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Five stoichiometric phases of the NaC1-FeC12 system that can be represented by the general formula Nas_2~Fe~Cls (x = 0,1,2,3,4,) have been identified in high temperature Na]FeC12 cells. Their formation is dependent on the operating temperature and the state of charge of the cell. The structural characteristics of the five phases, which provide an insight into the reaction mechanism that occurs at 250~ during cell operation, are discussed.A novel, high temperature, high energy density battery, now commonly known as the "Zebra" battery, with the configuration

The crystal structures of Ca5Cr3O12 and Ca5Cr1.8Si1.2O12, the chromium analogues of silicocarnotite, Ca5P2SiO12, have been determined. Both compounds were grown at 1250°C and analyzed by electron microprobe analysis. Diffraction data collection was done on spherically ground crystals which are both orthorhombic with space group Pnma. Charge‐balance requirements as well as siteoccupancy refinement of the Si‐containing compound point strongly to the presence of both tetravalent and hexavalent chromium in tetrahedral sites. The Si is located together with tetravalent Cr in a general position, whereas the hexavalent Cr is situated on a mirror plane. The calcium atoms are located in seven‐, eight‐, and nine‐coordinated sites. The presence of vacant channels of 3.5 Å diameter perpendicular to (100) is a feature of this structural type. Its relation to the apatite and glaserite structures is also shown.