3D interdigitated microbattery architectures (3D-IMA) are fabricated by printing concentrated lithium oxide-based inks. The microbatteries are composed of interdigitated, high-aspect ratio cathode and anode structures. Our 3D-IMA, which exhibit high areal energy and power densities, may find potential application in autonomously powered microdevices.

The development of highly active and stable oxygen evolution reaction (OER) electrocatalysts is crucial for improving the efficiency of water splitting and metal-air battery devices. Herein, an efficient strategy is demonstrated for making the oxygen vacancies dominated cobalt-nickel sulfide interface porous nanowires (NiS /CoS -O NWs) for boosting OER catalysis through in situ electrochemical reaction of NiS /CoS interface NWs. Because of the abundant oxygen vacancies and interface porous nanowires structure, they can catalyze the OER efficiently with a low overpotential of 235 mV at j = 10 mA cm and remarkable long-term stability in 1.0 m KOH. The home-made rechargeable portable Zn-air batteries by using NiS /CoS -O NWs as the air-cathode display a very high open-circuit voltage of 1.49 V, which can maintain for more than 30 h. Most importantly, a highly efficient self-driven water splitting device is designed with NiS /CoS -O NWs as both anode and cathode, powered by two-series-connected NiS /CoS -O NWs-based portable Zn-air batteries. The present work opens a new way for designing oxygen vacancies dominated interface nanowires as highly efficient multifunctional electrocatalysts for electrochemical reactions and renewable energy devices.

No abstract

In recent years, vision-aided inertial odometry for state estimation has matured significantly. However, we still encounter challenges in terms of improving the computational efficiency and robustness of the underlying algorithms for applications in autonomous flight with micro aerial vehicles in which it is difficult to use high quality sensors and powerful processors because of constraints on size and weight. In this paper, we present a filter-based stereo visual inertial odometry that uses the Multi-State Constraint Kalman Filter (MSCKF) [1]. Previous work on stereo visual inertial odometry has resulted in solutions that are computationally expensive. We demonstrate that our Stereo Multi-State Constraint Kalman Filter (S-MSCKF) is comparable to state-of-art monocular solutions in terms of computational cost, while providing significantly greater robustness. We evaluate our S-MSCKF algorithm and compare it with state-of-art methods including OKVIS, ROVIO, and VINS-MONO on both the EuRoC dataset, and our own experimental datasets demonstrating fast autonomous flight with maximum speed of 17.5m/s in indoor and outdoor environments. Our implementation of the S-MSCKF is available at https://github.com/KumarRobotics/msckf vio.

A monolithically integrated device, protected by a TiO2 stabilization layer, splits water using sunlight.

No abstract

Spinel transition metal oxides are important electrode materials for lithium-ion batteries, whose lithiation undergoes a two-step reaction, whereby intercalation and conversion occur in a sequential manner. These two reactions are known to have distinct reaction dynamics, but it is unclear how their kinetics affects the overall electrochemical response. Here we explore the lithiation of nanosized magnetite by employing a strain-sensitive, bright-field scanning transmission electron microscopy approach. This method allows direct, real-time, high-resolution visualization of how lithiation proceeds along specific reaction pathways. We find that the initial intercalation process follows a two-phase reaction sequence, whereas further lithiation leads to the coexistence of three distinct phases within single nanoparticles, which has not been previously reported to the best of our knowledge. We use phase-field theory to model and describe these non-equilibrium reaction pathways, and to directly correlate the observed phase evolution with the battery's discharge performance.

A solar-driven CO2 reduction (CO2R) cell was constructed, consisting of a tandem GaAs/InGaP/TiO2/Ni photoanode in 1.0 M KOH­(aq) (pH = 13.7) to facilitate the oxygen-evolution reaction (OER), a Pd/C nanoparticle-coated Ti mesh cathode in 2.8 M KHCO3(aq) (pH = 8.0) to perform the CO2R reaction, and a bipolar membrane to allow for steady-state operation of the catholyte and anolyte at different bulk pH values. At the operational current density of 8.5 mA cm–2, in 2.8 M KHCO3(aq), the cathode exhibited <100 mV overpotential and >94% Faradaic efficiency for the reduction of 1 atm of CO2(g) to formate. The anode exhibited a 320 ± 7 mV overpotential for the OER in 1.0 M KOH­(aq), and the bipolar membrane exhibited ∼480 mV voltage loss with minimal product crossovers and >90 and >95% selectivity for protons and hydroxide ions, respectively. The bipolar membrane facilitated coupling between two electrodes and electrolytes, one for the CO2R reaction and one for the OER, that typically operate at mutually different pH values and produced a lower total cell overvoltage than known single-electrolyte CO2R systems while exhibiting ∼10% solar-to-fuels energy-conversion efficiency.