High conductivity, large mechanical strength, and elongation are important parameters for soft electronic applications. However, it is difficult to find a material with balanced electronic and mechanical performance. Here, a simple method is developed to introduce ion-rich pores into strong hydrogel matrix and fabricate a novel ionic conductive hydrogel with a high level of electronic and mechanical properties. The proposed ionic conductive hydrogel is achieved by physically cross-linking the tough biocompatible polyvinyl alcohol (PVA) gel as the matrix and embedding hydroxypropyl cellulose (HPC) biopolymer fibers inside matrix followed by salt solution soaking. The wrinkle and dense structure induced by salting in PVA matrix provides large stress (1.3 MPa) and strain (975%). The well-distributed porous structure as well as ion migration-facilitated ion-rich environment generated by embedded HPC fibers dramatically enhances ionic conductivity (up to 3.4 S m −1 , at f = 1 MHz). The conductive hybrid hydrogel can work as an artificial nerve in a 3D printed robotic hand, allowing passing of stable and tunable electrical signals and full recovery under robotic hand finger movements. This natural rubber-like ionic conductive hydrogel has a promising application in artificial flexible electronics.

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In this study, a highly stable air-operating ionic polymer-metal composite (IPMC) actuator with consecutive channels suitable for transportation of the cations and anions of ionic liquids was prepared by introducing and removing copper foam. The electromechanical properties of this novel porous IPMC were investigated. Scanning electron microscopy observation showed that channels and pores ranging in size from ∼100 nm to ∼50 μm were distributed in the Nafion membrane. The porous IPMC was doped with 1-ethyl-3-methylimidazolium thiocyanate ionic liquid. A larger capacitance (285.00 mF cm −2 ) was obtained, which can be attributed to the electric double layer generated at the interface between the ionic polymer membrane and platinum electrode under the input voltage. The fast ion migration channels, high conductivity, and large capacitance enabled high strain of 0.051%-0.666%, a relatively large blocking force of 17.63 mN, and excellent actuation durability for more than 180 000 cycles to be achieved. Furthermore, a soft gripper consisting of a bio-inspired micropillar dry adhesive glued on one surface of the porous IPMC assembled with a mobile mechanical arm was fabricated, and the soft gripper successfully grabbed objects with various features.

Vertically-aligned carbon nanotubes (VACNTs) have extraordinary structural and mechanical properties, and have been considered as potential candidates for creating dry adhesives inspired by adhesive structures in nature. Catalytic chemical vapor deposition is widely used to grow VACNTs; however, the influential mechanism of VACNT preparation parameters (such as H 2 concentration) on its adhesion property is not clear, making accurate control over the structure of VACNTs adhesive an ongoing challenge. In this article, we use electron beam-deposited SiO 2 /Al 2 O 3 as a support layer, Fe as catalyst, and C 2 H 4 /H 2 gas mixtures as a feed gas to prepare VACNTs, while varying the ratio of the reducing atmosphere (H 2 ) from 0% to 35%. VACNTs synthesized at a 15% H 2 concentration (5 mm × 5 mm in size) can support a maximal weight of 856 g, which indicates a macroscopic shear adhesive strength of 34 N/cm 2 . We propose a hydrogen-concentration-dependent model for the shear adhesive performance of VACNTs. By adjusting the amount of hydrogen present during the reaction, the morphology and quality of the prepared VACNTs can be precisely controlled, which significantly influences its shear adhesive performance. These results are advantageous for the application of carbon nanotubes as dry adhesives.

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