PERSPECTIVE This journal isAs a family member of redox-flow batteries (RFBs), nonaqueous RFBs can offer wide working temperature, high cell voltage, and potentially high energy density. These key features make nonaqueous RFBs an important complement of aqueous RFBs, broadening the spectrum of RFB applications. The development of nonaqueous RFBs is still at its early research stage and great challenges remain to be addressed before successful for practical applications. As such, it is essential to understand the major components in order to advance the nonaqueous RFB technology. In this perspective, three key major components of nonaqueous RFBs: organic solvent, supporting electrolyte, and redox pairs are selectively focused and discussed, with the emphases on providing an overview for those components and on highlighting the relationship between structure and property. Urgent challenges are also discussed. To advance nonaqueous RFBs, the understanding of both components and systems is critically needed and it calls for inter-disciplinary collaborations across expertise including electrochemistry, organic chemistry, physical chemistry, cell design, and system engineering. In order to demonstrate key features of nonaqueous RFBs, herein we also present an example of designing a 4.5 V ultrahigh-voltage nonaqueous RFB by combining BP/BP• − redox pair and ONF• + /OFN redox pair. PERSPECTIVEThis journal is less negative charge. When ions that do not follow those assumptions are used, the working principles are still applicable with minor alterations. (Reproduced with permission from Ref. 22) Figure 3. The BP-OFN nonaqueous RFB concept and its working principles. The negative electrolyte containing the BP/BP•redox pair and the positive electrolyte containing the OFN• + /OFN redox pair are separated by a Li + -conducting ceramic membrane (e.g., LiSICON). 1 M LiPF 6 is used as an example of supporting electrolyte. When the cell is being charged, BP molecules are reduced to form BP•radical anions in negative electrolyte (i.e., BP + e -= BP• -), and OFN molecules are oxidized to form OFN• + radical cations in positive electrolyte (i.e., OFN = OFN• + + e -). Meanwhile, Li + ions pass through Li + -conducting ceramic membrane from positive electrolyte to negative electrolyte. The discharging process is in reverse.
While the emerging wire-shaped supercapacitors (WSS) have been demonstrated as promising energy storage devices to be implemented in smart textiles, challenges in achieving the combination of both high mechanical stretchability and excellent electrochemical performance still exist. Here, an asymmetric configuration is applied to the WSS, extending the potential window from 0.8 to 1.5 V, achieving tripled energy density and doubled power density compared to its asymmetric counterpart while accomplishing stretchability of up to 100% through the prestrainning-then-buckling approach. The stretchable asymmetric WSS constituted of MnO2/CNT hybrid fiber positive electrode, aerogel CNT fiber negative electrode and KOH-PVA electrolyte possesses a high specific capacitance of around 157.53 μF cm(-1) at 50 mV s(-1) and a high energy density varying from 17.26 to 46.59 nWh cm(-1) with the corresponding power density changing from 7.63 to 61.55 μW cm(-1). Remarkably, a cyclic tensile strain of up to 100% exerts negligible effects on the electrochemical performance of the stretchable asymmetric WSS. Moreover, after 10,000 galvanostatic charge-discharge cycles, the specific capacitance retains over 99%, demonstrating a long cyclic stability.
The rapid growth of intermittent renewable energy (e.g., wind and solar) demands low-cost and large-scale energy storage systems for smooth and reliable power output, where redox-flow batteries (RFBs) could find their niche. In this work, we introduce the first all-soluble all-iron RFB based on iron as the same redox-active element but with different coordination chemistries in alkaline aqueous system. The adoption of the same redox-active element largely alleviates the challenging problem of cross-contamination of metal ions in RFBs that use two redox-active elements. An all-soluble all-iron RFB is constructed by combining an iron–triethanolamine redox pair (i.e., [Fe(TEOA)OH]−/[Fe(TEOA)(OH)]2–) and an iron–cyanide redox pair (i.e., Fe(CN)6 3–/Fe(CN)6 4–), creating 1.34 V of formal cell voltage. Good performance and stability have been demonstrated, after addressing some challenges, including the crossover of the ligand agent. As exemplified by the all-soluble all-iron flow battery, combining redox pairs of the same redox-active element with different coordination chemistries could extend the spectrum of RFBs.
A zinc–iron redox-flow battery is developed that uses low cost redox materials and delivers high cell performance, consequently achieving an unprecedentedly low system capital cost under $100 per kW h.
The emergence of stretchable electronic devices has attracted intensive attention. However, most of the existing stretchable electronic devices can generally be stretched only in one specific direction and show limited specific capacitance and energy density. Here, we report a stretchable isotropic buckled carbon nanotube (CNT) film, which is used as electrodes for supercapacitors with low sheet resistance, high omnidirectional stretchability, and electro-mechanical stability under repeated stretching. After acid treatment of the CNT film followed by electrochemical deposition of polyaniline (PANI), the resulting isotropic buckled acid treated CNT@PANI electrode exhibits high specific capacitance of 1147.12 mF cm(-2) at 10 mV s(-1). The supercapacitor possesses high energy density from 31.56 to 50.98 μWh cm(-2) and corresponding power density changing from 2.294 to 28.404 mW cm(-2) at the scan rate from 10 to 200 mV s(-1). Also, the supercapacitor can sustain an omnidirectional strain of 200%, which is twice the maximum strain of biaxially stretchable supercapacitors based on CNT assemblies reported in the literature. Moreover, the capacitive performance is even enhanced to 1160.43-1230.61 mF cm(-2) during uniaxial, biaxial, and omnidirectional elongations.
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