temperatures act as latent initiators, thereby controlling the kinetics without changing the number of polymerization active sites. As a result, the aspect ratio can be improved with a factor of 5–7 in comparison with previously proposed similar processes.
Table of contentWe record contact line motion of ink-jet printed drops spreading and evaporating on surfaces patterned with polygonal microposts and, aided by lattice Boltzmann simulations, explain the drop shapes in terms of interface pinning at posts.
AbstractWe present results showing how water drops, produced by ink-jet printing, spread on surfaces patterned with lattices of diamond or triangular posts. Considering post widths typically ~7 m and lattice spacings between 15-40 m, we observe drop shapes with 3,4 and 6-fold symmetry, depending on both the symmetry of the lattice and the shape of the posts. This is a result of the different mechanisms of interface pinning and depinning which depend on the direction of the contact line motion with respect to the post shape. Lattice Boltzmann simulations are used to describe these mechanisms in detail for triangular posts. We also follow the motion of the contact line as the drops evaporate showi ng that they tend to return to their original shape. To explain this we show that the easy direction for movement is the same for sprea ding and drying drops. We compare the behaviour of small drops with that of larger drops created by jetting several drops at the same position. We find that the contact line motion is unexpectedly insensitive to drop volume, even when a spherical cap of fluid forms above the posts. The findings are relevant to m icro-fluidic applications and to the control of drop shapes in i nk-jet printing.
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