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There is great concern for contamination of sensitive ecosystems in high latitudes by long-range transport of heavy metals and other pollutants derived from industrial areas in lower latitudes. Atmospheric pollution of heavy metals has a very long history, and since metals accumulate in the environment, understanding of present-day pollution conditions requires knowledge of past atmospheric deposition. We use analyses of lead concentrations and stable lead isotopes ( 206 Pb/ 207 Pb ratios) of annually laminated sediments from four lakes in northern Sweden (∼65°N) to provide a decadal record of atmospheric lead pollution for the last 3000 years. There is a clear signal in the sediments of airborne pollution from Greek and Roman cultures 2000 years ago, followed by a period of "clean" conditions 400-900 A.D. From 900 A.D. there was a conspicuous, permanent increase in atmospheric lead pollution fallout. The sediments reveal peaks in atmospheric lead pollution at 1200 and 1530 A.D. comparable to present-day levels. These peaks match the history of metal production in Europe. This study indicates that the contemporary atmospheric pollution climate in northern Europe was established in Medieval time, rather than in the Industrial period. Atmospheric lead pollution deposition did not, when seen in a historical perspective, increase as much as usually assumed with the Industrial Revolution (1800 A.D.).

The Northern Norrbotten Ore Province in northernmost Sweden includes the type localities for Kirunatype apatite iron deposits and has been the focus for intense exploration and research related to Fe oxide-Cu-Au mineralisation during the last decades. Several different types of Fe-oxide and Cu-Au±Fe oxide mineralisation occur in the region and include: stratiform Cu±Zn±Pb±Fe oxide type, iron formations (including BIF´s), Kirunatype apatite iron ore, and epigenetic Cu±Au±Fe oxide type which may be further subdivided into different styles of mineralisation, some of them with typical IOCG (Iron Oxide-Copper-Gold) characteristics. Generally, the formation of Fe oxide±Cu±Au mineralisation is directly or indirectly dated between ~2.1 and 1.75 Ga, thus spanning about 350 m.y. of geological evolution.The current paper will present in more detail the characteristics of certain key deposits, and aims to put the global concepts of Fe-oxide Cu-Au mineralisations into a regional context. The focus will be on iron deposits and various types of deposits containing Fe-oxides and Cu-sulphides in different proportions which generally have some characteristics in common with the IOCG style. In particular, ore fluid characteristics (magmatic versus non-magmatic) and new geochronological data are used to link the ore-forming processes with the overall crustal evolution to generate a metallogenetic model. Rift bounded shallow marine basins developed at ~2.1-2.0 Ga following a long period of extensional tectonics within the Greenstone-dominated, 2.5-2.0 Ga Karelian craton. The ~1.9-1.8 Ga Svecofennian Orogen is characterised by subduction and accretion from the southwest. An initial emplacement of calc-alkaline magmas into ~1.9 Ga continental arcs led to the formation of the Haparanda Suite and the Porphyrite Group volcanic rocks. Following this early stage of magmatic activity, and separated from it by the earliest deformation and metamorphism, more alkali-rich magmas of the Perthite Monzonite Suite and the Kiirunavaara Group volcanic rocks were formed at ~1.88 Ga. Subsequently, partial melting of the middle crust produced large volumes of ~1.85 and 1.8 Ga S-type granites in conjunction with subduction related A-/I-type magmatism and associated deformation and metamorphism. A C C E P T E D M A N U S C R I P T ACCEPTED MANUSCRIPTIn our metallogenetic model the ore formation is considered to relate to the geological evolution as follows. Iron formations and a few stratiform sulphide deposits were deposited in relation to exhalative processes in rift bounded marine basins. The iron formations may be sub-divided into BIF-(banded iron formations) andMg-rich types, and at several locations these types grade into each other. There is no direct age evidence to constrain the deposition of iron formations, but stable isotope data and stratigraphic correlations suggest a formation within the 2.1-2.0 Ga age range. The major Kiruna-type ores formed from an iron-rich magma (generally with a hydrothermal over-print) and are restricted to areas occup...

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This article presents the results of a comprehensive provenance study based on a combined geochemical-isotopic and archaeological approach, comprising 98 analyses of 97 copper-alloy objects from the Danish Bronze Age. When it comes to the question of the origin of the metal, our interpretations diverge somewhat from earlier established theories about the origin of copper imported to Denmark, which mainly pointed to Central and Eastern Europe. Clear geochronological patterns in the Danish dataset are interpreted as being due to shifts in ore sources; reflecting varying areas of origin as well as the utilization of varying ore types. This again relates to shifting trade networks/suppliers and shifting technological trends. Plausible sources for Danish copper-alloys identified in the current study are ore regions in the British Isles, Alpine ore districts in Italy and Austria, as well as ore regions in the western part of the Mediterranean and to some degree the Slovak Carpathians. The comparison includes hundreds of recently published lead isotope data for ores in Slovakia, the Iberian Peninsula and the Italian and Austrian Alps.

Keywords: Gabbroic rocks Crustal recycling Variscan orogeny Uthospheric mantle Spanish Central SystemThe gabbroic intrusions that crop out along the Spanish Central System (SCS) are geochemically heterogeneous, including primitive and evolved rocks. Differentiation is mainly related to fractionation of Cr-spinel and olivine, but mixing with coeval granitic magmas or crustal assimilation may have also played a role in the evolution of the most differentiated rocks. The most primitive uncontaminated gabbros show arc like trace element chondrite and primitive-mantle normalised patterns, characterised by large ion Iithophile elements (ULE)-Iigh t rare earth elements (tREE) enrichment, Sr and Pb positive and Nb-Ta-Ti negative anomalies. However, paleogeographic constraints suggest that the SCS was located far from subduction zones, so these geochemical signatures could be better explained by a recycling of continental crustal components within the mantle. The most primitive SCS gabbros expand the Sr-Nd isotopic compositional range of the Variscan basic magmatism in the Central Iberian Zone to more depleted values. This reflects a heterogeneous sub-continental Iithospheric mantle under central Spain ranging from a depleted mantle (ENd = +3.1. 87Sr/86Sr= 0.704) towards an isotopically enriched component (ENd = -1.6, 87Sr/ 86Sr = 0.706). Geochemical modelling suggests that mantle enrichment could be explained by minor lower crustal metapelitic granulite contamination (-2%). Additionally. the Sr-Nd-Pb isotopic ratios of the most primitive gabbros match the composition of the European subcontinental lithospheric mantle recorded in ultramafic xenoliths from western and central Europe.

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