Porous ceramics of lead zirconate titanate (PZT) were prepared by sintering powder compacts consisting of PZT and stearic acid powders in an air atmosphere; stearic acid was added as a pore‐forming agent (PFA). The dielectric, elastic and piezoelectric properties of uniformly porous PZT ceramics were investigated as a function of the porosity volume fraction. Furthermore, a beam‐shaped PZT actuator sample with a graded porosity content across its thickness was fabricated by sintering PFA‐graded powder compacts. The electric‐field‐induced bending displacement characteristics of the actuator samples were measured by using strain gauges and were found to be in good agreement with the theoretical predication based on a classical lamination theory.
As a model for composite materials of piezoelectric ceramic and metal, lead zirconate titanate (PZT) and platinum (Pt) particulate composites were fabricated by power processing. The electrical and mechanical properties of the PZT–Pt composites were measured as a function of the Pt volume fraction. The relative dielectric constants of the PZT–Pt composites increased markedly, while the piezoelectric constants and electromechanical coupling coefficients decreased with increasing Pt content. When the Pt volume fraction exceeded 30%, the PZT–Pt composite became electrically conductive because of percolation of the Pt particles. The Pt-dispersed PZT composites enhanced the mechanical properties, particularly the high fracture resistance, compared to the monolithic PZT ceramics.
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