Dye-sensitized quantum dots (QDs) are promising candidates for dye-sensitized solar cells (DSSCs). Here, we report steady state (absorption and photoluminescence) optical measurements on several sizes of CdS QDs ligated with Coumarin 343 dye (C-343) and two different solvents, viz., chloroform and toluene. We further report detailed first principles density functional theory and time-dependent density functional theory studies of the geometric, electronic and optical (absorption and emission) properties of three different sized capped QDs, ligated with C-343 dye. The absorption spectrum shows a QD-size-independent peak, and another peak which shifts to blue with decrease in QD size. The first peak is found to arise from the dye molecule and the second one from the QD. Charge transfer using natural transition orbitals (NTOs) is found to occur from dye-to-QDs and is solvent-dependent. In the emission spectra, the luminescence intensity of the dye is quenched by the addition of the QD indicating a strong interaction between the QD and the dye.
Abstract-The effect of temperature on the photonic band gap has been investigated. One dimensional photonic crystal in the form of Si/air multilayer system has been studied in this communication. The refractive index of silicon layers is taken as a function of temperature and wavelength both. Therefore, this study may be considered to be physically more realistic. It may be useful for computing the optical properties for wider range of wavelength as well as temperature. We can use the proposed structure as temperature sensing device, narrow band optical filter and in many optical systems.
Abstract-A simple design of one dimensional gradual stacked photonic crystal (GSPC) structure has been proposed. The proposed structure consists of a periodic array of alternate layers of SiO 2 and Si as the materials of low and high refractive indices respectively. The structure considered here has three stacks of periodic structures with five layers each. The lattice period of successive stack is increased by a certain multiple (say gradual constant, γ) of the lattice period of the just preceding stack. For numerical computation, the transfer matrix method (TMM) has been employed. It is found that such a structure has wider reflection bands in comparison to a conventional dielectric PC structure, and the width of the omni-directional reflection (ODR) bands can be enlarged by increasing the value of the gradual constant. Hence, a GSPC structure can be used as a broadband omnidirectional reflector, and the bandwidth of omni-directional gaps can be tuned to a desired wavelength region by choosing appropriate value of γ.
In this paper, some studies on one-dimensional plasma photonic crystal (PPC) containing alternate layers of dielectric and micro-plasma have been presented. The band structures, reflectivity, group velocities and effective group index of such photonic crystals have been studied. For the purpose of computation, we have used transfer matrix method. In this study, we take two PPC structures named PPC1 and PPC2. In PPC1, we take SiO 2 as the material for the dielectric layers whereas in PPC2, we take TiO 2 as the material for the dielectric layers. It is found that the forbidden band gap(s) can be increased by increasing the thickness of plasma layers. The ranges of 100% reflection is found to be in the higher normalized frequency region in the case of PPC1 whereas in PPC2 the ranges of 100% reflection is found in the lower normalized frequency region. It is also found that for a certain normalized frequency, the group velocity becomes negative in both PPCs. However, the range of normalized frequency for which the group velocity is negative is larger in the case PPC1 than in PPC2. This abnormal behaviour of group velocities of both PPCs results in superluminal propagation (speed of EM wave in PPC greater than speed of light) of electromagnetic waves. Also, because of the abnormal behaviour of group velocity, effective group index becomes negative and possesses ultra high values. Such structures may be considered as a flip flop as there is positive and negative symmetry of effective group velocity. Also, PPC2 exhibits superluminal propagation Corresponding author: V. Kumar (vrpcommon@yahoo.com). 228Kumar, Singh, and Ojha for wider range of normalized frequency where there is superluminal propagation inside the structure as compared to that of PPC1.
Transmission of electromagnetic waves through a Si-based one dimensional photonic crystal has been investigated. The proposed structure works as an omni-directional reflector for a certain range of wavelength for an angle of incidence up to 55˚. The structure works as a narrow band TM-polarization filter for an angle of incidence more than 55˚, i.e. a filter which completely blocks TE-polarized waves but allows certain wavelengths of TM-polarized waves. But at an angle of incidence of 89˚, the structure works as a multiple narrow band TM-polarization filter even though no defect layer is introduced inside the structure. It is also found that this multiple narrow pass-bands of TM-polarized waves can be tuned to a desired range of wavelength by changing the temperature of the structure.
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