Klaus Pohl scite author profile

An extraordinary cation with eight FeIII centres is contained in the title compound. It has been characterized X‐ray crystallographically as the first FeIII‐oligomer with more than three centres. Besides the strong bridging by oxo‐ and hydroxo‐groups the “hydrophobization” of the surface by the six amine ligands is worthy of note. In the crystal, seven of the eight Br⊖ ions and a H2O molecule are associated with the cation—it can thus be regarded as a bromide‐ion bearing complex monocation.

show abstract

[{(C₆H₁₅N₃)Fe}₂(μ‐O)(μ‐CH₃CO₂)₂]²⁺ a Dinuclear Iron, (III)Complex with a Metazidohemerythrin‐Type Structure

Wieghardt

Pohl

Gebert

1983

Angew. Chem. Int. Ed. Engl.

141

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Klaus Pohl

Sensitization of highly porous, polycrystalline TiO2 electrodes by quantum sized CdS

Synthesis and characterization of (.mu.-hydroxo)bis(.mu.-acetato)diiron(II) and (.mu.-oxo)bis(.mu.-acetato)diiron(III) 1,4,7-trimethyl-1,4,7-triazacyclononane complexes as models for binuclear iron centers in biology; properties of the mixed valence diiron(II,III) species

Preparation and magnetism of the binuclear iron(II) complexes [{Fe(C9H21N3)X2}2](X = NCS, NCO, or N3) and their reaction with NO. Crystal structures of [{Fe(C9H21N3)(NCS)2}2] and [Fe(C9H21N3)(NO)(N3)2]

Hydrolysis Products of the Monomeric Amine Complex (C₆H₁₅N₃)FeCl₃: The Structure of the Octameric Iron(III) Cation of {[(C₆H₁₅N₃)₆Fe₈(μ₃‐O)₂(μ₂‐OH)₁₂]Br₇(H₂O)}Br·8H₂O

[{(C₆H₁₅N₃)Fe}₂(μ‐O)(μ‐CH₃CO₂)₂]²⁺ a Dinuclear Iron, (III)Complex with a Metazidohemerythrin‐Type Structure

Contact Info

Product

Resources

About

Klaus Pohl

Sensitization of highly porous, polycrystalline TiO2 electrodes by quantum sized CdS

Synthesis and characterization of (.mu.-hydroxo)bis(.mu.-acetato)diiron(II) and (.mu.-oxo)bis(.mu.-acetato)diiron(III) 1,4,7-trimethyl-1,4,7-triazacyclononane complexes as models for binuclear iron centers in biology; properties of the mixed valence diiron(II,III) species

Preparation and magnetism of the binuclear iron(II) complexes [{Fe(C9H21N3)X2}2](X = NCS, NCO, or N3) and their reaction with NO. Crystal structures of [{Fe(C9H21N3)(NCS)2}2] and [Fe(C9H21N3)(NO)(N3)2]

Hydrolysis Products of the Monomeric Amine Complex (C6H15N3)FeCl3: The Structure of the Octameric Iron(III) Cation of {[(C6H15N3)6Fe8(μ3‐O)2(μ2‐OH)12]Br7(H2O)}Br·8H2O

[{(C6H15N3)Fe}2(μ‐O)(μ‐CH3CO2)2]2+ a Dinuclear Iron, (III)Complex with a Metazidohemerythrin‐Type Structure

Contact Info

Product

Resources

About

Hydrolysis Products of the Monomeric Amine Complex (C₆H₁₅N₃)FeCl₃: The Structure of the Octameric Iron(III) Cation of {[(C₆H₁₅N₃)₆Fe₈(μ₃‐O)₂(μ₂‐OH)₁₂]Br₇(H₂O)}Br·8H₂O

[{(C₆H₁₅N₃)Fe}₂(μ‐O)(μ‐CH₃CO₂)₂]²⁺ a Dinuclear Iron, (III)Complex with a Metazidohemerythrin‐Type Structure