The solvatochromic ThTCF probe responds to anion coordination. Correlations of UV/Vis data from ThTCF with various basicity-related polarity scales (Kamlet-Taft β, Freire EHB, Laurence β1) allow an evaluation of their physical significance.
The synthesis of organic–inorganic hybrid materials, microporous carbon and fluorine-doped mesoporous silica by the twin polymerization of pentacoordinated fluoridosilicates is reported.
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