Polymer hydrogels with intense yet tunable fluorescence are of great research interest due to their wide potential use in biological imaging, sensing, information storage, etc. However, the conventional fluorophores such as naphthalimide and its derivatives are usually not recommended to prepare highly fluorescent hydrogels because of their aggregation-caused quenching (ACQ) nature and spontaneous tendency to undergo fluorescence self-quenching in quasi-solid-state hydrogel systems. Additionally, local regulation over fluorescent behavior of hydrogels, despite being important, still remains underdeveloped. Herein, we report highly fluorescent polymeric hydrogels based on conventional ACQ-type naphthalimide fluorophores, followed by spatial and temporal control of their fluorescent behavior. The hydrogels were prepared by one-pot radical copolymerization of naphthalimide-containing monomer and acrylamide in chitosan−acetic acid solution. Their intense emission comes from synergetic anchoring and diluting effect of the protonated naphthalimide moieties grafted on polymer chains, which result in the electrostatic repulsion among ACQ luminogens and reduced PET (photoinduced electron transfer) effect from adjacent dimethylamine groups to naphthalimide fluorophores. After being deprotonated in alkaline conditions, both PET and the ACQ effect work again to greatly quench fluorescence, endowing the hydrogels with pH-sensitive emission behavior. These properties encourage us to develop a diffusion-reaction (D-R) method to spatially and temporally control their fluorescent behavior. Based on these results, the ion-transfer-printing-assisted D-R method was further developed to fabricate many high-precision and meaningful fluorescent patterns on hydrogels. These fluorescent patterns are invisible under daylight but become vivid under specific UV light illumination, suggesting their wide potential applications in information security and transmission.
Recently, attempts have been made to develop ionic polymer–metal composite (IPMC), which is garnering growing interest for ionic artificial muscle, as a soft actuator and sensor due to its inherent properties of low weight, flexibility, softness, and particularly, its efficient transformation of electrical energy into mechanical energy, with large bending strain response under a low activation voltage. In this paper, we focused on several current deficiencies of IPMC that restrict its application, such as non-standardized preparation steps, relaxation under DC voltage, solvent evaporation, and poor output force. Corresponding solutions to overcome the abovementioned problems have recently been proposed from our point of view and developed through our research. After a brief introduction to the working mechanism of IPMC, we here investigate the key factors that influence the actuating performance of IPMC. We also review the optimization strategies in IPMC actuation, including those for preparation steps, additive selection for a thick casting membrane, solvent substitutes, water content, encapsulation, etc. With consideration of the role of the interface electrode, its effects on the performance of IPMC are revealed based on our previous work. Finally, we also discuss IPMCs as potential sensors theoretically and experimentally. The elimination of the deficiencies of IPMC will promote its applications in soft robotics.
In this study, a highly stable air-operating ionic polymer-metal composite (IPMC) actuator with consecutive channels suitable for transportation of the cations and anions of ionic liquids was prepared by introducing and removing copper foam. The electromechanical properties of this novel porous IPMC were investigated. Scanning electron microscopy observation showed that channels and pores ranging in size from ∼100 nm to ∼50 μm were distributed in the Nafion membrane. The porous IPMC was doped with 1-ethyl-3-methylimidazolium thiocyanate ionic liquid. A larger capacitance (285.00 mF cm −2 ) was obtained, which can be attributed to the electric double layer generated at the interface between the ionic polymer membrane and platinum electrode under the input voltage. The fast ion migration channels, high conductivity, and large capacitance enabled high strain of 0.051%-0.666%, a relatively large blocking force of 17.63 mN, and excellent actuation durability for more than 180 000 cycles to be achieved. Furthermore, a soft gripper consisting of a bio-inspired micropillar dry adhesive glued on one surface of the porous IPMC assembled with a mobile mechanical arm was fabricated, and the soft gripper successfully grabbed objects with various features.
As an excellent transducer, ionic polymer-metal composites (IPMCs) can act as both an actuator and a sensor. During its sensing process, many factors, such as the water content, the cation type, the surface electrode, and the dimensions of the IPMC sample, have a considerable impact on the IPMC sensing performance. In this paper, the effect of dimensions focused on the Pd-Au typed IPMC samples with various thicknesses, widths, and lengths that were fabricated and their deformation sensing performances were tested and estimated using a self-made electromechanical sensing platform. In our experiments, we employed a two-sensing mode (both current and voltage) to record the signals generated by the IPMC bending. By comparison, it was found that the response trend was closer to the applied deformation curve using the voltage-sensing mode. The following conclusions were obtained. As the thickness increased, IPMC exhibited a better deformation-sensing performance. The thickness of the sample changed from 50 μm to 500 μm and corresponded to a voltage response signal from 0.3 to 1.6 mV. On the contrary, as the length increased, the sensing performance of IPMC decreased when subjected to equal bending. The width displayed a weaker effect on the sensing response. In order to obtain a stronger sensing response, a thickness increase, together with a length reduction, of the IPMC sample is a feasible way. Also, a simplified static model was proposed to successfully explain the sensing properties of IPMC with various sizes.
A newly developed ionic electro-active actuator composed of an ionic electrolyte layer sandwiched between two graphene film layers was investigated. Scanning electronic microscopy observation and x-ray diffraction analysis showed that the graphene sheets in the film stacked in a nearly face-to-face fashion but did not restack back to graphite, and the resulting graphene film with low sheet resistance (10 Ω sq −1 ) adheres well to the electrolyte membrane. Contact angle measurement showed the surface energy (37.98 mJ m −2 ) of the ionic electrolyte polymer is 2.67 times higher than that (14.2 mJ m −2 ) of the Nafion membrane, contributing to the good adhesion between the graphene film electrode and the electrolyte membrane. An electric double-layer is formed at the interface between the graphene film electrode and the ionic electrolyte membrane under the input potential, resulting in a higher capacitance of 27.6 mF cm −2 . We report that this ionic actuator exhibits adequate bending strain, ranging from 0.032 to 0.1% (305 to 945 μm) as functions of voltage.
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