The reaction of Li2S and P2S5 with Li4[SnS4], a recently discovered, good Li(+) ion conductor, yields Li10SnP2S12, the thiostannate analogue of the record holder Li10GeP2S12 and the second compound of this class of superionic conductors with very high values of 7 mS/cm for the grain conductivity and 4 mS/cm for the total conductivity at 27 °C. The replacement of Ge by Sn should reduce the raw material cost by a factor of ~3.

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The spatial distribution of charge carriers in lithium ion batteries during current flow is of fundamental interest for a detailed understanding of transport properties and the development of strategies for future improvements of the electrolyte-electrode interface behaviour. In this work we explored the potential of (7)Li 1D in situ NMR imaging for the identification of concentration gradients under constant current load in a battery cell. An electrochemical cell based on PTFE body and a stack of glass microfiber discs that are soaked with a technically relevant electrolyte suitable for high-temperature application and squeezed between a Li metal and a nano-Si-graphite composite electrode was assembled to acquire (7)Li 1D in situ NMR profiles with an improved NMR pulse sequence as function of time and state of charge, thereby visualizing the course of ion concentration during charge and discharge. Surface localized changes of Li concentration were attributed to processes such as solid electrolyte interphase formation or full lithiation of the composite electrode. The method allows the extraction of lithium ion transport properties.

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Voltage noise not only detracts from reliability and performance, but has been used to attack system security. Most systems are completely unaware of fluctuations occurring on nanosecond time scales. This paper quantifies the threat to FPGA-based systems and presents a solution approach. Novel measurements of transients on 28nm FPGAs show that extreme activity in the fabric can cause enormous undershoot and overshoot, more than 10× larger than what is allowed by the specification. An existing voltage sensor is evaluated and shown to be insufficient. Lastly, a sensor design using reconfigurable logic is presented; its timeto-digital converter enables sample rates 500× faster than the 28nm Xilinx ADC. This enables quick characterization of transients that would normally go undetected, thereby providing potentially useful data for system optimization and helping to defend against supply voltage attacks.

Quantum annealing is a proposed combinatorial optimization technique meant to exploit quantum mechanical effects such as tunneling and entanglement. Real-world quantum annealing-based solvers require a combination of annealing and classical pre- and post-processing; at this early stage, little is known about how to partition and optimize the processing. This article presents an experimental case study of quantum annealing and some of the factors involved in real-world solvers, using a 504-qubit D-Wave Two machine and the graph isomorphism problem. To illustrate the role of classical pre-processing, a compact Hamiltonian is presented that enables a reduced Ising model for each problem instance. On random N-vertex graphs, the median number of variables is reduced from N2 to fewer than N log2 N and solvable graph sizes increase from N = 5 to N = 13. Additionally, error correction via classical post-processing majority voting is evaluated. While the solution times are not competitive with classical approaches to graph isomorphism, the enhanced solver ultimately classified correctly every problem that was mapped to the processor and demonstrated clear advantages over the baseline approach. The results shed some light on the nature of real-world quantum annealing and the associated hybrid classical-quantum solvers.

Electronic systems on a chip increasingly suffer from component variation, voltage noise, thermal hotspots, and other subtle physical phenomena. Systems with reconfigurability have unique opportunities for adapting to such effects. Required, however, are low-cost, fine-grained methods for sensing physical parameters. This article presents powerful, novel approaches to online sensing, including methods for designing compact reconfigurable sensors, low-cost threshold detection, and several enhanced measurement procedures. Together, the approaches help enable systems to autonomously uncover a wealth of physical information. A highly efficient counter and improved ring oscillator are introduced, enabling an entire sensor node in just 8 Virtex-5 LUTs. We describe how variations can be measured in delay, temperature, switching-induced IR drop, and leakage-induced IR drop. We demonstrate the proposed approach with an experimental system based on a Virtex-5, instrumented with over 100 sensors at an overhead of only 1.3%. Results from thermally controlled experiments provide some surprising insights and illustrate the utility of the approach. Online sensing can help open the door to physically adaptive computing, including fine-grained power, reliability, and health management schemes for systems on a chip. ACM Reference Format:Zick, K. M. and Hayes, J. P. 2012. Low-cost sensing with ring oscillator arrays for healthier reconfigurable systems.

Several lines of evidence suggest that β-cyclodextrin (β-CD) derivatives initiate the efflux of accumulated, unesterified cholesterol from the late endosomal/lysosomal compartment in Niemann Pick C (NPC) disease models. Unfortunately, repeated injections or continuous infusions of current β-CD therapies are required to sustain suppression of symptoms and prolong life. In an effort to make CD treatment a more viable option by boosting efficacy and improving pharmacokinetics, a library of Pluronic surfactant-based β-CD polyrotaxanes has been developed using biocompatible poly(ethylene glycol) (PEG)–polypropylene glycol (PPG)–PEG triblock copolymers. These compounds carry multiple copies of β-CD as shown by 1H NMR, 2D nuclear Overhouser effect spectroscopy, gel permeation chromatography/multiangle light scattering, analytical ultracentrifugation analysis, matrix assisted laser desorption/ionization mass spectrometry, and diffusion-ordered spectroscopy. Analyses of free β-cyclodextrin contamination in the compounds were made by reverse phase high pressure liquid chromatography and hydrophilic interaction liquid chromatography. Dethreading kinetics were studied by reverse phase high pressure liquid chromatography, UV/vis, and 1H NMR analysis. Filipin staining studies using npc2−/− fibroblasts show significant reversal of cholesterol accumulation after treatment with polyrotaxane compounds. The rate and efficacy of reversal is similar to that achieved by equivalent amounts of monomeric β-CD alone.